A Guide to Organophosphorus Chemistry PDF Download
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Author: Louis D. Quin
Publisher: John Wiley & Sons
ISBN: 9780471318248
Category : Science
Languages : en
Pages : 416
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Book Description
Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)
Author: Louis D. Quin
Publisher: John Wiley & Sons
ISBN: 9780471318248
Category : Science
Languages : en
Pages : 416
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Book Description
Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)
Author: Dr. Patrick J. Murphy
Publisher: Practical Approach in Chemistr
ISBN: 9780198502623
Category : Science
Languages : en
Pages : 296
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Book Description
Organophosphorus Chemistry: A Practical Approach in Chemistry provides a practical introduction to the field by mixing a brief review of the subject area with key experimental details and sample procedures. Phosphorus is an element that has been central to the development of our modern way of life. Its chemistry plays a key role in the development of such important areas as pharmaceuticals, agrochemicals, modern materials and molecular biology. Much of this work requires a sound understanding of the organic chemistry of phosphorus and this volume is designed to instruct the reader in the essential methodology used. Topics covered include phosphines, applications of phosphorus (III) and (V) compounds as reagents in synthesis, the chemistry of phosphorus ylides, applications of the Wittig reaction in the synthesis of heterocyclic and carbocyclic compounds, preparation of Iminophosphoranes and their synthetic applications in the aza-Wittig reaction, phospho-transfer processes leading to [P-C] bond formation, low valent phosphorus compounds and phosphorus methods in oligonucleotide chemistry. It is intended not only for the specialist in organophosphorus chemistry, but also for the organic chemist with little experience in the field who wishes to add phophorus-based techniques to his or her ensemble of synthetic methods.
Author: György Keglevich
Publisher: MDPI
ISBN: 3039282360
Category : Science
Languages : en
Pages : 602
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Book Description
Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik–Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge. Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses, solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry.
Author: Alwyn G. Davies
Publisher: John Wiley & Sons
ISBN: 3527606319
Category : Science
Languages : en
Pages : 438
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Book Description
At long last: The second, completely revised edition of this comprehensive standard reference. Alwyn G. Davies has updated the contents of his book to reflect the current state of research into organotin chemistry. He covers all aspects in detail, such as its synthesis, characterization, structures and applications, while also devoting space to such hot topics as environmental issues. This new edition also includes a CD-ROM with more than 5,000 references, making this database an invaluable tool for everyone working in the field. "The text is well written, extremely accessible and very comprehensive: particularly impressive is the inclusion of up-to-the-minute references in these areas...." - Advanced Materials, 13 (1998) "The standard of production is very good, with well-structured tables and an abundance of clear formula schemas, which enable the reader to quickly grasp the essence of the text." - Angewandte Chemie 16, 1997
Author: Robert Engel
Publisher: CRC Press
ISBN: 0203998243
Category : Science
Languages : en
Pages : 200
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Book Description
Synthesis of Carbon-Phosphorus Bonds, Second Edition is a working guide for the laboratory, incorporating classical approaches with the recent developments of carbon-phosphorus (C-P) bond formation. These advances include the preparation of phosphoranes - specifically in the use of transient oxophosphoranes as intermediates in organophosphorus comp
Author: Kolio D. Troev
Publisher: Academic Press
ISBN: 0128138351
Category : Science
Languages : en
Pages : 465
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Book Description
Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification. - Describes the diverse reactivity of the phosphorus-hydrogen group, perhaps the most powerful in organic chemistry - Includes practical information for the synthesis of catalysts, biologically active substances, flame retardants, advance materials and polymer materials - Offers a visually-accessible guide to important reactions by an internationally recognized chemist
Author: Viktor Iaroshenko
Publisher: John Wiley & Sons
ISBN: 3527335722
Category : Science
Languages : en
Pages : 586
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Book Description
Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.
Author: Roger L. Lundblad
Publisher: CRC Press
ISBN: 1439849005
Category : Medical
Languages : en
Pages : 422
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Book Description
Examining the chemical modification of biological polymers and the emerging applications of this technology, Chemical Modification of Biological Polymers reflects the change in emphasis in this subsection of biotechnology from the study of protein structure and function toward applications in therapeutics and diagnostics. HighlightsThe basic organi
Author: D.E.C. Corbridge
Publisher: CRC Press
ISBN: 1439840881
Category : Science
Languages : en
Pages : 1476
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Book Description
Over two decades have passed since the fifth edition of Phosphorus: Chemistry, Biochemistry and Technology. Major advances in chemistry, materials science, electronics, and medicine have expanded and clarified the role of phosphorus in both our everyday appliances and groundbreaking research. Significantly expanded, updated, and reorganized, this sixth edition organizes and explains vital phosphorus research and relevant information available in highly specialized reviews and references on select related topics. An authoritative and comprehensive review of phosphorus chemistry and related technology, Phosphorus: Chemistry, Biochemistry and Technology covers historical, academic, industrial, agricultural, military, biological, and medical aspects of phosphorous. Furthermore, it offers a starting point for more extended studies of the highly specialized branches of phosphorus chemistry. Although this book deals with a small fraction of the > 106 known phosphorus compounds, it thoroughly covers the simpler derivatives and most key compounds of economic, sociological, and biological importance. Extensively updated and expanded with tables, figures, equations, structural formulae, and references, it is ideal for scientists in related fields seeking a rapid introduction to phosphorus chemistry.
Author: Ian Fairlamb
Publisher: Royal Society of Chemistry
ISBN: 1788012208
Category : Science
Languages : en
Pages : 171
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Book Description
With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. This interdisciplinary field has the potential to provide answers to problems and challenges faced in catalysis, synthetic organic chemistry and the development of therapeutic agents and new materials. Providing an invaluable volume, Organometallic Chemistry Volume 41 contains analysed, evaluated and distilled information on the latest in organometallic chemistry research including developments and applications of Lewis acidic boron reagents, masked low-coordinate main group species in synthesis and the diiron centre.
