Atomistic Modelling of Structure and Dynamics of Pure, Blends, and Doped Chromonic Solutions

Atomistic Modelling of Structure and Dynamics of Pure, Blends, and Doped Chromonic Solutions PDF Author: Oscar Matus Rivas
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
"Lyotropic chromonic liquid crystals are an emerging class of mesogenic materials under current intense research and development due to their exceptional phase properties and promising advanced materials and devices’ applications. Although remarkable progress has been achieved in characterizing chromonic phases, a comprehensive understanding of the underlying mechanisms governing their spontaneous self-assembly and aggregation, miscibility capabilities and phase properties is still not entirely understood at the atomistic scale. These challenges arise from the inherent difficulty of characterizing chromonic behaviour at the molecular level with traditional experimental methods. This thesis aims to evaluate and characterize the structural and dynamical properties of relevant pure, blends, and doped chromonic liquid crystal solutions prepared with Disodium Cromoglycate, Sunset Yellow, and Bordeaux dye mesogens using atomistic molecular dynamics simulations. The relationship between equilibrium stacking structure and chromonic molecular architecture is examined, resolved and explained in detail. The formation of structured water around chromonic columnar aggregates via hydrogen bonding interactions and its crucial dynamic role on the aggregation and stability of chromonic mesogens are rigorously investigated. Additionally, molecular mixing affinity rules are determined for binary chromonic blends. Finally, the influence of doping agents, such as NaCl and MgCl2 ionic salts and L-alanine amino acid chiral additive, on the structure and dynamics of chromonic solutions is evaluated. Taken together, the results presented throughout this work provide an in-depth description of the atomistic-level mechanisms controlling the self-assembly and phase properties of lyotropic chromonic liquid crystal solutions, in addition to insights for the development of future experimental and simulation methodologies for expanding chromonics research and applications. These findings represent substantial contributions to the fundamental understanding of chromonic aggregation rules, which are crucial for the fabrication of innovative chromonic functionalities based on the fine-tuning of noncovalent interactions by designing novel custom-made chromonic mesogens"--

Springer Handbook of Glass

Springer Handbook of Glass PDF Author: J. David Musgraves
Publisher: Springer
ISBN: 9783319937267
Category : Technology & Engineering
Languages : en
Pages : 1590

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Book Description
This handbook provides comprehensive treatment of the current state of glass science from the leading experts in the field. Opening with an enlightening contribution on the history of glass, the volume is then divided into eight parts. The first part covers fundamental properties, from the current understanding of the thermodynamics of the amorphous state, kinetics, and linear and nonlinear optical properties through colors, photosensitivity, and chemical durability. The second part provides dedicated chapters on each individual glass type, covering traditional systems like silicates and other oxide systems, as well as novel hybrid amorphous materials and spin glasses. The third part features detailed descriptions of modern characterization techniques for understanding this complex state of matter. The fourth part covers modeling, from first-principles calculations through molecular dynamics simulations, and statistical modeling. The fifth part presents a range of laboratory and industrial glass processing methods. The remaining parts cover a wide and representative range of applications areas from optics and photonics through environment, energy, architecture, and sensing. Written by the leading international experts in the field, the Springer Handbook of Glass represents an invaluable resource for graduate students through academic and industry researchers working in photonics, optoelectronics, materials science, energy, architecture, and more.

Introduction to Nanoscience

Introduction to Nanoscience PDF Author: Stuart Lindsay
Publisher: OUP Oxford
ISBN: 0191609277
Category : Technology & Engineering
Languages : en
Pages : 480

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Book Description
Nanoscience is not physics, chemistry, engineering or biology. It is all of them, and it is time for a text that integrates the disciplines. This is such a text, aimed at advanced undergraduates and beginning graduate students in the sciences. The consequences of smallness and quantum behaviour are well known and described Richard Feynman's visionary essay 'There's Plenty of Room at the Bottom' (which is reproduced in this book). Another, critical, but thus far neglected, aspect of nanoscience is the complexity of nanostructures. Hundreds, thousands or hundreds of thousands of atoms make up systems that are complex enough to show what is fashionably called 'emergent behaviour'. Quite new phenomena arise from rare configurations of the system. Examples are the Kramer's theory of reactions (Chapter 3), the Marcus theory of electron transfer (Chapter 8), and enzyme catalysis, molecular motors, and fluctuations in gene expression and splicing, all covered in the final Chapter on Nanobiology. The book is divided into three parts. Part I (The Basics) is a self-contained introduction to quantum mechanics, statistical mechanics and chemical kinetics, calling on no more than basic college calculus. A conceptual approach and an array of examples and conceptual problems will allow even those without the mathematical tools to grasp much of what is important. Part II (The Tools) covers microscopy, single molecule manipulation and measurement, nanofabrication and self-assembly. Part III (Applications) covers electrons in nanostructures, molecular electronics, nano-materials and nanobiology. Each chapter starts with a survey of the required basics, but ends by making contact with current research literature.

