Catalytic Addition Reactions of Acetylenic Alcohols PDF Download
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Author: William S. Murray
Publisher:
ISBN:
Category :
Languages : en
Pages : 35
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Book Description
Author: William S. Murray
Publisher:
ISBN:
Category :
Languages : en
Pages : 35
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Book Description
Author: Herman Pines
Publisher: Elsevier
ISBN: 0323144829
Category : Science
Languages : en
Pages : 602
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Book Description
Base-Catalyzed Reactions of Hydrocarbons and Related Compounds focuses on the use of bases as catalysts for the conversion of hydrocarbons and related compounds. In order to emphasize the broad scope of base-catalyzed reactions, examples dealing with the conversion of non-hydrocarbons are given. Comprised of 14 chapters, this book begins with a historical overview of base-catalyzed conversions of hydrocarbons, followed by a discussion on the isomerization of olefins, acetylenes, and allenes, as well as the dimerization and oligomerization of hydrocarbons. The reader is then introduced to a variety of reactions, including those between aromatic hydrocarbons and olefins and between alkylpyridines and alkenylpyridines; homogeneous carbon-carbon addition reactions; and reactions of aprotic solvents with olefins. Subsequent chapters explore carbon-carbon addition of olefins with miscellaneous compounds; addition of ammonia, amines, and anilines to olefinic hydrocarbons; hydrogenation and oxygenation; dehydrogenation, aromatization, and hydrogen transfer; and dehydration of alcohols. This monograph will be of interest to chemists.
Author: Dale W. Blackburn
Publisher: CRC Press
ISBN: 1000104370
Category : Science
Languages : en
Pages : 377
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Book Description
This volume is a collection of the papers presented at the Twelfth Conference on the Catalysis of Organic Reactions, where all phases of catalysis, including heterogeneous catalytic hydrogenation, catalytic oxidation, homogeneous catalysis, carbonylation, and amination have been discussed.
Author: Barry M. Trost
Publisher: John Wiley & Sons
ISBN: 3527335056
Category : Science
Languages : en
Pages : 420
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Book Description
A comprehensive and up-to-date overview of alkyne chemistry, taking into account the progress made over the last two decades. The experienced editors are renowned world leaders in the field, while the list of contributors reads like a "Who's Who" of synthetic organic chemistry. The result is a valuable reference not only for organic chemists at universities and in the chemical industry, but also for biologists and material scientists involved in the modern synthesis of organic compounds and materials.
Author: A.E. Shilov
Publisher: Springer Science & Business Media
ISBN: 0792361016
Category : Science
Languages : en
Pages : 551
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Book Description
This monograph is devoted to the activation and various transformations of saturated hydrocarbons (alkanes), i.e. reactions accompanied by the C-H and C-C bond cleavage. Alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for the chemical industry. On the other hand, these substances are known to be the least reactive organic compounds. Special attention is paid to the recently found alkane activations in the presence of metal complexes, which are described in more detail. In addition to the reactions of saturated hydrocarbons which are the main topic of this book, the activation of C-H bonds in arenes and even olefins and acetylenes are considered. The monograph will be useful not only for those who are interested in the activation of alkanes and other hydrocarbons by metal complexes, but also for specialists in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. Some parts of the monograph will be of interest for specialists in inorganic and organic chemistry, theoretical chemistry, biochemistry and even biology, and also for those who work in the petrochemical industry, industrial organic synthesis and biotechnology.
Author: Peter Maitlis
Publisher: Elsevier
ISBN: 0323159613
Category : Science
Languages : en
Pages : 233
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Book Description
The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Industrial applications can re-oxidize the palladium metal back to Pd(II) in situ, making the reactions catalytic. The text also discusses certain reactions that can form C-O bonds as part of an oxidative process. The book also describes significant reactions that can be catalyzed by palladium metal, such as in the hydrogenation of multiple bonds, in the carbonylation of certain olefins and acetylenes, and in the catalytic cracking of high molecular weight hydrocarbons. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the book truly useful.
Author: Charles Kelley
Publisher:
ISBN:
Category :
Languages : en
Pages : 18
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Book Description
Author: A. W. Johnson
Publisher: London : E. Arnold, [1946-50 .
ISBN:
Category : Acetylene compounds
Languages : en
Pages : 424
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Book Description
Author: P. Henry
Publisher: Springer Science & Business Media
ISBN: 9789027709868
Category : Science
Languages : en
Pages : 458
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Book Description
The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.
Author: George William Parshall
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 262
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Book Description
Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.
