Classical Thermodynamics of Nonelectrolyte Solutions PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Classical Thermodynamics of Nonelectrolyte Solutions PDF full book. Access full book title Classical Thermodynamics of Nonelectrolyte Solutions by Hendrick C. Van Ness. Download full books in PDF and EPUB format.
Author: Hendrick C. Van Ness
Publisher: McGraw-Hill Companies
ISBN:
Category : Science
Languages : en
Pages : 504
Get Book Here
Book Description
Author: Hendrick C. Van Ness
Publisher: McGraw-Hill Companies
ISBN:
Category : Science
Languages : en
Pages : 504
Get Book Here
Book Description
Author: H. C. Van Ness
Publisher: Elsevier
ISBN: 148322547X
Category : Science
Languages : en
Pages : 176
Get Book Here
Book Description
Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.
Author: William Acree
Publisher: Academic Press
ISBN: 032314067X
Category : Science
Languages : en
Pages : 319
Get Book Here
Book Description
Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler's theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.
Author: M L McGlashan
Publisher: Royal Society of Chemistry
ISBN: 1847555829
Category : Science
Languages : en
Pages : 376
Get Book Here
Book Description
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.
Author: Yoshikata Koga
Publisher: Elsevier
ISBN: 0080551874
Category : Technology & Engineering
Languages : en
Pages : 311
Get Book Here
Book Description
As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book "mixing scheme), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as "Koga line. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol – sample species – H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. - A new differential approach to solution thermodynamics - A particularly clear elucidation of the mixing schemes in aqueous solutions - A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O - A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect - A new differential approach to studies in muti-component aqueous solutions
Author: David A. Palmer
Publisher: CRC Press
ISBN: 1351087886
Category : Science
Languages : en
Pages : 381
Get Book Here
Book Description
This practical handbook features an overview of the importance of physical properties and thermodynamics; and the use of thermo-dynamics to predict the extent of reaction in proposed new chem-ical combinations. The use of special types of data and pre-diction methods to develop flowsheets for probing projects; and sources of critically evaluated data, dividing the published works into three categories depending on quality are given. Methods of doing one's own critical evaluation of literature, a list of known North American contract experimentalists with the types of data mea-sured by each, methods for measuring equilibrium data, and ther-modynamic concepts to carry out process opti-mization are also featured.
Author: Paul E. Smith
Publisher: CRC Press
ISBN: 1439899231
Category : Medical
Languages : en
Pages : 383
Get Book Here
Book Description
There are essentially two theories of solutions that can be considered exact: the McMillan-Mayer theory and Fluctuation Solution Theory (FST). The first is mostly limited to solutes at low concentrations, while FST has no such issue. It is an exact theory that can be applied to any stable solution regardless of the number of components and their co
Author: Scott Emerson Wood
Publisher: Cambridge University Press
ISBN: 0521330416
Category : Science
Languages : en
Pages : 461
Get Book Here
Book Description
The aim of this book is to develop the concepts and relations pertinent to the solution of many thermodynamic problems encountered in multi-phase, multi-component systems. In doing so, it emphasizes a comprehension and development of general expressions for solving such problems, rather than ready-made equations for particular applications. Throughout the book, the methods of Gibbs are used with emphasis on the chemical potential.
Author: Emmerich Wilhelm
Publisher: Royal Society of Chemistry
ISBN: 1839164107
Category : Science
Languages : en
Pages : 449
Get Book Here
Book Description
This book contains the latest information on all aspects of the most important chemical thermodynamic properties of Gibbs energy and Helmholtz energy, as related to fluids. Both the Gibbs energy and Helmholtz energy are very important in the fields of thermodynamics and material properties as many other properties are obtained from the temperature or pressure dependence. Bringing all the information into one authoritative survey, the book is written by acknowledged world experts in their respective fields. Each of the chapters will cover theory, experimental methods and techniques and results for all types of liquids and vapours. This book is the fourth in the series of Thermodynamic Properties related to liquids, solutions and vapours, edited by Emmerich Wilhelm and Trevor Letcher. The previous books were: Heat Capacities (2010), Volume Properties (2015), and Enthalpy (2017). This book fills the gap in fundamental thermodynamic properties and is the last in the series.
Author: A Anderko
Publisher: World Scientific
ISBN: 9814611778
Category :
Languages : en
Pages : 526
Get Book Here
Book Description
This volume is a collection of papers, mostly state-of-the-art reviews, describing main topics of current research in Applied Thermodynamics. The papers deal with measurements of thermodynamic properties which are important for process design in chemical and related industries as well as for theoretical investigations of pure fluids and mixtures. Besides measuring techniques, methods are reviewed for the processing and correlation of experimental data.
