Author: Zhiqun Lin
Publisher: Royal Society of Chemistry
ISBN: 1788014707
Category : Science
Languages : en
Pages : 330
Book Description
This book summarises the significant progress made in organic thermoelectric materials, focusing on effective routes to minimize thermal conductivity and maximize power factor.
Organic Thermoelectric Materials
Thin Film and Flexible Thermoelectric Generators, Devices and Sensors
Author: Sergey Skipidarov
Publisher: Springer Nature
ISBN: 3030458628
Category : Technology & Engineering
Languages : en
Pages : 306
Book Description
This book presents and facilitates new research and development results with hot topics in the thermoelectric generators (TEGs) field. Topics include: novel thin film; multilayer, composite and nanostructured thermoelectric materials; simulation of phenomena related to thermoelectricity; thermoelectric thin film and multilayer materials manufacturing technologies; measurement techniques for characterization; thermoelectric generators; and the simulation, modeling, design, thermal, and mechanical degradation problems. This book helps researchers tackle the challenges that still remain in creating cheap and effective TEGs and presents the latest trends and technologies in development and production of advanced thermoelectric generation devices.
Publisher: Springer Nature
ISBN: 3030458628
Category : Technology & Engineering
Languages : en
Pages : 306
Book Description
This book presents and facilitates new research and development results with hot topics in the thermoelectric generators (TEGs) field. Topics include: novel thin film; multilayer, composite and nanostructured thermoelectric materials; simulation of phenomena related to thermoelectricity; thermoelectric thin film and multilayer materials manufacturing technologies; measurement techniques for characterization; thermoelectric generators; and the simulation, modeling, design, thermal, and mechanical degradation problems. This book helps researchers tackle the challenges that still remain in creating cheap and effective TEGs and presents the latest trends and technologies in development and production of advanced thermoelectric generation devices.
Thermoelectric Thin Films
Author: Paolo Mele
Publisher: Springer
ISBN: 3030200434
Category : Technology & Engineering
Languages : en
Pages : 222
Book Description
This book will provide readers with deep insight into the intriguing science of thermoelectric thin films. It serves as a fundamental information source on the techniques and methodologies involved in thermoelectric thin film growth, characterization and device processing. This book involves widespread contributions on several categories of thermoelectric thin films: oxides, chalcogenides, iodates, nitrides and polymers. This will serve as an invaluable resource for experts to consolidate their knowledge and will provide insight and inspiration to beginners wishing to learn about thermoelectric thin films. Provides a single-source reference on a wide spectrum of topics related to thermoelectric thin films, from organic chemistry to devices, from physical chemistry to applied physics, from synthesis to device implementation; Covers several categories of thermoelectric thin films based on different material approaches such as oxides, chalcogenides, iodates, nitrides and polymers; Discusses synthesis, characterization, and device processing of thermoelectric thin films, as well as the nanoengineering approach to tailor the properties of the used materials at the nanoscale level.
Publisher: Springer
ISBN: 3030200434
Category : Technology & Engineering
Languages : en
Pages : 222
Book Description
This book will provide readers with deep insight into the intriguing science of thermoelectric thin films. It serves as a fundamental information source on the techniques and methodologies involved in thermoelectric thin film growth, characterization and device processing. This book involves widespread contributions on several categories of thermoelectric thin films: oxides, chalcogenides, iodates, nitrides and polymers. This will serve as an invaluable resource for experts to consolidate their knowledge and will provide insight and inspiration to beginners wishing to learn about thermoelectric thin films. Provides a single-source reference on a wide spectrum of topics related to thermoelectric thin films, from organic chemistry to devices, from physical chemistry to applied physics, from synthesis to device implementation; Covers several categories of thermoelectric thin films based on different material approaches such as oxides, chalcogenides, iodates, nitrides and polymers; Discusses synthesis, characterization, and device processing of thermoelectric thin films, as well as the nanoengineering approach to tailor the properties of the used materials at the nanoscale level.
