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ISBN:
Category :
Languages : en
Pages : 1157
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 1157
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Author: Satya Prakash et al.
Publisher: S. Chand Publishing
ISBN: 9788121917872
Category : Science
Languages : en
Pages : 680
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Book Description
Advanced Inorganic Chemistry - Volume II is a concise book on basic concepts of inorganic chemistry. Beginning with Coordination Chemistry, it presents a systematic treatment of all Transition and Inner-Transition chemical elements and their compounds according to the periodic table. Special topics such as Pollution and its adverse effects, chromatography, use of metal ions in biological systems, to name a few, are discussed to provide additional relevant information to the students. It primarily caters to the undergraduate courses (Pass and Honours) offered in Indian universities.
Author: Narayan S. Hosmane
Publisher: Academic Press
ISBN: 012801993X
Category : Science
Languages : en
Pages : 278
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Book Description
Advanced Inorganic Chemistry: Applications in Everyday Life connects key topics on the subject with actual experiences in nature and everyday life. Differing from other foundational texts with this emphasis on applications and examples, the text uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes. From this foundation, the text explores more advanced topics, such as: Ligands and Ligand Substitution Processes with an emphasis on Square-Planar Substitution and Octahedral Substitution Reactions in Inorganic Chemistry and Transition Metal Complexes, with a particular focus on Crystal-Field and Ligand-Field Theories, Electronic States and Spectra and Organometallic, Bioinorganic Compounds, including Carboranes and Metallacarboranes and their applications in Catalysis, Medicine and Pollution Control. Throughout the book, illustrative examples bring inorganic chemistry to life. For instance, biochemists and students will be interested in how coordination chemistry between the transition metals and the ligands has a direct correlation with cyanide or carbon monoxide poisoning (strong-field Cyanide or CO ligand versus weak-field Oxygen molecule). - Engaging discussion of key concepts with examples from the real world - Valuable coverage from the foundations of chemical bonds and stereochemistry to advanced topics, such as organometallic, bioinorganic, carboranes and environmental chemistry - Uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes
Author: Satya Prakash et al.
Publisher: S. Chand Publishing
ISBN: 9788121902632
Category : Science
Languages : en
Pages : 1432
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Book Description
Advanced Inorganic Chemistry - Volume I is a concise book on basic concepts of inorganic chemistry. It acquaints the students with the basic principles of chemistry and further dwells into the chemistry of main group elements and their compounds. It primarily caters to the undergraduate courses (Pass and Honours) offered in Indian universities.
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 482
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Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: F. Albert Cotton
Publisher: John Wiley & Sons
ISBN: 0471199575
Category : Science
Languages : en
Pages : 1380
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Book Description
For more than a quarter century, Cotton and Wilkinson's Advanced Inorganic Chemistry has been the source that students and professional chemists have turned to for the background needed to understand current research literature in inorganic chemistry and aspects of organometallic chemistry. Like its predecessors, this updated Sixth Edition is organized around the periodic table of elements and provides a systematic treatment of the chemistry of all chemical elements and their compounds. It incorporates important recent developments with an emphasis on advances in the interpretation of structure, bonding, and reactivity.“/p> From the reviews of the Fifth Edition: "The first place to go when seeking general information about the chemistry of a particular element, especially when up-to-date, authoritative information is desired." —Journal of the American Chemical Society "Every student with a serious interest in inorganic chemistry should have [this book]." —Journal of Chemical Education "A mine of information . . . an invaluable guide." —Nature "The standard by which all other inorganic chemistry books are judged." —Nouveau Journal de Chimie "A masterly overview of the chemistry of the elements." —The Times of London Higher Education Supplement "A bonanza of information on important results and developments which could otherwise easily be overlooked in the general deluge of publications." —Angewandte Chemie
Author:
Publisher: Krishna Prakashan Media
ISBN: 9788187224037
Category :
Languages : en
Pages : 1480
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Book Description
Author: Frank Albert Cotton
Publisher:
ISBN: 9789354245701
Category : Chemistry, Inorganic
Languages : en
Pages : 0
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Book Description
"Advanced inorganic chemistry is a well-established source that students and professional chemists have turned to for the background needed to understand current research literature in inorganic chemistry and aspects of organometallic chemistry. This textbook is organized around the periodic table of elements and provides a systematic treatment of the chemistry of all chemical elements and their compounds. It incorporates important recent developments with an emphasis on advances in the interpretation of structure, bonding, and reactivity. This Indian adaptation of the book is restructured at places and offers new and updated material on chemical elements and their compounds, particularly related to their applications. The introduction section in all the chapters has also been completely updated to reflect current developments. Some of the new topics covered include sections on nomenclature and isomerism in coordination compounds; hydrides, their classification and applications. Useful new inclusions in the book are practice exercise comprising review questions multiple-choice questions (based on various competitive examinations) at the end of each part and appendices on IUPAC nomenclature of complexes and latimer diagram" -- Cover.
Author: R. John Errington
Publisher: CRC Press
ISBN: 9780751402254
Category : Science
Languages : en
Pages : 312
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Book Description
While the boundaries between the areas of chemistry traditionally labeled as inorganic, organic and physical are gradually diffusing, the practical techniques adopted by workers in each of these areas are often radically different. The breadth and variety of research classed as "inorganic chemistry" is readily apparent from an inspection of some of the leading international journals, and can be quite daunting for newcomers to this domain who are likely to have only limited experience of the methodologies involved. This book has therefore been written to provide guidance for those unfamiliar with the techniques most often encountered in synthetic inorganic / metalorganic chemistry, with an emphasis on procedures for handling air-sensitive compounds. One chapter is devoted to more specialized techniques such as metal vapor synthesis, and a review of preparative methods for a selection of starting materials is included as an aid to those planning research projects. While this book is aimed primarily at postgraduate and advanced undergraduate students involved in inorganic research projects, synthetic organic chemists and industrial chemists will also find much useful information within its pages. Similarly, it serves as a useful reference source for materials and polymer scientists who wish to take advantage of recent progress in precursor synthesis and catalyst development.
Author: Robert R. Crichton
Publisher: Elsevier
ISBN: 0080556221
Category : Science
Languages : en
Pages : 383
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Book Description
The importance of metals in biology, the environment and medicine has become increasingly evident over the last twenty five years. The study of the multiple roles of metal ions in biological systems, the rapidly expanding interface between inorganic chemistry and biology constitutes the subject called Biological Inorganic Chemistry. The present text, written by a biochemist, with a long career experience in the field (particularly iron and copper) presents an introduction to this exciting and dynamic field. The book begins with introductory chapters, which together constitute an overview of the concepts, both chemical and biological, which are required to equip the reader for the detailed analysis which follows. Pathways of metal assimilation, storage and transport, as well as metal homeostasis are dealt with next. Thereafter, individual chapters discuss the roles of sodium and potassium, magnesium, calcium, zinc, iron, copper, nickel and cobalt, manganese, and finally molybdenum, vanadium, tungsten and chromium. The final three chapters provide a tantalising view of the roles of metals in brain function, biomineralization and a brief illustration of their importance in both medicine and the environment.Relaxed and agreeable writing style. The reader will not only fiind the book easy to read, the fascinating anecdotes and footnotes will give him pegs to hang important ideas on.Written by a biochemist. Will enable the reader to more readily grasp the biological and clinical relevance of the subject.Many colour illustrations. Enables easier visualization of molecular mechanismsWritten by a single author. Ensures homgeneity of style and effective cross referencing between chapters
