A New Route to the Synthesis of Organic Phosphorus Compounds PDF Download
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Author: Warren Leon Jensen
Publisher:
ISBN:
Category : Phosphorus compounds
Languages : en
Pages : 200
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Book Description
Author: Warren Leon Jensen
Publisher:
ISBN:
Category : Phosphorus compounds
Languages : en
Pages : 200
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Book Description
Author: Oleg I. Kolodiazhnyi
Publisher: John Wiley & Sons
ISBN: 3527613919
Category : Science
Languages : en
Pages : 568
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Book Description
When Wittig first developed and described phosphorus ylides, nobody could have imagined how useful and versatile this class of compounds could be. This book provides a comprehensive and up-to-date compilation of the chemistry and applications of phosphorus ylides in organic synthesis. The ylides are discussed as reagents in the synthesis of a broad range of substances, amongst them olefins, acetylenes, cyclic and heterocyclic compounds, in such naturally occurring compounds as pheromones, steroids and carotenoids, and pharmaceutically and biologically active compounds such as antibiotics and prostaglandins. A particularly beneficial feature of this book is the 150 key experimental procedures with all the necessary data, allowing the preparation to start immediately without the need for an extremely time-consuming literature search. But should a search prove inevitable, around 2,500 references provide easy access to the primary literature. Every chemist in academia and industry working in organic, bioorganic, inorganic, and medicinal chemistry will welcome this book as an inspiration of concepts, ideas and practical syntheses.
Author: T. Henshall
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Robert Engel
Publisher: CRC Press
ISBN: 0203998243
Category : Science
Languages : en
Pages : 200
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Book Description
Synthesis of Carbon-Phosphorus Bonds, Second Edition is a working guide for the laboratory, incorporating classical approaches with the recent developments of carbon-phosphorus (C-P) bond formation. These advances include the preparation of phosphoranes - specifically in the use of transient oxophosphoranes as intermediates in organophosphorus comp
Author: Stanford University
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1266
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Book Description
Author: Kolio D. Troev
Publisher: Academic Press
ISBN: 0128138351
Category : Science
Languages : en
Pages : 465
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Book Description
Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification. - Describes the diverse reactivity of the phosphorus-hydrogen group, perhaps the most powerful in organic chemistry - Includes practical information for the synthesis of catalysts, biologically active substances, flame retardants, advance materials and polymer materials - Offers a visually-accessible guide to important reactions by an internationally recognized chemist
Author: Edward Chang
Publisher:
ISBN:
Category :
Languages : en
Pages : 176
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Book Description
Author: Louis D. Quin
Publisher: John Wiley & Sons
ISBN: 9780471318248
Category : Science
Languages : en
Pages : 416
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Book Description
Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)
Author: Robert Engel
Publisher: CRC Press
ISBN: 1482277247
Category : Science
Languages : en
Pages : 896
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Book Description
This practical work summarizes the development of organophosphorus chemistry in topical areas and details the discipline's current state - providing applications and experimental procedures throughout.;Written by 18 leading authorities in the field, the Handbook of Organophosphorus Chemistry: examines advances in the mechanistic understanding of th
Author: Xuanshu Xia
Publisher: Open Dissertation Press
ISBN: 9781361371367
Category :
Languages : en
Pages :
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Book Description
This dissertation, "Development of phosphorus-mediated reactions in organic synthesis / y Xia Xuanshu, B. Sc., Sun Yat-sen U" by Xuanshu, Xia, 夏轩庶, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Polymer-supported catalysts and reagents have been widely used in organic chemistry because they could facilitate the purification procedures and usually be recycled. Much research has been directed to polymer-supported catalysts and reagents, mainly focusing on these aspects, such as new polymer support, new application in organic chemistry, different modifications and so on. Many polymer-supported phosphine reagents have been developed for Wittig reaction. However, most of them suffer from swelling issue or low loading. A new polyethlyeneimine-supported triphenylphosphine has been synthesized and used as a highly loaded bifunctional homogeneous reagent in a range of one-pot Wittig reactions. All the substrates afforded desired products in high yields after only simple purification procedures. Furthermore, it also served efficiently in reaction cascades involving a one-pot Wittig reaction followed by conjugate reduction of alkene products. In these transformations the phosphine oxide generated in Wittig reaction served as the catalyst for activating trichlorosilane in the subsequent reduction reaction. Triphenylphosphine oxide is always considered as a byproduct of Wittig and Mitsunobu reactions which complicates the purification procedures. One option to utilize it is its application in halogenation reaction with oxalyl halide. Heterogeneous polymer-supported triphenylphosphine oxides based on the rasta resin architecture have been synthesized, and applied as reagent precursors in a wide range of halogenation reactions. The rasta resin-triphenylphosphine oxides reacted with either oxalyl chloride or oxalyl bromide to form the corresponding halophosphonium salts, and these in turn reacted with alcohols, aldehydes, aziridines and epoxides to form halogenated products in high yields after simple purification. The polymer-supported triphenylphosphine oxides formed as a byproduct during these reactions could be recovered and reused numerous times with no appreciable decrease in reactivity. Another option is to use triphenylphosphine oxide as catalyst in organic synthesis. A highly regioselective 1,4-reduction of conjugated polyunsaturated ketones catalyzed by triphenylphosphine oxide is described. In the presence of triphenylphosphine oxide, conjugated di-, tri-, and tetraenones were selectively α,β-reduced using trichlorosilane without over reduction or isomerization, and all the substrates rendered desired products in high yields. Furthermore, 1,4-reduction products were successfully obtained in sequential one-pot Wittig/conjugate reduction reaction, triphenylphosphine oxide generated in Wittig reaction served as the catalyst for reduction reaction. In addition, natural moth pheromones and their analogues were synthesized in high yields using this method. Finally, the synthesis of γ-sanshool and hydroxy-γ-sanshool is depicted. The synthetic route started from simple and commercially available building blocks using an alkyne for E, E-2,4-diene group of the key synthetic intermediate 2E,4E,8Z,10E,12E-tetradecapentaenoic acid, which in turn was converted into both γ-sanshool and hydroxy-γ-sanshool by reaction with the appropriate amines. DOI: 10.5353/th_b5435655 Subjects: Supported reagents Polymers
