Carbanions in Organic Synthesis PDF Download
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Author: John Charles Stowell
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 276
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Book Description
Author: John Charles Stowell
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 276
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Book Description
Author: E. Buncel
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 372
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Book Description
Table of contents
Author: Donald J. Cram
Publisher: Elsevier
ISBN: 0323162444
Category : Science
Languages : en
Pages : 299
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Book Description
Organic Chemistry, Volume 4: Fundamentals of Carbanion Chemistry provides information pertinent to carbanion chemistry. This book explores several topics, including carbonium ions, carbanions, carbenes, and carbon radicals. Comprised of six chapters, this volume starts with an overview of the variation of the kinetic and thermodynamic acidities of carbon acids with substituents and environments. This text then explores the methods of carbanion stabilization by substituents and discusses the various types of stabilization. Other chapters explain the stereochemistry of hydrogen–deuterium exchange and examine the stereochemistry of substitution reactions of organometallic compounds. This book discusses as well the structure and immediate environment of reaction intermediates through the use of stereochemical techniques. The final chapter considers the unsaturated anionic rearrangements of carbanions, carbonium ions, as well as carbon radicals and other rearrangements. Chemists, organic chemists, researchers, and graduate students interested in the field of carbanion chemistry will find this book extremely useful.
Author: R. Richard Goehring
Publisher:
ISBN:
Category : Carbanions
Languages : en
Pages : 384
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Book Description
Author: Robert B. Bates
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 136
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Book Description
Author: Charles M. Thompson
Publisher: CRC Press
ISBN: 9780849378683
Category : Science
Languages : en
Pages : 264
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Book Description
Many laboratories were reluctant at first to embrace dianion chemistry as part of the standard reaction repertoire. Today, however, researchers can comfortably draw upon the dianion literature to choose an abundance of reagents and strategies that are reliable, effective, and, in many cases, the best answer to a synthetic problem. This interesting book introduces, surveys, and consolidates carbon-based dianion chemistry. Chapter 1 serves as an introduction and as an index of the various dianions covered in the book. Chapters 2 through 5 cover the ensemble of dianion types designated by their first deprotonation site. Each chapter contains an experimental section that explains relevant protocols.
Author: Jie Jack Li
Publisher: CRC Press
ISBN: 1315353199
Category : Medical
Languages : en
Pages : 304
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Book Description
Gives a comprehensive and up-to-date summary of carbocation chemistry. Discusses the widespread applications of carbocation chemistry, with an emphasis on organic synthesis. Contains the contributions of highly experienced authors. Provides a panoramic view of carbocation chemistry, which is part of the foundation of organic chemistry.
Author: Bernd Giese
Publisher: C R C Press Reprints
ISBN:
Category : Science
Languages : en
Pages : 316
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Book Description
Author: A. Bruylants
Publisher: Butterworth-Heinemann
ISBN: 1483156176
Category : Science
Languages : en
Pages : 278
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Book Description
Organic Synthesis is a collection of papers dealing with synthetic tools, the effect of pressure on the electronic states of organic solids, and some novel approaches to alkylations. Some papers explain the cyclopropanation of silyl enol ethers and the two-phase reactions in the chemistry of carbanions and halocarbenes as useful tools in organic synthesis. One paper investigates the "biogenetic-type" synthesis of the bicyclic penicillin-cephalosporin antibiotics from an acyclic tripeptide equivalent. Another paper explains the advantages of the two-phase system to generate trihalomethylanions and dihalocarbenes as it allows the investigator to carry out all the reactions typical for these species easily. The system also readily applies to the reactions of some carbanions with aromatic nitrocompounds. Thallium(III) nitrate (TTN) can be used as an oxidant in organic synthesis; reactions that follow it use include the oxidations and oxidative rearrangements of olefins, acetylenes, ketones and compounds containing carbon-nitrogen double bonds. Another paper presents some examples that use singlet oxygen in synthetic organic chemistry. This collection is useful for researchers, technicians, and scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry, such as physical chemistry and inorganic chemistry.
Author: William B. Motherwell
Publisher: Elsevier
ISBN: 0080924956
Category : Science
Languages : en
Pages : 289
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Book Description
Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field