Thermoelectrics for Power Generation
Author: Mikhail Nikitin
Publisher: BoD – Books on Demand
ISBN: 9535128450
Category : Technology & Engineering
Languages : en
Pages : 574
Book Description
Thermoelectrics for Power Generation - A Look at Trends in the Technology is the first part of the InTech collection of international community works in the field of thermoelectric power generation. The authors from many counties have presented in this book their achievements and vision for the future development in different aspects of thermoelectric power generation. Remarkably, this hot topic unites together efforts of researchers and engineers from all continents of our planet. The reader will find in the book a lot of new interesting information concerning prospective materials for thermoelectric generators, both inorganic and organic; results of theoretical studies of materials characteristics; novel methods and apparatus for measuring performance of thermoelectric materials and devices; and thermoelectric power generator simulation, modeling, design, and practice.
Publisher: BoD – Books on Demand
ISBN: 9535128450
Category : Technology & Engineering
Languages : en
Pages : 574
Book Description
Thermoelectrics for Power Generation - A Look at Trends in the Technology is the first part of the InTech collection of international community works in the field of thermoelectric power generation. The authors from many counties have presented in this book their achievements and vision for the future development in different aspects of thermoelectric power generation. Remarkably, this hot topic unites together efforts of researchers and engineers from all continents of our planet. The reader will find in the book a lot of new interesting information concerning prospective materials for thermoelectric generators, both inorganic and organic; results of theoretical studies of materials characteristics; novel methods and apparatus for measuring performance of thermoelectric materials and devices; and thermoelectric power generator simulation, modeling, design, and practice.
Flexible Thermoelectric Polymers and Systems
Author: Jianyong Ouyang
Publisher: John Wiley & Sons
ISBN: 1119550637
Category : Science
Languages : en
Pages : 273
Book Description
Flexible Thermoelectric Polymers and Systems Comprehensive review of the rapidly evolving field of flexible thermoelectric polymers Flexible Thermoelectric Polymers and Systems delivers an expansive exploration of the most recent developments in flexible thermoelectric polymers and composites, as well as their applications in thermoelectric generators and Peltier coolers. The book focuses on novel designs and applications of technologies such as low-dimensional thermoelectric materials and how the latest advances have begun to overcome problems including poor mechanical flexibility and high fabrication costs. The book begins with a review of the fundamentals of thermoelectric materials, including discussions of the properties of thermoelectric materials, the Seebeck, Peltier, and Thomson effects, electrical conductivity, thermal conductivity, and thermoelectric generators, cooling, and sensors. It goes on to discuss more advanced developments in the field, such as flexible thermoelectric plastics and the thermoelectric properties of conducting polymers with ionic conductors. The book also includes: Thorough introductions to thermoelectric materials and systems, as well as the chemistry and physics of intrinsically conductive polymers Comprehensive explorations of thermoelectric PEDOTs, p-type thermoelectric polymers, and N-type thermoelectric polymers Practical discussions of thermoelectric composites of carbon nanotubes, graphene, and nanomaterials In-depth examinations of polymer composites of inorganic thermoelectric semiconductors Perfect for academic and industrial researchers and engineers in physics, materials science, chemistry, and engineering, Flexible Thermoelectric Polymers and Systems is also an indispensable resource for graduate students and early-career professionals working in those fields.
