Kinetics and Mechanisms of the Gas-phase Reactions of the Hydroxyl Radical with Organic Compounds PDF Download
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Author: Roger Atkinson
Publisher: American Institute of Physics
ISBN:
Category : Science
Languages : en
Pages : 270
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Book Description
Author: Roger Atkinson
Publisher: American Institute of Physics
ISBN:
Category : Science
Languages : en
Pages : 270
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Book Description
Author:
Publisher:
ISBN:
Category : Research
Languages : en
Pages : 232
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Author: N. M. Emanuel
Publisher: Elsevier
ISBN: 1483145115
Category : Science
Languages : en
Pages : 628
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Book Description
Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.
Author: V.N. Kondratiev
Publisher: Springer Science & Business Media
ISBN: 3642676081
Category : Science
Languages : en
Pages : 254
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Book Description
The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category :
Languages : en
Pages : 52
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Author:
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 1082
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Author: National Research Council (U.S.)
Publisher:
ISBN:
Category : Research grants
Languages : en
Pages : 68
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Author: Andrew Burrows
Publisher: Oxford University Press
ISBN: 0198733801
Category : Science
Languages : en
Pages : 1433
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Book Description
Chemistry3 establishes the fundamental principles of all three strands of chemistry; organic, inorganic and physical. By building on what students have learned at school, using carefully-worded explanations, annotated diagrams and worked examples, it presents an approachable introduction to chemistry and its relevance to everyday life.
Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category :
Languages : en
Pages : 60
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Book Description
Author: United States. Environmental Protection Agency. Library Systems Branch
Publisher:
ISBN:
Category : Environmental protection
Languages : en
Pages : 748
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Book Description
