Thermodynamics and Statistical Mechanics PDF Download
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Author: M. Scott Shell
Publisher: Cambridge University Press
ISBN: 1107014530
Category : Science
Languages : en
Pages : 499
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Book Description
Learn classical thermodynamics alongside statistical mechanics and how macroscopic and microscopic ideas interweave with this fresh approach to the subjects.
Author: M. Scott Shell
Publisher: Cambridge University Press
ISBN: 1107014530
Category : Science
Languages : en
Pages : 499
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Book Description
Learn classical thermodynamics alongside statistical mechanics and how macroscopic and microscopic ideas interweave with this fresh approach to the subjects.
Author: Martin Bailyn
Publisher: American Institute of Physics
ISBN:
Category : Science
Languages : en
Pages : 680
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Book Description
"Blurb & Contents" "A superb reference." Physics Today "Will become a classic text in climate research. " Physics World "Valuable to anyone who studies, models, or uses the climate of the earth." Walter Robinson, Bulletin of the American Meteorological Society "Informative and authoritative on a remarkably wide range of topics." Nature Are we entering a period of global warming? Is weather predictable? Physics of Climate offers you an in-depth description of atmospheric circulation and how environmental phenomena worldwide interact in a single, unified system. This integrated approach unites all the key features of the climate system--oceans, atmosphere, and cryosphere--to explain the structure and behavior of climate over time. Ideal for students and professionals in meteorology, oceanography, geophysics, and physics. Contents: Nature of the Problem. Basic Equations for the Atmosphere and Oceans. Various Decompositions of the Circulation. The Data. Radiation Balance. Observed Mean State of the Atmosphere. Observed Mean State of the Oceans. Observed Mean State of the Cryosphere. Exchange Processes between the Earth's Surface and the Atmosphere. Angular Momentum Cycle. Water Cycle. Energetics. The Ocean-Atmosphere Heat Engine. Entropy in the Climate System. Interannual and Interdecadal Variability in the Climate System. Mathematical Simulation of Climate. Acknowledgments. Appendices. References.
Author: Bahman Zohuri
Publisher: Elsevier
ISBN: 012814520X
Category : Technology & Engineering
Languages : en
Pages : 728
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Book Description
Physics of Cryogenics: An Ultralow Temperature Phenomenon discusses the significant number of advances that have been made during the last few years in a variety of cryocoolers, such as Brayton, Joule-Thomson, Stirling, pulse tube, Gifford-McMahon and magnetic refrigerators. The book reviews various approaches taken to improve reliability, a major driving force for new research areas. The advantages and disadvantages of different cycles are compared, and the latest improvements in each of these cryocoolers is discussed. The book starts with the thermodynamic fundamentals, followed by the definition of cryogenic and the associated science behind low temperature phenomena and properties. This book is an ideal resource for scientists, engineers and graduate and senior undergraduate students who need a better understanding of the science of cryogenics and related thermodynamics. - Defines the fundamentals of thermodynamics that are associated with cryogenic processes - Provides an overview of the history of the development of cryogenic technology - Includes new, low temperature tables written by the author - Deals with the application of cryogenics to preserve objects at very low temperature - Explains how cryogenic phenomena work for human cell and human body preservations and new medical approaches
Author: Peter Atkins
Publisher: OUP Oxford
ISBN: 0191647632
Category : Science
Languages : en
Pages : 142
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Book Description
The laws of thermodynamics drive everything that happens in the universe. From the sudden expansion of a cloud of gas to the cooling of hot metal, and from the unfurling of a leaf to the course of life itself - everything is directed and constrained by four simple laws. They establish fundamental concepts such as temperature and heat, and reveal the arrow of time and even the nature of energy itself. Peter Atkins' powerful and compelling introduction explains what the laws are and how they work, using accessible language and virtually no mathematics. Guiding the reader from the Zeroth Law to the Third Law, he introduces the fascinating concept of entropy, and how it not only explains why your desk tends to get messier, but also how its unstoppable rise constitutes the engine of the universe.
Author: Keith P. Johnston
Publisher:
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 568
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Book Description
New directions in supercritical fluids science and technology, fluorescence spectroscopy studies of intermolecular interactions in supercritical fluids, solvation structure in supercritical fluid mixtures based on molecular distribution functions, gibbs-ensemble Monte Carlo simulations of phase equilibria in supercritical fluid mixtures, spectroscopic determination of solvent strength and structure in supercritical fluid mixtures, partition coefficients of polyethyle glycols in super critical carbon dioxide, experimental measurement of supercritical fluid-liquid phase equilibrium, vapor-liquid equilibria of fatty acid esters in supercritical fluids, four-phase equilibrium of two ternary organic systems with carbon dioxide, direct viscosity enhancement of carbon dioxide, inverse emulsion polymerization of acrylamide, interaction of polymers with near-critical carbon dioxide, fundamental kinetics of methanol oxidation in supercritical fluids, thermodynamic analysis of corrosion of iron alloys in supercritical water, electrochemical measurements of corrosion of iron alloys in supercritical water, phase and reaction equilibria considerations in the evaluation and operation of supercritical fluid reaction processes, kinetic model for supercritical delignification of wood, gas antisolvent recrystallization solids formation after the expansion of supercritical mixtures, food, pharmaceutical, and environmental applications, design of commercial plant.