Publisher: John Wiley & Sons
ISBN: 1119550637
Category : Science
Languages : en
Pages : 273
Book Description
Flexible Thermoelectric Polymers and Systems Comprehensive review of the rapidly evolving field of flexible thermoelectric polymers Flexible Thermoelectric Polymers and Systems delivers an expansive exploration of the most recent developments in flexible thermoelectric polymers and composites, as well as their applications in thermoelectric generators and Peltier coolers. The book focuses on novel designs and applications of technologies such as low-dimensional thermoelectric materials and how the latest advances have begun to overcome problems including poor mechanical flexibility and high fabrication costs. The book begins with a review of the fundamentals of thermoelectric materials, including discussions of the properties of thermoelectric materials, the Seebeck, Peltier, and Thomson effects, electrical conductivity, thermal conductivity, and thermoelectric generators, cooling, and sensors. It goes on to discuss more advanced developments in the field, such as flexible thermoelectric plastics and the thermoelectric properties of conducting polymers with ionic conductors. The book also includes: Thorough introductions to thermoelectric materials and systems, as well as the chemistry and physics of intrinsically conductive polymers Comprehensive explorations of thermoelectric PEDOTs, p-type thermoelectric polymers, and N-type thermoelectric polymers Practical discussions of thermoelectric composites of carbon nanotubes, graphene, and nanomaterials In-depth examinations of polymer composites of inorganic thermoelectric semiconductors Perfect for academic and industrial researchers and engineers in physics, materials science, chemistry, and engineering, Flexible Thermoelectric Polymers and Systems is also an indispensable resource for graduate students and early-career professionals working in those fields.
Inorganic and Organic Thin Films
Author: Yu Song
Publisher: John Wiley & Sons
ISBN: 3527344977
Category : Technology & Engineering
Languages : en
Pages : 771
Book Description
Learn more about foundational and advanced topics in polymer thin films and coatings besides species with this powerful two-volume resource The two-volume Inorganic and Organic Thin Films: Fundamentals, Fabrication, and Applications delivers a foundational resource for current researchers and commercial users involved in the design and fabrication of thin films. The book offers newcomers to the field a thorough description of new design theory, fabrication methods, and applications of advanced thin films. Readers will discover the physics and chemistry underlying the manufacture of new thin films and coatings in this leading new resource that promises to become a handbook for future applications of the technology. This one-stop reference brings together all important aspects of inorganic and polymeric thin films and coatings, including construction, assembly, deposition, functionality, patterning, and characterization. Explorations of their applications in industries as diverse as information technology, new energy, biomedical engineering, aerospace, and oceanographic engineering round out this fulsome exploration of one of the most exciting and rapidly developing areas of scientific and industrial research today. Readers will also learn from: A comprehensive introduction to the progress of thin films and coatings as well as fundamentals in functional thin films and coatings An exploration of multi-layered magnetic thin films for electron transport control and signal sensing, including giant magnetoresistance, colossal magnetoresistance, tunneling magnetoresistance, and the quantum anomalous Holzer effect An in time summary of high-quality magneto-optics, nanophotonics, spin waves and spintronics using bismuth-substituted iron garnet thin films as examples A thorough discussion of template-assisted fabrication of nanostructure thin films for ultrasensitive detection of chemicals and biomolecules A treatment of biomass derived functional films and coatings Perfect for materials scientists and inorganic chemists, Inorganic and Organic Thin Films will also earn a place in the libraries of solid state physicists and physical chemists working in private industry, as well as polymer and surface chemists who seek to improve their understanding of thin films and coatings.
Publisher: John Wiley & Sons
ISBN: 3527344977
Category : Technology & Engineering
Languages : en
Pages : 771
Book Description
Learn more about foundational and advanced topics in polymer thin films and coatings besides species with this powerful two-volume resource The two-volume Inorganic and Organic Thin Films: Fundamentals, Fabrication, and Applications delivers a foundational resource for current researchers and commercial users involved in the design and fabrication of thin films. The book offers newcomers to the field a thorough description of new design theory, fabrication methods, and applications of advanced thin films. Readers will discover the physics and chemistry underlying the manufacture of new thin films and coatings in this leading new resource that promises to become a handbook for future applications of the technology. This one-stop reference brings together all important aspects of inorganic and polymeric thin films and coatings, including construction, assembly, deposition, functionality, patterning, and characterization. Explorations of their applications in industries as diverse as information technology, new energy, biomedical engineering, aerospace, and oceanographic engineering round out this fulsome exploration of one of the most exciting and rapidly developing areas of scientific and industrial research today. Readers will also learn from: A comprehensive introduction to the progress of thin films and coatings as well as fundamentals in functional thin films and coatings An exploration of multi-layered magnetic thin films for electron transport control and signal sensing, including giant magnetoresistance, colossal magnetoresistance, tunneling magnetoresistance, and the quantum anomalous Holzer effect An in time summary of high-quality magneto-optics, nanophotonics, spin waves and spintronics using bismuth-substituted iron garnet thin films as examples A thorough discussion of template-assisted fabrication of nanostructure thin films for ultrasensitive detection of chemicals and biomolecules A treatment of biomass derived functional films and coatings Perfect for materials scientists and inorganic chemists, Inorganic and Organic Thin Films will also earn a place in the libraries of solid state physicists and physical chemists working in private industry, as well as polymer and surface chemists who seek to improve their understanding of thin films and coatings.
