Comprehensive Organic Synthesis: -2. Additions to C-X[pi]-Bonds - v. 3. Carbon-carbons-Bond formation PDF Download
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Category : Organic compounds
Languages : en
Pages :
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![Comprehensive Organic Synthesis: -2. Additions to C-X[pi]-Bonds - v. 3. Carbon-carbons-Bond formation PDF](https://books.google.com/books/content/images/frontcover/3Xh4zQEACAAJ?fife=w80-h100)
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Category : Organic compounds
Languages : en
Pages :
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Author: G. Pattenden
Publisher: Elsevier
ISBN: 008091246X
Category : Science
Languages : en
Pages : 1209
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Book Description
Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.
Author: G. Pattenden
Publisher: Pergamon
ISBN: 9780080405940
Category : Science
Languages : en
Pages : 1212
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Book Description
Volume 3 covers carbon-to-carbon single bond forming reactions involving sp3, sp2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations ofsp3, sp2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.
Author: Barry M. Trost
Publisher: Pergamon
ISBN: 9780080405926
Category : Science
Languages : en
Pages : 0
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Book Description
Volume 1 provides a detailed survey of reactions that entail the 1,2-addition of nonstabilized carbanion equivalents of carbonyl, imino and thiocarbonyl functionality. Emphasis has been placed on those reagents that result in highly selective addition reactions. Methods are reported to select, for example, one carbonyl group over another in the same molecule, or to add preferentially a fragment to one (enantiotopic of diastereotopic) face of a carbonyl group. Processes that result from an initial addition to the C=X functional group, for example alkenations and rearrangements, are also covered in this volume.
![Comprehensive Organic Synthesis: -2. Additions to C-X[pi]-Bonds PDF](https://books.google.com/books/content/images/frontcover/00JLAQAAIAAJ?fife=w80-h100)
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Category : Chemistry, Organic
Languages : en
Pages : 1020
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Author: Barry M. Trost
Publisher: Pergamon
ISBN: 9780080405933
Category : Science
Languages : en
Pages : 1233
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Book Description
Volume 2 deals mainly with the addition reactions of delocalized carbanions (enolates) and their synthetic relatives (metalloenamines, enol ethers, allyl organometallics) with carbonyl compounds, imines and iminium ions. Major emphasis is placed on C-C bond-forming reactions such as the aldol and Mannich reactions. Acylation reactions are also included in this volume. Several topics that have not previously been reviewed are covered, including the use of enzymatic aldol reactions in synthesis and the Passerini-Ugi reactions.
![Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds PDF](https://books.google.com/books/content/images/frontcover/VEVLAQAAIAAJ?fife=w80-h100)
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ISBN:
Category : Chemistry, Organic
Languages : en
Pages : 1332
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Author: Robert Sunheimer
Publisher: Pearson
ISBN: 013441358X
Category : Medical
Languages : en
Pages : 672
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Book Description
This is the eBook of the printed book and may not include any media, website access codes, or print supplements that may come packaged with the bound book. Specifically designed for use in Clinical Chemistry courses in clinical laboratory technician/medical laboratory technician (CLT/MLT) and clinical laboratory science/medical technology (CLS/MT) education programs. A reader-friendly introduction that focuses on the essential analytes CLT/MLT and CLS/MT students will use in the lab Clinical Laboratory Chemistry is a part of Pearson’s Clinical Laboratory Science series of textbooks, which is designed to balance theory and application in an engaging and useful way. Highly readable, the book concentrates on clinically significant analyses students are likely to encounter in the lab. The combination of detailed technical information and real-life case studies helps learners envision themselves as members of the health care team, providing the laboratory services specific to chemistry that assist in patient care. The book’s fundamental approach and special features allow students to analyze and synthesize information, and better understand the ever-evolving nature of clinical chemistry. The Second Edition has been streamlined and updated to include four new chapters covering safety, pediatrics, geriatrics, and nutrition; real-life mini cases; new figures and photographs; updated sources and citations; and a complete teaching and learning package.
Author: Byron C. Hardinge
Publisher: Society for Mining Metallurgy & Exploration
ISBN: 9780873351041
Category : Technology & Engineering
Languages : en
Pages : 1131
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Book Description
This reference continues to be an industry standard. Anyone working in, or interested in, the coal industry needs a copy of this hardbound text for their bookshelf. Chapters include: Chemical/Physical Properties and Marketing; Preliminary Design Considerations; Coal Preparation Costs; Pre-Preparation; Size Reduction; Sizing; Concentration; Dewatering; Post Preparation/Storage and Loading; Process Control; Plant Waste and Environmental Considerations; Sampling and Analysis; Utilization; and Topics of Special Interest.
Author: R. Maggi
Publisher: Elsevier
ISBN: 0080539459
Category : Technology & Engineering
Languages : en
Pages : 1007
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Book Description
The proceedings of the VIIth International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, are in line with the general scope of this series of events. Emphasis in all Symposia has been on the scientific aspects of the preparation of new and industrial catalysts, or on new methods of preparation, rather than on the catalytic reactions in which such solids are ultimately used. In the present context, the catalytic event itself has only been considered as another, though often decisive, method of catalyst characterization.
