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Author: Mamantov
Publisher: Springer Science & Business Media
ISBN: 1461339820
Category : Science
Languages : en
Pages : 322
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Book Description
This book consists of contributions by participants in the Symposium "Spectroscopic and Electrochemical Characterizat.ion of Solute Species in Non~Aqueous Solvents" which took place at the American Chemical Society Meeting, Division of Analytical Chemistry, August 31 and September I, 1976, San Francisco, California. The manuscripts were submitted to the editor during the first half of 1977 and, in most cases, represent reviews of selected research topics in the broad area of characterization of solute species in non~aqueous solvents. In organizing this Symposium, I attempted to bring together a significantly large group of research workers involved in spectro scopic and electrochemical studies in the three large classes of non-aqueous solvents ~ organic solvents, covalent inorganic sol vents and molten salts. The experimental apprcaches and problems, such as avoidance of traces of moisture and oxygen, are frequently similar for all types of non-aqueous solvents. It is hoped that this volume will be useful to all concerned with chemistry in non-aqueous solvents. Gleb l>lamantov , Contents 1. IDENTIFICATION AND SYSTEMIZATION OF SOLVENT PROPERTIES INVOLVED IN THE LIGAND SUBSTITUTION KINETICS OF LABILE COMPLEXES OF NICKEL(II) J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J.
Author: Mamantov
Publisher: Springer Science & Business Media
ISBN: 1461339820
Category : Science
Languages : en
Pages : 322
Get Book Here
Book Description
This book consists of contributions by participants in the Symposium "Spectroscopic and Electrochemical Characterizat.ion of Solute Species in Non~Aqueous Solvents" which took place at the American Chemical Society Meeting, Division of Analytical Chemistry, August 31 and September I, 1976, San Francisco, California. The manuscripts were submitted to the editor during the first half of 1977 and, in most cases, represent reviews of selected research topics in the broad area of characterization of solute species in non~aqueous solvents. In organizing this Symposium, I attempted to bring together a significantly large group of research workers involved in spectro scopic and electrochemical studies in the three large classes of non-aqueous solvents ~ organic solvents, covalent inorganic sol vents and molten salts. The experimental apprcaches and problems, such as avoidance of traces of moisture and oxygen, are frequently similar for all types of non-aqueous solvents. It is hoped that this volume will be useful to all concerned with chemistry in non-aqueous solvents. Gleb l>lamantov , Contents 1. IDENTIFICATION AND SYSTEMIZATION OF SOLVENT PROPERTIES INVOLVED IN THE LIGAND SUBSTITUTION KINETICS OF LABILE COMPLEXES OF NICKEL(II) J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J.
Author:
Publisher:
ISBN: 9781461339830
Category :
Languages : en
Pages : 336
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Author: Gleb Mamantov
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
Author: Symposium on Spectroscopic and Electrochemical Characterization of Solute Species in Nonaqueous Solvents (1976, San Francisco, Calif.)
Publisher:
ISBN:
Category :
Languages : en
Pages : 325
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Author: K. Burger
Publisher: Elsevier
ISBN: 0444597514
Category : Science
Languages : en
Pages : 269
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Book Description
Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
Author: Gleb Mamantov
Publisher:
ISBN:
Category :
Languages : en
Pages : 325
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Author: Michéla L. Brumfield
Publisher:
ISBN:
Category : Dichloronitrobenzene
Languages : en
Pages : 178
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Book Description
Experimental data were obtained for the computation of mole fraction solubilities of three dichloronitrobenzenes in organic solvents at 25oC, and solubility ratios were obtained from this data. Abraham model equations were developed for solutes in tributyl phosphate that describe experimental values to within 0.15 log units, and correlations were made to describe solute partitioning in systems that contain either "wet" or "dry" tributyl phosphate. Abraham model correlations have also been developed for solute transfer into anhydrous diisopropyl ether, and these correlations fit in well with those for other ethers. Abraham correlations for the solvation of enthalpy have been derived from experimental and literature data for mesitylene, p-xylene, chlorobenzene, and 1,2-dichlorobenzene at 298.15 K. In addition, the enthalpy contribution of hydrogen bonding between these solutes and acidic solvents were predicted by these correlations and were in agreement with an established method. Residual plots corresponding to Abraham models developed in all of these studies were analyzed for trends in error between experimental and calculated values.
Author: David Glick
Publisher: John Wiley & Sons
ISBN: 0470110791
Category : Science
Languages : en
Pages : 421
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Book Description
Biochemical analysis is a rapidly expanding field and is a key component of modern drug discovery and research. Methods of Biochemical Analysis provides a periodic and authoritative review of the latest achievements in biochemical analysis. Founded in 1954 by Professor David Glick, Methods of Biochemical Analysis provides a timely review of the latest developments in the field.
Author: Dr. A. V. Kasture
Publisher: Pragati Books Pvt. Ltd.
ISBN: 9788185790077
Category : Drugs
Languages : en
Pages : 264
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