Thermoelectric Polymers
Author: Inamuddin
Publisher: Materials Research Forum LLC
ISBN: 1644903008
Category : Technology & Engineering
Languages : en
Pages : 153
Book Description
The book presents recent developments in the field of thermoelectric polymers and polymer composites. It focuses on the link between thermoelectric characteristics and material structure. Topics covered include chemical composition, microstructure, dopants, doping levels, methods of fabrication, thermoelectric effect, thermoelectric device conversion efficiency, and thermoelectric properties of conducting polymers. Keywords: Cage Compounds, Calixarenes, Conducting Polymers, Cryptophanes, Energy Conversion, Half-Heusler Compounds, Skutterudite Compounds, Hybrid Thermoelectric Materials, Supramolecular Chemistry, Thermoelectric Conversion Efficiency, Thermoelectric Plastics.
Publisher: Materials Research Forum LLC
ISBN: 1644903008
Category : Technology & Engineering
Languages : en
Pages : 153
Book Description
The book presents recent developments in the field of thermoelectric polymers and polymer composites. It focuses on the link between thermoelectric characteristics and material structure. Topics covered include chemical composition, microstructure, dopants, doping levels, methods of fabrication, thermoelectric effect, thermoelectric device conversion efficiency, and thermoelectric properties of conducting polymers. Keywords: Cage Compounds, Calixarenes, Conducting Polymers, Cryptophanes, Energy Conversion, Half-Heusler Compounds, Skutterudite Compounds, Hybrid Thermoelectric Materials, Supramolecular Chemistry, Thermoelectric Conversion Efficiency, Thermoelectric Plastics.
Handbook of Conducting Polymers, Fourth Edition - 2 Volume Set
Author: John R. Reynolds
Publisher: CRC Press
ISBN: 1351660233
Category : Technology & Engineering
Languages : en
Pages : 1525
Book Description
In the last 10 years there have been major advances in fundamental understanding and applications and a vast portfolio of new polymer structures with unique and tailored properties was developed. Work moved from a chemical repeat unit structure to one more based on structural control, new polymerization methodologies, properties, processing, and applications. The 4th Edition takes this into account and will be completely rewritten and reorganized, focusing on spin coating, spray coating, blade/slot die coating, layer-by-layer assembly, and fiber spinning methods; property characterizations of redox, interfacial, electrical, and optical phenomena; and commercial applications.
Publisher: CRC Press
ISBN: 1351660233
Category : Technology & Engineering
Languages : en
Pages : 1525
Book Description
In the last 10 years there have been major advances in fundamental understanding and applications and a vast portfolio of new polymer structures with unique and tailored properties was developed. Work moved from a chemical repeat unit structure to one more based on structural control, new polymerization methodologies, properties, processing, and applications. The 4th Edition takes this into account and will be completely rewritten and reorganized, focusing on spin coating, spray coating, blade/slot die coating, layer-by-layer assembly, and fiber spinning methods; property characterizations of redox, interfacial, electrical, and optical phenomena; and commercial applications.