Transmission Electron Microscopy

Transmission Electron Microscopy PDF Author: C. Barry Carter
Publisher: Springer
ISBN: 3319266519
Category : Technology & Engineering
Languages : en
Pages : 543

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Book Description
This text is a companion volume to Transmission Electron Microscopy: A Textbook for Materials Science by Williams and Carter. The aim is to extend the discussion of certain topics that are either rapidly changing at this time or that would benefit from more detailed discussion than space allowed in the primary text. World-renowned researchers have contributed chapters in their area of expertise, and the editors have carefully prepared these chapters to provide a uniform tone and treatment for this exciting material. The book features an unparalleled collection of color figures showcasing the quality and variety of chemical data that can be obtained from today’s instruments, as well as key pitfalls to avoid. As with the previous TEM text, each chapter contains two sets of questions, one for self assessment and a second more suitable for homework assignments. Throughout the book, the style follows that of Williams & Carter even when the subject matter becomes challenging—the aim is always to make the topic understandable by first-year graduate students and others who are working in the field of Materials Science Topics covered include sources, in-situ experiments, electron diffraction, Digital Micrograph, waves and holography, focal-series reconstruction and direct methods, STEM and tomography, energy-filtered TEM (EFTEM) imaging, and spectrum imaging. The range and depth of material makes this companion volume essential reading for the budding microscopist and a key reference for practicing researchers using these and related techniques.

Surface and Thin Film Analysis

Surface and Thin Film Analysis PDF Author: Gernot Friedbacher
Publisher: Wiley-VCH
ISBN: 9783527320479
Category : Technology & Engineering
Languages : en
Pages : 0

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Book Description
Surveying and comparing all techniques relevant for practical applications in surface and thin film analysis, this second edition of a bestseller is a vital guide to this hot topic in nano- and surface technology. This new book has been revised and updated and is divided into four parts - electron, ion, and photon detection, as well as scanning probe microscopy. New chapters have been added to cover such techniques as SNOM, FIM, atom probe (AP),and sum frequency generation (SFG). Appendices with a summary and comparison of techniques and a list of equipment suppliers make this book a rapid reference for materials scientists, analytical chemists, and those working in the biotechnological industry. From a Review of the First Edition (edited by Bubert and Jenett) "... a useful resource..." (Journal of the American Chemical Society)

Perovskite Photovoltaics

Perovskite Photovoltaics PDF Author: Aparna Thankappan
Publisher: Academic Press
ISBN: 0128129166
Category : Technology & Engineering
Languages : en
Pages : 521

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Book Description
Perovskite Photovoltaics: Basic to Advanced Concepts and Implementation examines the emergence of perovskite photovoltaics, associated challenges and opportunities, and how to achieve broader development. Consolidating developments in perovskite photovoltaics, including recent progress solar cells, this text also highlights advances and the research necessary for sustaining energy. Addressing different photovoltaics fields with tailored content for what makes perovskite solar cells suitable, and including commercialization examples of large-scale perovskite solar technology. The book also contains a detailed analysis of the implementation and economic viability of perovskite solar cells, highlighting what photovoltaic devices need to be generated by low cost, non-toxic, earth abundant materials using environmentally scalable processes. This book is a valuable resource engineers, scientists and researchers, and all those who wish to broaden their knowledge on flexible perovskite solar cells. Includes contributions by leading solar cell academics, industrialists, researchers and institutions across the globe Addresses different photovoltaics fields with tailored content for what makes perovskite solar cells different Provides commercialization examples of large-scale perovskite solar technology, giving users detailed analysis on the implementation, technical challenges and economic viability of perovskite solar cells

