Thermodynamics of Systems in Nonequilibrium States PDF Download
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Author: Ralph John Tykodi
Publisher:
ISBN:
Category : Entropy
Languages : en
Pages : 488
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Book Description
Author: Ralph John Tykodi
Publisher:
ISBN:
Category : Entropy
Languages : en
Pages : 488
Get Book Here
Book Description
Author: Ralph John Tykodi
Publisher:
ISBN: 9781888710120
Category : Entropy
Languages : en
Pages : 474
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Book Description
Author: V. Parmon
Publisher: Elsevier
ISBN: 0080931960
Category : Technology & Engineering
Languages : en
Pages : 340
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Book Description
Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis consists of materials adapted from lectures on the thermodynamics of nonequilibrium processes that have been taught at the Department of Natural Sciences of Novosibirsk State University since 1995. The thermodynamics of nonequilibrium processes traditionally required students to have a strong background in physics. However, the materials featured in this volume allow anyone with knowledge in classical thermodynamics of equilibrium processes and traditional chemical kinetics to understand the subject. Topics discussed include systems in the thermodynamics of irreversible processes; thermodynamics of systems that are close to and far from equilibrium; thermodynamics of catalysts; the application of nonequilibrium thermodynamics to material science; and the relationship between entropy and information. This book will be helpful for research into complex chemical transformations, particularly catalytic transformations. Applies simple approaches of non-equilibrium thermodynamics to analyzing properties of chemically reactive systems Covers systems far from equilibrium, allowing the consideration of most chemically reactive systems of a chemical or biological nature This approach resolves many complicated problems in the teaching of chemical kinetics
Author: Signe Kjelstrup
Publisher: World Scientific
ISBN: 9812779132
Category : Technology & Engineering
Languages : en
Pages : 451
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Book Description
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
Author: Joel Keizer
Publisher: Springer Science & Business Media
ISBN: 1461210542
Category : Science
Languages : en
Pages : 517
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Book Description
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.
Author: Yasar Demirel
Publisher: Newnes
ISBN: 0444595813
Category : Technology & Engineering
Languages : en
Pages : 787
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Book Description
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. Informs and updates on all the latest developments in the field Contributions from leading authorities and industry experts A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems Presents a unified analysis for transport and rate processes in various time and space scales Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories Has 198 fully solved examples and 287 practice problems An Instructor Resource containing the Solution Manual can be obtained from the author:
[email protected]
Author: S. R. De Groot
Publisher: Courier Corporation
ISBN: 0486153509
Category : Science
Languages : en
Pages : 532
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Book Description
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.
Author: Axel Kleidon
Publisher: Springer Science & Business Media
ISBN: 9783540224952
Category : Science
Languages : en
Pages : 288
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Book Description
The present volume studies the application of concepts from non-equilibrium thermodynamics to a variety of research topics. Emphasis is on the Maximum Entropy Production (MEP) principle and applications to Geosphere-Biosphere couplings. Written by leading researchers from a wide range of backgrounds, the book presents a first coherent account of an emerging field at the interface of thermodynamics, geophysics and life sciences.
Author: Phil Attard
Publisher: OUP Oxford
ISBN: 019163977X
Category : Science
Languages : en
Pages : 480
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Book Description
`Non-equilibrium Thermodynamics and Statistical Mechanics: Foundations and Applications' builds from basic principles to advanced techniques, and covers the major phenomena, methods, and results of time-dependent systems. It is a pedagogic introduction, a comprehensive reference manual, and an original research monograph. Uniquely, the book treats time-dependent systems by close analogy with their static counterparts, with most of the familiar results of equilibrium thermodynamics and statistical mechanics being generalized and applied to the non-equilibrium case. The book is notable for its unified treatment of thermodynamics, hydrodynamics, stochastic processes, and statistical mechanics, for its self-contained, coherent derivation of a variety of non-equilibrium theorems, and for its quantitative tests against experimental measurements and computer simulations. Systems that evolve in time are more common than static systems, and yet until recently they lacked any over-arching theory. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is unique in its unified presentation of the theory of non-equilibrium systems, which has now reached the stage of quantitative experimental and computational verification. The novel perspective and deep understanding that this book brings offers the opportunity for new direction and growth in the study of time-dependent phenomena. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is an invaluable reference manual for experts already working in the field. Research scientists from different disciplines will find the overview of time-dependent systems stimulating and thought-provoking. Lecturers in physics and chemistry will be excited by many fresh ideas and topics, insightful explanations, and new approaches. Graduate students will benefit from its lucid reasoning and its coherent approach, as well as from the chem12physof mathematical techniques, derivations, and computer algorithms.
Author: Yasar Demirel
Publisher: Elsevier
ISBN: 0444641130
Category : Science
Languages : en
Pages : 880
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Book Description
Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Fourth Edition emphasizes the unifying role of thermodynamics in analyzing natural phenomena. This updated edition expands on the third edition by focusing on the general balance equations for coupled processes of physical, chemical and biological systems. Updates include stochastic approaches, self-organization criticality, ecosystems, mesoscopic thermodynamics, constructual law, quantum thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems. The book also emphasizes nonequilibrium thermodynamics tools, such as fluctuation theories, mesoscopic thermodynamic analysis, information theories, and quantum thermodynamics in describing and designing small scale systems. Provides a useful text for seniors and graduate students from diverse engineering and science programs Highlights the fundamentals of equilibrium thermodynamics, transport processes and chemical reactions Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical and biological systems Presents a unified analysis for transport and rate processes in various time and space scales Discusses stochastic approaches in thermodynamic analysis, including fluctuation and information theories, mesoscopic nonequilibrium thermodynamics, constructal law and quantum thermodynamics