PEDOT
Author: Andreas Elschner
Publisher: CRC Press
ISBN: 1420069128
Category : Technology & Engineering
Languages : en
Pages : 380
Book Description
While there is information available in handbooks on polythiophene chemistry and physics, until now, few if any books have focused exclusively on the most forwardly developed electrically conductive polymer, Poly (3,4-ethylenedioxythiophene)-otherwise known as PEDOT. This resource provides full chemical, physical, and technical information about this important conducting polymer, discussing basic knowledge and exploring its technical applications. Presented information is based on information generated at universities and through academic research, as well as by industrial scientists, providing a complete picture of the experimental and the practical aspects of this important polymer.
Publisher: CRC Press
ISBN: 1420069128
Category : Technology & Engineering
Languages : en
Pages : 380
Book Description
While there is information available in handbooks on polythiophene chemistry and physics, until now, few if any books have focused exclusively on the most forwardly developed electrically conductive polymer, Poly (3,4-ethylenedioxythiophene)-otherwise known as PEDOT. This resource provides full chemical, physical, and technical information about this important conducting polymer, discussing basic knowledge and exploring its technical applications. Presented information is based on information generated at universities and through academic research, as well as by industrial scientists, providing a complete picture of the experimental and the practical aspects of this important polymer.
Optics of Conducting Polymer Thin Films and Nanostructures
Author: Shangzhi Chen
Publisher: Linköping University Electronic Press
ISBN: 9179297455
Category :
Languages : en
Pages : 142
Book Description
Intrinsically conducting polymers forms a category of doped conjugated polymers that can conduct electricity. Since their discovery in the late 1970s, they have been widely applied in many fields, ranging from optoelectronic devices to biosensors. The most common type of conducting polymers is poly(3,4-ethylenedioxythiophene), or PEDOT. PEDOT has been popularly used as electrodes for solar cells or light-emitting diodes, as channels for organic electrochemical transistors, and as p-type legs for organic thermoelectric generators. Although many studies have been dedicated to PEDOT-based materials, there has been a lack of a unified model to describe their optical properties across different spectral ranges. In addition, the interesting optical properties of PEDOT-based materials, benefiting from its semi-metallic character, have only been rarely studied and utilized, and could potentially enable new applications. Plasmonics is a research field focusing on interactions between light and metals, such as the noble metals (gold and silver). It has enabled various opportunities in fundamental photonics as well as practical applications, varying from biosensors to colour displays. This thesis explores highly conducting polymers as alternatives to noble metals and as a new type of active plasmonic materials. Despite high degrees of microstructural disorder, conducting polymers can possess electrical conductivity approaching that of poor metals, with particularly high conductivity for PEDOT deposited via vapour phase polymerization (VPP). In this thesis, we systematically studied the optical and structural properties of VPP PEDOT thin films and their nanostructures for plasmonics and other optical applications. We employed ultra-wide spectral range ellipsometry to characterize thin VPP PEDOT films and proposed an anisotropic Drude-Lorentz model to describe their optical conductivity, covering the ultraviolet, visible, infrared, and terahertz ranges. Based on this model, PEDOT doped with tosylate (PEDOT:Tos) presented negative real permittivity in the near infrared range. While this indicated optical metallic character, the material also showed comparably large imaginary permittivity and associated losses. To better understand the VPP process, we carefully examined films with a collection of microstructural and spectroscopic characterization methods and found a vertical layer stratification in these polymer films. We unveiled the cause as related to unbalanced transport of polymerization precursors. By selection of suitable counterions, e.g., trifluoromethane sulfonate (OTf), and optimization of reaction conditions, we were able to obtain PEDOT films with electrical conductivity exceeding 5000 S/cm. In the near infrared range from 1 to 5 µm, these PEDOT:OTf films provided a well-defined plasmonic regime, characterized by negative real permittivity and lower magnitude imaginary component. Using a colloidal lithography-based approach, we managed to fabricate nanodisks of PEDOT:OTf and showed that they exhibited clear plasmonic absorption features. The experimental results matched theoretical calculations and numerical simulations. Benefiting from their mixed ionic-electronic conducting characters, such organic plasmonic materials possess redox-tunable properties that make them promising as tuneable optical nanoantennas for spatiotemporally dynamic systems. Finally, we presented a low-cost and efficient method to create structural colour surfaces and images based on UV-treated PEDOT films on metallic mirrors. The concept generates beautiful and vivid colours through-out the visible range utilizing a synergistic effect of simultaneously modulating polymer absorption and film thickness. The simplicity of the device structure, facile fabrication process, and tunability make this proof-of-concept device a potential candidate for future low-cost backlight-free displays and labels.
