Chemical Reactions and Interactions of CN-containing Molecules on Metal Surfaces PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Chemical Reactions and Interactions of CN-containing Molecules on Metal Surfaces PDF full book. Access full book title Chemical Reactions and Interactions of CN-containing Molecules on Metal Surfaces by Hugo Celio. Download full books in PDF and EPUB format.
Author: Hugo Celio
Publisher:
ISBN:
Category :
Languages : en
Pages : 544
Get Book Here
Book Description
Author: Hugo Celio
Publisher:
ISBN:
Category :
Languages : en
Pages : 544
Get Book Here
Book Description
Author: Norman H. March
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 308
Get Book Here
Book Description
The problem of molecules interacting with metal surfaces has for a very long time been recognized to be of considerable technological as well as fundamental importance. Thus in the former category, a substantial number of important synthetic reactions for industrial purposes make use of metal surfaces as catalysts. Or again, problems of corrosion of metals are of great practical importance, such as in nuclear-reactor technology [see, for instance, my earlier articles, in: Physics Bulletin, Volume 25, p. 582, Institute of Physics, UK (1974); and in: Physics and Contemporqry Needs (Riazuddin, ed. ), Vol. 1, p. 53, Plenum Press, New York (1977)]. It is therefore of significance to strive to gain a more fundamental understand ing of the atomic, and ultimately the electronic, processes that occur when a molecule is brought into the proximity of a metal surface. The present volume focuses mainly on the theory and concepts involved; however, it is intended for readers in chemistry, physics, and materials science who are not specialists in theory but nevertheless wish to learn more about this truly interdisciplinary area of theoretical science. The aim of the book is to present the way in which valence theory can be synthesized with the understanding of metals that has been gained over the last half century or so. While advanced theory has at times been necessary, is largely presented in an extensive set of Appendixes.
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 924
Get Book Here
Book Description
Author: Emile Dominique Léon Rienks
Publisher:
ISBN:
Category :
Languages : en
Pages : 96
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 25
Get Book Here
Book Description
In coordinately unsaturated molecular metal complexes, carbonhydrogen bonds of the peripheral ligands may, if the stereochemistry allows, closely approach a metal center so as to develop a three-center two-electron bond between the carbon, the hydrogen, and the metal atoms, C-H-M. In some instances, the interaction is followed by a scission of the C-H bond whereby the metal is effectively oxidized and discrete M-H and M-C ó bonds are formed. In this paper, this class of metal-hydrogen-carbon interactions and reactions is shown to be a common phenomenon in metal surface chemistry. Ultra high vacuum studies of nickel and platinum with simple organic molecules like olefins and arenes are described. These surface chemistry studies were done as a function of surface crystallography and surface composition. The discussion is limited to the chemistry of methyl isocyanide, acetonitrile, benzene and toluene, pyridine, trimethylphosphine, ethylene, acetylene and saturated hydrocarbons. Finally, molecular orbital calculations are presented that support the experimental identification of the importance of C-H-M metal bonding for metal surfaces.
Author: John P. Fackler Jr.
Publisher: Springer
ISBN: 0306435276
Category : Science
Languages : en
Pages : 342
Get Book Here
Book Description
This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.
Author: Mark Francis Lynch
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author:
Publisher: PHI Learning Pvt. Ltd.
ISBN: 8120343085
Category : Chemistry, Inorganic
Languages : en
Pages : 1069
Get Book Here
Book Description
Author: G. Alefeld
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 420
Get Book Here
Book Description
Author: E W Abel
Publisher: Royal Society of Chemistry
ISBN: 1847554148
Category : Science
Languages : en
Pages : 476
Get Book Here
Book Description
Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
