Transport, Relaxation, and Kinetic Processes in Electrolyte Solutions PDF Download
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Author: Pierre Turq
Publisher: Springer Science & Business Media
ISBN: 3642487556
Category : Science
Languages : en
Pages : 222
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Book Description
The presence of freely moving charges gives peculiar properties to electrolyte solutions, such as electric conductance, charge transfer, and junction potentials in electrochemical systems. These charges play a dominant role in transport processes, by contrast with classical equilibrium thermodynamics which considers the electrically neutral electrolyte compounds. The present status of transport theory does not permit a first prin ciples analys1s of all transport phenomena with a detailed model of the relevant interactions. Host of the models are still unsufficient for real systems of reasonable complexity. The Liouville equation may be adapted with some Brownian approximations to problems of interact ing solute particles in a continuum (solvent>; however, keeping the Liouville level beyond the limiting laws is an unsolvable task. Some progress was made at the Pokker-Planck level; however, despite a promising start, this theory in its actual form is still unsatis factory for complex systems involving many ions and chemical reac tions. A better approach is provided by the so-called Smoluchowski level in which average velocities are used, but there the hydrodyna mic interactions produce some difficulties. The chemist or chemical engineer, or anyone working with complex electrolyte solutions in applied research wants a general representa tion of the transport phenomena which does not reduce the natural complexity of the multicomponent systems. Reduction of the natural complexity generally is connected with substantial changes of the systems.
Author: Pierre Turq
Publisher: Springer Science & Business Media
ISBN: 3642487556
Category : Science
Languages : en
Pages : 222
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Book Description
The presence of freely moving charges gives peculiar properties to electrolyte solutions, such as electric conductance, charge transfer, and junction potentials in electrochemical systems. These charges play a dominant role in transport processes, by contrast with classical equilibrium thermodynamics which considers the electrically neutral electrolyte compounds. The present status of transport theory does not permit a first prin ciples analys1s of all transport phenomena with a detailed model of the relevant interactions. Host of the models are still unsufficient for real systems of reasonable complexity. The Liouville equation may be adapted with some Brownian approximations to problems of interact ing solute particles in a continuum (solvent>; however, keeping the Liouville level beyond the limiting laws is an unsolvable task. Some progress was made at the Pokker-Planck level; however, despite a promising start, this theory in its actual form is still unsatis factory for complex systems involving many ions and chemical reac tions. A better approach is provided by the so-called Smoluchowski level in which average velocities are used, but there the hydrodyna mic interactions produce some difficulties. The chemist or chemical engineer, or anyone working with complex electrolyte solutions in applied research wants a general representa tion of the transport phenomena which does not reduce the natural complexity of the multicomponent systems. Reduction of the natural complexity generally is connected with substantial changes of the systems.
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 0306455544
Category : Science
Languages : en
Pages : 814
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Book Description
This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.
Author: Josef Barthel
Publisher: Springer Science & Business Media
ISBN: 9783798510760
Category : Science
Languages : en
Pages : 434
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Book Description
The aim and purpose of this book is a survey of our actual basic knowledge of electrolyte solutions. It is meant for chemical engineers looking for an introduction to this field of increasing interest for various technologies, and for scientists wishing to have access to the broad field of modern electrolyte chemistry.
Author: Andrew Agnew
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Georgiĭ Georgievich Aseev
Publisher: Begell House Publishers
ISBN: 9781567001044
Category : Science
Languages : en
Pages : 549
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Book Description
This book is another in a series of works by this author dealing with studies, representation, and methods of calculation of physicochemical properties of binary and multicomponent electrolyte solutions. A vast amount of data is presented here that will be invaluable to scientific workers and engineers in the chemical and allied industries. Methods for calculation of the dynamic viscosities of multicomponent solutions with minimum error are given. Related equations for calculation of the densities of multicomponent solutions, the viscosity of water at the saturation line in the temperature range from zero to 150 degrees C, and the density of water at the saturation line in the temperature range from zero to 500 degrees C and the pressure range from one to 1,000 Mpa are also analyzed.
Author: Satish K. Jalota
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: W. Jakubetz
Publisher: Springer Science & Business Media
ISBN: 3642565115
Category : Science
Languages : en
Pages : 206
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Book Description
Methods in Reaction Dynamics is a collection of lectures given at the 1999 Mariapfarr Workshop in Theoretical Chemistry. Arranged as a series of detailed reviews, it provides an overview of quantum mechanical techniques used to describe and simulate the dynamics and kinetics of elementary chemical reactions. The volume provides in-depth discussions of selected topics in Theoretical Chemistry, such as quantum methods in theoretical and computational reaction dynamics and kinetics; time-dependent, time-independent and mixed quantum-classical techniques. Some of the topics have not been reviewed before in detail.
Author: Timothy S. Margulies
Publisher: Xlibris Corporation
ISBN: 1462802389
Category : Science
Languages : en
Pages : 157
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Book Description
A derivation of the averaged balance equations of fluid mechanics is presented including compressibility with alternative equations of state, viscous and thermal dissipation contributions, stream tube end boundary motion, and chemical reaction. Explicit utilization of the energy equation, or enthalpy equation in combination with the linear momentum and mass balances is investigated. Both the vorticity and Bernouilli equations are provided in alternative forms with thermodynamic energy assumptions to be used in engineering analysis and to discern assumptions.
Author:
Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 1812
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Book Description
Author: William S. Price
Publisher: Cambridge University Press
ISBN: 1139476106
Category : Science
Languages : en
Pages : 417
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Book Description
Translational motion in solution, either diffusion or fluid flow, is at the heart of chemical and biochemical reactivity. Nuclear Magnetic Resonance (NMR) provides a powerful non-invasive technique for studying the phenomena using magnetic field gradient methods. Describing the physical basis of measurement techniques, with particular emphasis on diffusion, balancing theory with experimental observations and assuming little mathematical knowledge, this is a strong, yet accessible, introduction to the field. A detailed discussion of magnetic field gradient methods applied to Magnetic Resonance Imaging (MRI) is included, alongside extensive referencing throughout, providing a timely, definitive book to the subject, ideal for researchers in the fields of physics, chemistry and biology.