Electronic Properties of Materials

Electronic Properties of Materials PDF Author: Rolf E. Hummel
Publisher: Springer
ISBN: 9401749140
Category : Technology & Engineering
Languages : en
Pages : 412

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Book Description
It is quite satisfying for an author to learn that his brainchild has been favorably accepted by students as well as by professors and thus seems to serve some useful purpose. This horizontally integrated text on the electronic properties of metals, alloys, semiconductors, insulators, ceramics, and poly meric materials has been adopted by many universities in the United States as well as abroad, probably because of the relative ease with which the material can be understood. The book has now gone through several re printing cycles (among them a few pirate prints in Asian countries). I am grateful to all readers for their acceptance and for the many encouraging comments which have been received. I have thought very carefully about possible changes for the second edition. There is, of course, always room for improvement. Thus, some rewording, deletions, and additions have been made here and there. I withstood, how ever, the temptation to expand considerably the book by adding completely new subjects. Nevertheless, a few pages on recent developments needed to be inserted. Among them are, naturally, the discussion of ceramic (high-tempera ture) superconductors, and certain elements of the rapidly expanding field of optoelectronics. Further, I felt that the readers might be interested in learning some more practical applications which result from the physical concepts which have been treated here.

Advanced Techniques for Surface Engineering

Advanced Techniques for Surface Engineering PDF Author: W. Gissler
Publisher: Springer Science & Business Media
ISBN: 940170631X
Category : Technology & Engineering
Languages : en
Pages : 402

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Book Description
Today's shortages of resources make the search for wear and corrosion resistant materials one of the most important tasks of the next century. Since the surface of a material is the location where any interaction occurs, it is that there the hardest requirements on the material are imposed: to be wear resistant for tools and bearings; to be corrosion resistant for turbine blades and tubes in the petrochemical industry; to be antireflecting for solar cells; to be decorative for architectural panels and to combine several of these properties in other applications. Surface engineering is the general term that incorporates all the techniques by which a surface modification can be accomplished. These techniques include both coating and modification of the surface by ion implantation and laser beam melting. In recent years a continuously growing number of these techniques were developed to the extent that it became more and more difficult to maintain an overlook and to understand which of these highly differentiated techniques might be applied to resolve a given surface engineering problem. A similar development is also occuring for surface characterization techniques. This volume contains contributions from renowned scientists and engineers to the Eurocourse the aim of which was to inform about the various techniques and to give a comprehensive survey of the latest development on this subject.

Handbook of Transparent Conductors

Handbook of Transparent Conductors PDF Author: David S. Ginley
Publisher: Springer Science & Business Media
ISBN: 1441916385
Category : Technology & Engineering
Languages : en
Pages : 537

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Book Description
Transparent conducting materials are key elements in a wide variety of current technologies including flat panel displays, photovoltaics, organic, low-e windows and electrochromics. The needs for new and improved materials is pressing, because the existing materials do not have the performance levels to meet the ever- increasing demand, and because some of the current materials used may not be viable in the future. In addition, the field of transparent conductors has gone through dramatic changes in the last 5-7 years with new materials being identified, new applications and new people in the field. “Handbook of Transparent Conductors” presents transparent conductors in a historical perspective, provides current applications as well as insights into the future of the devices. It is a comprehensive reference, and represents the most current resource on the subject.

Next Generation of Photovoltaics

Next Generation of Photovoltaics PDF Author: Ana Cristobal
Publisher: Springer Science & Business Media
ISBN: 3642233686
Category : Technology & Engineering
Languages : en
Pages : 362

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Book Description
This book presents new concepts for a next generation of PV. Among these concepts are: Multijunction solar cells, multiple excitation solar cells (or how to take benefit of high energy photons for the creation of more than one electron hole-pair), intermediate band solar cells (or how to take advantage of below band-gap energy photons) and related technologies (for quantum dots, nitrides, thin films), advanced light management approaches (plasmonics). Written by world-class experts in next generation photovoltaics this book is an essential reference guide accessible to both beginners and experts working with solar cell technology. The book deeply analyzes the current state-of-the-art of the new photovoltaic approaches and outlines the implementation paths of these advanced devices. Topics addressed range from the fundamentals to the description of state-of-the-art of the new types of solar cells.