Transition Metals in the Synthesis of Complex Organic Molecules PDF Download
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Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9781891389047
Category : Science
Languages : en
Pages : 358
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Book Description
This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9781891389047
Category : Science
Languages : en
Pages : 358
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Book Description
This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Author: Peter J. Harrington
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 520
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Book Description
Examines the use of transition metal complexes as reagents for the synthesis of complex organic molecules. Presented here are total syntheses whose efficiency depends upon the unique reactivity patterns of organometallic complexes. For each total synthesis, the biological activity of the molecule is presented, followed by discussion of the principles of the organometallic processes involved.
Author: H.M. Colquhoun
Publisher: Springer Science & Business Media
ISBN: 1461326516
Category : Science
Languages : en
Pages : 459
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Book Description
The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.
Author: Roderick Bates
Publisher: John Wiley & Sons
ISBN: 1119978939
Category : Science
Languages : en
Pages : 5
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Book Description
Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.
Author: S. G. Davies
Publisher: Elsevier
ISBN: 1483285847
Category : Science
Languages : en
Pages : 430
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Book Description
Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.
Author: Jiro Tsuji
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 220
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Book Description
In 1970 I wrote a review article for "Topics in Current Chemistry", surveying the general reaction patterns of transition-metal complexes from the standpoint of organic synthesis. The article seems to have evoked wide interest, and I therefore thought it appropriate to treat the subject more comprehensively in the form of a monograph. Organometallic chemistry is a rapidly growing field of intensive research. In this field, the application of organometallic compounds to organic synthesis is an important subject and many unique synthetic methods have been discovered, especially in the last decade. Syntheses using transition-metal com pounds are now in the foreground of organic chemistry. The purpose of this monograph is to give a bird's-eye view of this field to both organic and inorganic chemists through a mechanistic approach. A systematic unification of the voluminous data accumulated in this field is now urgently required. This subject is discussed by classifying various reactions into general patterns and by illustrating them with a limited number of pertinent examples.
Author: Susan E. Gibson
Publisher: Oxford University Press, USA
ISBN:
Category : Electronic books
Languages : en
Pages : 264
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Book Description
This volume is designed to disseminate practical expertise in this important and demanding area of chemistry to undergraduate and postgraduate students in universities and to researchers working in the chemical industry. The authors have considerable practical and teaching experience in theareas they cover. Topics include transition metal-promoted oxidations, palladium-catalysed carbon-carbon bond formation, ferrocene chemistry, applications of organoiron complexes in organic synthesis, applications of titanocene and zirconocene complexes in organic synthesis and arene chromiumtricarbonyl chemistry.
Author: A. Noels
Publisher: Springer Science & Business Media
ISBN: 9401134081
Category : Science
Languages : en
Pages : 375
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Book Description
The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover, more and more chemicals, especially pharmaceuticals, have to be sold in an optically active form. The search for selectivity constitutes a tremendous challenge for the chemists. In the last two decades, homogeneous transition metal based catalysis has emerged as one of the most promising tools for obtaining selectivity. In connection with developments in this area, this book contains updated and expanded versions of most of the lectures presented at a Cornett course held in Trieste (Italy) in 1989 and sponsored by the European Community. A primary aim is to cultivate a deeper understanding of the parameters that govern the selectivities and stimulate a wider utilization of transition metal based catalysis in organic synthesis. All aspects of selectivity, chemo-, regio-, stereo- and enantioselectivity are considered and illustrated by applications in various fields or organic synthesis. The impact of catalysis in oxydation, reduction, carbonylation reactions, carbene chemistry, in Ni and Pd promoted dimerizations, oligomerizations as well as fonctionalisations is stressed, quite often with special emphasis laid on reaction mechanisms. In this aspect, the last chapter examplifies the interest of high pressure NMR and IR when investigating the nature of reaction intermediates in homogeneous reactions.
Author: L. Brandsma
Publisher: Springer Science & Business Media
ISBN: 3642603289
Category : Science
Languages : en
Pages : 349
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Book Description
Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.
Author: Howard Alper
Publisher: Academic Press
ISBN: 148321592X
Category : Science
Languages : en
Pages : 200
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Book Description
Transition Metal Organometallics in Organic Synthesis, Volume II covers chapters on the applications of arene and alkyne complexes, as well as cluster compounds, in organic synthesis. The book discusses the potential utility of transition metal-alkyne complexes and derived cluster compounds as reagents in organic synthesis, as well as the complexation reactions of arenes. The text also describes the oxidation, reduction, rearrangement, and other synthetically useful processes. Chemists will find the book invaluable.
