An Investigation of Intermetal Oxygen Atom Transfer Reactions PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download An Investigation of Intermetal Oxygen Atom Transfer Reactions PDF full book. Access full book title An Investigation of Intermetal Oxygen Atom Transfer Reactions by CuiXia Liu. Download full books in PDF and EPUB format.
Author: CuiXia Liu
Publisher:
ISBN:
Category :
Languages : en
Pages : 107
Get Book Here
Book Description
Author: CuiXia Liu
Publisher:
ISBN:
Category :
Languages : en
Pages : 107
Get Book Here
Book Description
Author: Robert Bakhtchadjian
Publisher: Bentham Science Publishers
ISBN: 9815050931
Category : Science
Languages : en
Pages : 137
Get Book Here
Book Description
This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Author: Robert Bakhtchadjian
Publisher: Chemical Reaction Mechanisms
ISBN: 9789815050943
Category : Science
Languages : en
Pages : 0
Get Book Here
Book Description
This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Author: Diana Elisabeth Over
Publisher:
ISBN:
Category : Chlorine
Languages : en
Pages : 252
Get Book Here
Book Description
Author: Arlene Feay Ghiron
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 236
Get Book Here
Book Description
Author: Anke Sieker
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Get Book Here
Book Description
Author: Anke Sieker
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: Jinheung Kim
Publisher:
ISBN:
Category :
Languages : en
Pages : 580
Get Book Here
Book Description
Author: Mark Richard Bray
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: Ying Wang
Publisher:
ISBN:
Category :
Languages : en
Pages : 230
Get Book Here
Book Description
In the case of oxygen atom transfer reaction between tert-butyl hydroperoxide and sulfide catalyzed by Re(V) dithiolato compounds, an induction period is observed due to the slow ligand exchange step. Reaction schemes are proposed to interpret the kinetic data. In both cases, the active intermediates are Re(VII) dioxo species, which were detected at the low temperature. Organic disulfides with both alkyl and aryl substituents are oxidized by hydrogen peroxide when CH3ReO33 (MTO) is used as a catalyst. Thiosulfinate is formed in the first step about an hour with nearly quantitative yield. Kinetics studies of the first oxidation reaction established that two peroxorhenium compounds are the active forms of the catalyst. Rate constants were obtained and a mechanism was proposed in which the electron-rich sulfur attacks the peroxo oxygen of intermediates.