Publisher: Linköping University Electronic Press
ISBN: 9179297455
Category :
Languages : en
Pages : 142
Book Description
Intrinsically conducting polymers forms a category of doped conjugated polymers that can conduct electricity. Since their discovery in the late 1970s, they have been widely applied in many fields, ranging from optoelectronic devices to biosensors. The most common type of conducting polymers is poly(3,4-ethylenedioxythiophene), or PEDOT. PEDOT has been popularly used as electrodes for solar cells or light-emitting diodes, as channels for organic electrochemical transistors, and as p-type legs for organic thermoelectric generators. Although many studies have been dedicated to PEDOT-based materials, there has been a lack of a unified model to describe their optical properties across different spectral ranges. In addition, the interesting optical properties of PEDOT-based materials, benefiting from its semi-metallic character, have only been rarely studied and utilized, and could potentially enable new applications. Plasmonics is a research field focusing on interactions between light and metals, such as the noble metals (gold and silver). It has enabled various opportunities in fundamental photonics as well as practical applications, varying from biosensors to colour displays. This thesis explores highly conducting polymers as alternatives to noble metals and as a new type of active plasmonic materials. Despite high degrees of microstructural disorder, conducting polymers can possess electrical conductivity approaching that of poor metals, with particularly high conductivity for PEDOT deposited via vapour phase polymerization (VPP). In this thesis, we systematically studied the optical and structural properties of VPP PEDOT thin films and their nanostructures for plasmonics and other optical applications. We employed ultra-wide spectral range ellipsometry to characterize thin VPP PEDOT films and proposed an anisotropic Drude-Lorentz model to describe their optical conductivity, covering the ultraviolet, visible, infrared, and terahertz ranges. Based on this model, PEDOT doped with tosylate (PEDOT:Tos) presented negative real permittivity in the near infrared range. While this indicated optical metallic character, the material also showed comparably large imaginary permittivity and associated losses. To better understand the VPP process, we carefully examined films with a collection of microstructural and spectroscopic characterization methods and found a vertical layer stratification in these polymer films. We unveiled the cause as related to unbalanced transport of polymerization precursors. By selection of suitable counterions, e.g., trifluoromethane sulfonate (OTf), and optimization of reaction conditions, we were able to obtain PEDOT films with electrical conductivity exceeding 5000 S/cm. In the near infrared range from 1 to 5 µm, these PEDOT:OTf films provided a well-defined plasmonic regime, characterized by negative real permittivity and lower magnitude imaginary component. Using a colloidal lithography-based approach, we managed to fabricate nanodisks of PEDOT:OTf and showed that they exhibited clear plasmonic absorption features. The experimental results matched theoretical calculations and numerical simulations. Benefiting from their mixed ionic-electronic conducting characters, such organic plasmonic materials possess redox-tunable properties that make them promising as tuneable optical nanoantennas for spatiotemporally dynamic systems. Finally, we presented a low-cost and efficient method to create structural colour surfaces and images based on UV-treated PEDOT films on metallic mirrors. The concept generates beautiful and vivid colours through-out the visible range utilizing a synergistic effect of simultaneously modulating polymer absorption and film thickness. The simplicity of the device structure, facile fabrication process, and tunability make this proof-of-concept device a potential candidate for future low-cost backlight-free displays and labels.