Author: Marissa Anne Caldwell
Publisher: Stanford University
ISBN:
Category :
Languages : en
Pages : 113
Get Book Here
Book Description
Phase change (PC) memory has emerged as a leading candidate for next generation information storage technology. Based on the reversible amorphous-crystalline phase transition of chalcogenide materials, PC technology has already been commercialized through the optical disk industry and is currently being evaluated for non-volatile electronic data storage as phase change random access memory (PCRAM). In either the optical or electronic application, device performance relies on the material properties of the active phase change material (PCM). Traditionally deposited through physio-chemical routes such as sputtering or chemical vapor deposition, the PCM fundamentally limits PC scaling potential as it is expected that key properties will change as the volume of PCM decreases. Colloidal nanoparticle systems provide a unique opportunity to systematically study the properties of materials in the nanosize regime due to the potential for exquisite composition and size control. In this talk, I will present the first colloidal nanoparticle system of a known phase change material. Colloidal GeTe nanoparticles 1.4-4nm in diameter were synthesized through a co-precipitation route and characterized by transmission electron microscopy, energy dispersive x-ray spectroscopy and x-ray diffraction. Nuclear magnetic resonance spectroscopy (1H and 31P) was used to elucidate the molecular species involved in the reaction pathway and found that a metal center mediated proton transfer is necessary to mediate the relative reactivity of the reactants. In addition, a post-synthetic size selective procedure was developed to separate the nanoparticles into distinct size ranges. Using in-situ heating, the size dependent crystallization temperature was measured by XRD and was found to increase with decreasing nanoparticle diameter suggesting favorable improvements in lifetime data retention for scaled PCRAM cells. To evaluate the potential use in PCRAM devices, electrical measurements were also collected on nanoparticle films. Resistance versus temperature measurements revealed that nanoparticle films retained the high resistive contrast between the amorphous and crystalline phases necessary for PCRAM operation. After design optimization, PCRAM cells were fabricated utilizing the nanoparticles as a solution processable precursor to the PCM. Completed cells showed reversible switching, including threshold switching, characteristic of PCRAM operation. Cycling up to 200 times, the cells are the best performing solution processed PCRAM devices reported to date, suggesting that colloidal nanoparticles are a viable route to PCMs.
Author: Marissa Anne Caldwell
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Phase change (PC) memory has emerged as a leading candidate for next generation information storage technology. Based on the reversible amorphous-crystalline phase transition of chalcogenide materials, PC technology has already been commercialized through the optical disk industry and is currently being evaluated for non-volatile electronic data storage as phase change random access memory (PCRAM). In either the optical or electronic application, device performance relies on the material properties of the active phase change material (PCM). Traditionally deposited through physio-chemical routes such as sputtering or chemical vapor deposition, the PCM fundamentally limits PC scaling potential as it is expected that key properties will change as the volume of PCM decreases. Colloidal nanoparticle systems provide a unique opportunity to systematically study the properties of materials in the nanosize regime due to the potential for exquisite composition and size control. In this talk, I will present the first colloidal nanoparticle system of a known phase change material. Colloidal GeTe nanoparticles 1.4-4nm in diameter were synthesized through a co-precipitation route and characterized by transmission electron microscopy, energy dispersive x-ray spectroscopy and x-ray diffraction. Nuclear magnetic resonance spectroscopy (1H and 31P) was used to elucidate the molecular species involved in the reaction pathway and found that a metal center mediated proton transfer is necessary to mediate the relative reactivity of the reactants. In addition, a post-synthetic size selective procedure was developed to separate the nanoparticles into distinct size ranges. Using in-situ heating, the size dependent crystallization temperature was measured by XRD and was found to increase with decreasing nanoparticle diameter suggesting favorable improvements in lifetime data retention for scaled PCRAM cells. To evaluate the potential use in PCRAM devices, electrical measurements were also collected on nanoparticle films. Resistance versus temperature measurements revealed that nanoparticle films retained the high resistive contrast between the amorphous and crystalline phases necessary for PCRAM operation. After design optimization, PCRAM cells were fabricated utilizing the nanoparticles as a solution processable precursor to the PCM. Completed cells showed reversible switching, including threshold switching, characteristic of PCRAM operation. Cycling up to 200 times, the cells are the best performing solution processed PCRAM devices reported to date, suggesting that colloidal nanoparticles are a viable route to PCMs.
Author: Andrea Redaelli
Publisher: Springer
ISBN: 3319690531
Category : Technology & Engineering
Languages : en
Pages : 342
Get Book Here
Book Description
This book describes the physics of phase change memory devices, starting from basic operation to reliability issues. The book gives a comprehensive overlook of PCM with particular attention to the electrical transport and the phase transition physics between the two states. The book also contains design engineering details on PCM cell architecture, PCM cell arrays (including electrical circuit management), as well as the full spectrum of possible future applications.
Author: Simone Raoux
Publisher: Springer Science & Business Media
ISBN: 0387848746
Category : Technology & Engineering
Languages : en
Pages : 430
Get Book Here
Book Description
"Phase Change Materials: Science and Applications" provides a unique introduction of this rapidly developing field. Clearly written and well-structured, this volume describes the material science of these fascinating materials from a theoretical and experimental perspective. Readers will find an in-depth description of their existing and potential applications in optical and solid state storage devices as well as reconfigurable logic applications. Researchers, graduate students and scientists with an interest in this field will find "Phase Change Materials" to be a valuable reference.
