Characterization and Catalytic Application of Unsaturated Transition Metal Complexes PDF Download
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Author: Todd J. Johnson
Publisher:
ISBN:
Category :
Languages : en
Pages : 632
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Author: Todd J. Johnson
Publisher:
ISBN:
Category :
Languages : en
Pages : 632
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Author: Lori Anne Watson
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
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Author: Guofang Zhang
Publisher:
ISBN:
Category :
Languages : en
Pages : 136
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Author: Adam Ruddy
Publisher:
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Category :
Languages : en
Pages :
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Author: Universitat de València. Facultat de Ciències Químiques
Publisher:
ISBN:
Category :
Languages : en
Pages : 214
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Author: Ewa Broclawik
Publisher: Springer
ISBN: 3030117146
Category : Science
Languages : en
Pages : 532
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This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
Author: John C. Linehan
Publisher:
ISBN:
Category :
Languages : en
Pages : 514
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Author: Alan Charles Cooper
Publisher:
ISBN:
Category :
Languages : en
Pages : 414
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Author: Veeranna Yempally
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Category :
Languages : en
Pages :
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The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
Author: Soumen Mukherjee
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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