A Study of NOx̲ Production in Sooty Radiating Counterflow Diffusion Flames PDF Download
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Author: Han-Kyoo Kim
Publisher:
ISBN:
Category :
Languages : en
Pages : 580
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Book Description
Author: Han-Kyoo Kim
Publisher:
ISBN:
Category :
Languages : en
Pages : 580
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
The formation of NO and NO2 are sensitive indicators of both temperature and residence time. In this work, the NOx emission index is measured in an unsteady counterflow diffusion flame for methane, propane and ethylene, as a function of average strain rate and amplitude and frequency of imposed sinusoidal oscillation. The flames studied vary from non-sooting to high soot loading, and from low average strain rate to near extinction. Due to the relatively long time scales associated with NOx formation, the effect of unsteadiness on emission index is weaker than on either temperature or soot volume fraction. Time average global measurements were taken using a California Analytical Instruments Model 400 HCLD NO/NOx analyzer. Results are compared with unsteady calculations using a modified OPPDIF code included in the Chemkin package.
Author: Christopher Dwayne DeBruhl
Publisher:
ISBN:
Category :
Languages : en
Pages : 67
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Book Description
Keywords: Counterflow diffusion flames Nox.
Author: Richard L. Axelbaum
Publisher:
ISBN:
Category :
Languages : en
Pages : 510
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Author: Tariq Shamim
Publisher:
ISBN:
Category :
Languages : en
Pages : 382
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Author: Harjit Singh Hura
Publisher:
ISBN:
Category :
Languages : en
Pages : 522
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Book Description
Author: Keunchul Lee
Publisher:
ISBN:
Category : Combustion
Languages : en
Pages : 276
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Book Description
Author: Charles E. Baukal Jr.
Publisher: CRC Press
ISBN: 1439862303
Category : Science
Languages : en
Pages : 779
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Book Description
Combustion technology has traditionally been dominated by air/fuel combustion. However, two developments have increased the significance of oxygen-enhanced combustion-new technologies that produce oxygen less expensively and the increased importance of environmental regulations. Advantages of oxygen-enhanced combustion include less pollutant emissi
Author: H. Yamashita
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages : 2
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Author: Kevin Wan
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Increasingly strict regulations on NOx and soot emissions from combustion systems drives the need to develop strategies to reduce them. One such strategy is to reduce them at the source. A basic understanding about how they form and how to properly characterize them is critical to improved combustion system design. In this dissertation, NOx formation is studied experimentally and numerically for a typical jet fuel. Characterization of soot by transmission electron microscopy and optical diagnostics is reevaluated here. The dissertation presents findings with new implications on the suitability on the use of these techniques to study soot. Reliable NOx data in stagnation flames of a typical jet fuel is presented here. The predictive capability for NOx is tested by combining a HyChem model with a NOx submodel. NOx formation is measured in premixed stagnation flames of methane, ethylene and Jet A (POSF10325). The experimental data and model predictions show reasonably good agreement. However, the model appears to underpredict NOx formation in the fuel-rich Jet A flames. Additional prompt NO reaction pathways not yet accounted for may play a role in flames of large hydrocarbons. Transmission electron microscopy imaging of nascent soot was carried out to observe and quantify the annealing of soot samples under continuous irradiation of the high-energy electron beam. Soot samples are imaged in 2 minute intervals over a duration of 16 minutes. The structural transformation is visually unambiguous. The sensitivity of the fringe properties to the apparent changes in the nanostructures imaged is examined. The difficulties in quantifying soot composition through TEM are further illustrated by analyzing simulated images of molecular-dynamics generated particles. Together, the results highlight the difficulties in using electron microscopy to reliably quantify structural properties for nascent soot particles. Quantum confinement is examined in the ionization energy and optical band gap of soot nanoparticles over the range of 4-23 nm in volume median diameter. The results reveal that soot nanoparticles behave like an indirect band gap material due to the electronic structure of the aromatic molecules comprising the soot nanoparticles. Both the ionization energy and optical band gap are found to follow the quantum confinement effect closely. Cyclic voltammetry measurements and density functional theory calculations provide additional support for the quantum dot behavior observed. A model for the refractive index of nascent soot particles is proposed over the wavelength range of 185 - 1400 nm. The refractive index of soot is shown to depend on the primary particle size for the first time. The refractive indices evaluated for large soot particles are in close agreement with literature values in the visible spectrum. The imaginary component is strongly sensitive to the particle size, deviating significantly from literature values at wavelengths > 700 nm and particle sizes ~ 15 nm in diameter. This highlights the need to account for the size effect in the refractive index in optical diagnostics of soot in flames, with implications on earlier extinction and scattering measurements of flame soot during the early stage of soot growth.