Author: Robert Kozma
Publisher: Springer Science & Business Media
ISBN: 9400744919
Category : Medical
Languages : en
Pages : 318
Get Book Here
Book Description
Physical implementation of the memristor at industrial scale sparked the interest from various disciplines, ranging from physics, nanotechnology, electrical engineering, neuroscience, to intelligent robotics. As any promising new technology, it has raised hopes and questions; it is an extremely challenging task to live up to the high expectations and to devise revolutionary and feasible future applications for memristive devices. The possibility of gathering prominent scientists in the heart of the Silicon Valley given by the 2011 International Joint Conference on Neural Networks held in San Jose, CA, has offered us the unique opportunity of organizing a series of special events on the present status and future perspectives in neuromorphic memristor science. This book presents a selection of the remarkable contributions given by the leaders of the field and it may serve as inspiration and future reference to all researchers that want to explore the extraordinary possibilities given by this revolutionary concept.
Author: Yan Hong
Publisher:
ISBN:
Category : Heat
Languages : en
Pages : 191
Get Book Here
Book Description
A major challenge of developing faster and smaller microelectronic devices is that high flux of heat needs to be removed efficiently to prevent overheating of devices. The conventional way of heat removal using liquid reaches a limit due to low thermal conductivity and limited heat capacity of fluids. Adding solid nanoparticles into fluids has been proposed as a way to enhance thermal conductivity of fluids, but recent results show inconclusive anomalous enhancements in thermal conductivity. A possible way to improve heat transfer is to increase the heat capacity of liquid by adding phase change nanoparticles with large latent heat of fusion into the liquid. Such nanoparticles absorb heat during solid to liquid phase change. However, the colloidal suspension of bare phase change nanoparticles has limited use due to aggregation of molten nanoparticles, irreversible sticking on fluid channels, and dielectric property loss. This dissertation describes a new method to enhance the heat transfer property of a liquid by adding encapsulated phase change nanoparticles (nano-PCMs), which will absorb thermal energy during solid-liquid phase change and release heat during freeze. Specifically, silica encapsulated indium nanoparticles, and polymer encapsulated paraffin (wax) nanoparticles have been prepared using colloidal method, and dispersed into poly-[alpha]-olefin (PAO) and water for high temperature and low temperature applications, respectively. The shell, with a higher melting point than the core, can prevent leakage or agglomeration of molten cores, and preserve the dielectric properties of the base fluids. Compared to single phase fluids, heat transfer of nanoparticle-containing fluids have been significantly enhanced due to enhanced heat capacities. The structural integrity of encapsulation allows repeated uses of nanoparticles for many cycles. By forming porous semi crystalline silica shells obtained from water glass, supercooling has been greatly reduced due to low energy barrier of heterogeneous nucleation. Encapsulated phase change nanoparticles have also been added into exothermic reaction systems such as catalytic and polymerization reactions to effectively quench local hot spots, prevent thermal runaway, and change product distribution. Specifically, silica-encapsulated indium nanoparticles, and silica encapsulated paraffin (wax) nanoparticles have been used to absorb heat released in catalytic reaction, and to mitigate the gel effect during polymerization, respectively. The reaction rates do not raise significantly owing to thermal buffering using phase change nanoparticles at initial stage of thermal runaway. The effect of thermal buffering depends on latent heats of fusion of nanoparticles, and heat releasing kinetics of catalytic reactions and polymerizations. Micro/nanoparticles of phase change materials will open a new dimension for thermal management of exothermic reactions.
Author: Philip G. Born
Publisher: Springer Science & Business Media
ISBN: 3319002309
Category : Science
Languages : en
Pages : 139
Get Book Here
Book Description
This thesis deals with the processes that create ordered assemblies from disordered nanoparticles. Ordered packings of nanoscale particles can exhibit unusual properties. This work investigates the self-assembly of such particles, a process widely employed for the generation of ordered structures, but not yet well understood. In situ methods are used to observe the assembly of sub-micron polymer lattices and sub-10 nm gold particles into crystalline monolayers and aggregates. On the basis of these results, the book develops new models that describe the competition between different influences, such as thermal agitation and directional forces. It suggests necessary criteria that lead to the emergence of order.
Author: Cheol Seong Hwang
Publisher: Springer Science & Business Media
ISBN: 146148054X
Category : Science
Languages : en
Pages : 266
Get Book Here
Book Description
Offering thorough coverage of atomic layer deposition (ALD), this book moves from basic chemistry of ALD and modeling of processes to examine ALD in memory, logic devices and machines. Reviews history, operating principles and ALD processes for each device.
Author: Wolfgang J. Parak
Publisher:
ISBN: 9781628419566
Category :
Languages : en
Pages : 176
Get Book Here
Book Description
Author: An Chen
Publisher: John Wiley & Sons
ISBN: 1118447743
Category : Technology & Engineering
Languages : en
Pages : 570
Get Book Here
Book Description
Emerging Nanoelectronic Devices focuses on the future direction of semiconductor and emerging nanoscale device technology. As the dimensional scaling of CMOS approaches its limits, alternate information processing devices and microarchitectures are being explored to sustain increasing functionality at decreasing cost into the indefinite future. This is driving new paradigms of information processing enabled by innovative new devices, circuits, and architectures, necessary to support an increasingly interconnected world through a rapidly evolving internet. This original title provides a fresh perspective on emerging research devices in 26 up to date chapters written by the leading researchers in their respective areas. It supplements and extends the work performed by the Emerging Research Devices working group of the International Technology Roadmap for Semiconductors (ITRS). Key features: • Serves as an authoritative tutorial on innovative devices and architectures that populate the dynamic world of “Beyond CMOS” technologies. • Provides a realistic assessment of the strengths, weaknesses and key unknowns associated with each technology. • Suggests guidelines for the directions of future development of each technology. • Emphasizes physical concepts over mathematical development. • Provides an essential resource for students, researchers and practicing engineers.
