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Author:
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ISBN:
Category :
Languages : en
Pages : 616
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Author:
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ISBN:
Category :
Languages : en
Pages : 616
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Author:
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ISBN:
Category : Chemistry
Languages : en
Pages : 280
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Author: Wolfgang Linert
Publisher: Springer Science & Business Media
ISBN: 3709161517
Category : Science
Languages : en
Pages : 224
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Book Description
Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance.
Author: National Science Foundation (U.S.)
Publisher:
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Category : Federal aid to research
Languages : en
Pages : 256
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Author:
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Category : Nuclear energy
Languages : en
Pages : 828
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Author: CAJ Paulson
Publisher: CSIRO PUBLISHING
ISBN: 0643105727
Category : Technology & Engineering
Languages : en
Pages : 1373
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Book Description
The control of greenhouse gas emissions continues to be a major global problem. It is inter-disciplinary, both in substance and approach, and covers technical, political and economic issues involving governments, industry and the scientific community. These proceedings contain 220 papers presented at the 5th International Conference on Greenhouse Gas Control Technologies (GHGT-5) held in August 2000 at Cairns, Queensland, Australia. The papers cover the capture of carbon dioxide, geological storage of carbon dioxide, ocean storage of carbon dioxide, storage of carbon dioxide with enhanced hydrocarbon recovery, utilisation of carbon dioxide, other greenhouse gases, fuel cells, alternative energy carriers, energy efficiency, life cycle assessments and energy modelling, economics, international and national policy, trading and accounting policy, social and community issues, and reducing emission from industry and power generation.
Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: International Society of Soil Science
Publisher:
ISBN:
Category : Soil science
Languages : en
Pages : 592
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Category : Power resources
Languages : en
Pages : 396
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Author:
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ISBN:
Category : Congresses and conventions
Languages : en
Pages : 388
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