Author: Antonio Saggion
Publisher: Springer Nature
ISBN: 3030269760
Category : Science
Languages : en
Pages : 444
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Book Description
This book offers a comprehensive overview of thermodynamics. It is divided into four parts, the first of which equips readers with a deeper understanding of the fundamental principles of thermodynamics of equilibrium states and of their evolution. The second part applies these principles to a series of generalized situations, presenting applications that are of interest both in their own right and in terms of demonstrating how thermodynamics, as a theory of principle, relates to different fields. In turn, the third part focuses on non-equilibrium configurations and the dynamics of natural processes. It discusses both discontinuous and continuous systems, highlighting the interference among non-equilibrium processes, and the nature of stationary states and of fluctuations in isolated systems. Lastly, part four introduces the relation between physics and information theory, which constitutes a new frontier in fundamental research. The book includes step-by-step exercises, with solutions, to help readers to gain a fuller understanding of the subjects, and also features a series of appendices providing useful mathematical formulae. Reflecting the content of modern university courses on thermodynamics, it is a valuable resource for students and young scientists in the fields of physics, chemistry, and engineering.
Author:
Publisher: Elsevier
ISBN: 0444640630
Category : Technology & Engineering
Languages : en
Pages : 862
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Book Description
Handbook of Thermal Analysis and Calorimetry: Recent Advances, Techniques and Applications, Volume Six, Second Edition, presents the latest in a series that has been well received by the thermal analysis and calorimetry community. This volume covers recent advances in techniques and applications that complement the earlier volumes. There has been tremendous progress in the field in recent years, and this book puts together the most high-impact topics selected for their popularity by new editors Sergey Vyazovkin, Nobuyoshi Koga and Christoph Schick—all editors of Thermochimica Acta. Among the important new techniques covered are biomass conversion; sustainable polymers; polymer nanocompsoties; nonmetallic glasses; phase change materials; propellants and explosives; applications to pharmaceuticals; processes in ceramics, metals, and alloys; ionic liquids; fast-scanning calorimetry, and more. - Features 19 all-new chapters to bring readers up to date on the current status of the field - Provides a broad overview of recent progress in the most popular techniques and applications - Includes chapters authored by a recognized leader in each field and compiled by a new team of editors, each with at least 20 years of experience in the field of thermal analysis and calorimetry - Enables applications across a wide range of modern materials, including polymers, metals, alloys, ceramics, energetics and pharmaceutics - Overviews the current status of the field and summarizes recent progress in the most popular techniques and applications
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872010
Category : Science
Languages : en
Pages : 432
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Book Description
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Author: Jurgen M. Honig
Publisher: Academic Press
ISBN: 0080525342
Category : Science
Languages : en
Pages : 469
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Book Description
Thermodynamics is a self-contained analysis of physical and chemical processes, based on classical thermodynamic principles. Emphasis is placed on the fundamental principles, with a conbination of theory and practice, and demonstrating their application to a variety of disciplines. Included in this work are new approaches to irreversible processes, electromagnetic effects, adsorption phenomena, self-assembly, the origin of phase diagrams, critical phenomena, and Carathéodory's treatment of the second law. This book will appeal to graduate students and professional chemists and physicists who wish to acquire a more sophisticated overview of thermodynamics and related subject matter. Easy-to-understand style appeals to both chemists and physicists Discusses treatment of electromagnetic phenomena and adsorption of surface gases surfaces Extensively revised to cater for advanced courses in thermodynamics
Author: R. Stephen Berry
Publisher: Yale University Press
ISBN: 0300238789
Category : Science
Languages : en
Pages : 184
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Book Description
A short and entertaining introduction to thermodynamics that uses real-world examples to explain accessibly an important but subtle scientific theory A romantic description of the second law of thermodynamics is that the universe becomes increasingly disordered. But what does that actually mean? Starting with an overview of the three laws of thermodynamics, MacArthur "genius grant" winner R. Stephen Berry explains in this short book the fundamentals of a fundamental science. Readers learn both the history of thermodynamics, which began with attempts to solve everyday engineering problems, and ongoing controversy and unsolved puzzles. The exposition, suitable for both students and armchair physicists, requires no previous knowledge of the subject and only the simplest mathematics, taught as needed. With this better understanding of one science, readers also gain an appreciation of the role of research in science, the provisional nature of scientific theory, and the ways scientific exploration can uncover fundamental truths. Thus, from a science of everyday experience, we learn about the nature of the universe.
