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Author: Miloslav Pekař
Publisher: Springer Science & Business Media
ISBN: 3319025147
Category : Science
Languages : en
Pages : 315
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Book Description
In this book, Samohýl and Pekař offer a consistent and general non-equilibrium thermodynamic description for a model of chemically reacting mixtures. This type of model is frequently encountered in practice and up until now, chemically reacting systems (out of equilibrium) have rarely been described in books on non-equilibrium thermodynamics. Readers of this book benefit from the systematic development of the theory; this starts with general principles, going through the applications to single component fluid systems, and finishing with the theory of mixtures, including chemical reactions. The authors describe the simplest mixture model – the linear fluid – and highlight many practical and thermodynamically consistent equations for describing transport properties and reaction kinetics for this model. Further on in the book, the authors also describe more complex models. Samohýl and Pekař take special care to clearly explain all methodology and starting axioms and they also describe in detail applied assumptions and simplifications. This book is suitable for graduate students in chemistry, materials science and chemical engineering as well as professionals working in these and related areas.
Author: Miloslav Pekař
Publisher: Springer Science & Business Media
ISBN: 3319025147
Category : Science
Languages : en
Pages : 315
Get Book Here
Book Description
In this book, Samohýl and Pekař offer a consistent and general non-equilibrium thermodynamic description for a model of chemically reacting mixtures. This type of model is frequently encountered in practice and up until now, chemically reacting systems (out of equilibrium) have rarely been described in books on non-equilibrium thermodynamics. Readers of this book benefit from the systematic development of the theory; this starts with general principles, going through the applications to single component fluid systems, and finishing with the theory of mixtures, including chemical reactions. The authors describe the simplest mixture model – the linear fluid – and highlight many practical and thermodynamically consistent equations for describing transport properties and reaction kinetics for this model. Further on in the book, the authors also describe more complex models. Samohýl and Pekař take special care to clearly explain all methodology and starting axioms and they also describe in detail applied assumptions and simplifications. This book is suitable for graduate students in chemistry, materials science and chemical engineering as well as professionals working in these and related areas.
Author: Miloslav Peka
Publisher:
ISBN: 9783319025155
Category :
Languages : en
Pages : 320
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Book Description
Author: A. R. H. Goodwin
Publisher: Royal Society of Chemistry
ISBN: 1847558062
Category : Science
Languages : en
Pages : 535
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Book Description
Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Author: Kolumban Hutter
Publisher: Springer
ISBN: 3319777459
Category : Science
Languages : en
Pages : 627
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Book Description
This third volume describes continuous bodies treated as classical (Boltzmann) and spin (Cosserat) continua or fluid mixtures of such bodies. It discusses systems such as Boltzmann continua (with trivial angular momentum) and Cosserat continua (with nontrivial spin balance) and formulates the balance law and deformation measures for these including multiphase complexities. Thermodynamics is treated in the spirit of Müller–Liu: it is applied to Boltzmann-type fluids in three dimensions that interact with neighboring fluids on two-dimensional contact surfaces and/or one-dimensional contact lines. For all these situations it formulates the balance laws for mass, momenta, energy, and entropy. Further, it introduces constitutive modeling for 3-, 2-, 3-d body parts for general processes and materially objective variable sets and their reduction to equilibrium and non-equilibrium forms. Typical (reduced) fluid spin continua are liquid crystals. Prominent nematic examples of these include the Ericksen–Leslie–Parodi (ELP) formulation, in which material particles are equipped with material unit vectors (directors). Nematic liquid crystals with tensorial order parameters of rank 1 to n model substructure behavior better, and for both classes of these, the book analyzes the thermodynamic conditions of consistency. Granular solid–fluid mixtures are generally modeled by complementing the Boltzmann laws with a balance of fluctuation (kinetic) energy of the particles. The book closes by presenting a full Reynolds averaging procedure that accounts for higher correlation terms e.g. a k-epsilon formulation in classical turbulence. However, because the volume fraction is an additional variable, the theory also incorporates ‘k-epsilon equations’ for the volume fraction.
Author: J.V. Sengers
Publisher: Elsevier
ISBN: 0080531180
Category : Science
Languages : en
Pages : 455
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Book Description
This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.
Author: I. M. Abdulagatov
Publisher: Begell House Publishers
ISBN: 9781567001303
Category : Science
Languages : en
Pages : 350
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Book Description
This book considers various methods of experimental study of thermal and caloric properties of pure substances and binary mixtures in wide ranges of the variation of independent variables, including the near critical region. Containing over 100 tables and figures, and exhaustively researched (over 500 references are listed), this monograph is addressed to both theorists and experimenters working in the fields of molecular physics, chemical technology, and power engineering, as well as researchers, lecturers, postgraduates, and students.
Author: J. C. Gibbings
Publisher: Elsevier
ISBN: 1483184161
Category : Technology & Engineering
Languages : en
Pages : 327
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Book Description
Thermomechanics gives an introduction to the governing equations of thermodynamics and of the mechanics of fluids. The book first gives a summary of the Newtonian mechanics of rigid bodies, which is followed by a discussion of mechanical properties of infinitesimal elements, including continuum, density, surface tension, stresses, and pressure. Temperature and the zero'th law; units; and the system of finite size are then examined. The book also explains the laws of thermodynamics including its applications. Heat processes, motionless fluids, and mixtures of phases are also tackled. The text then explains the conservation of mass in a fluid flow; the equations relating process phenomena; and the momentum equation for fluids in motion. The last part encompasses the adiabatic flow. The text will best serve those interested in thermomechanics and related concepts.
Author: Jose M. Ortiz de Zarate
Publisher: Elsevier
ISBN: 0080459439
Category : Science
Languages : en
Pages : 321
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Book Description
This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed. · Systematic exposition of fluctuating hydrodynamics and its applications· First book on nonequilibrium fluctuations in fluids· Fluctuating Boussinesq equations and nonequilibrium fluids· Fluid layers and onset of convection· Rayleigh scattering and Brillouin scattering in fluids· Shadowgraph technique for measuring fluctuations· Fluctuations near hydrodynamic instabilities
Author: Ivan Samohýl
Publisher:
ISBN:
Category : Fluids
Languages : en
Pages : 184
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Book Description
Author: D. Jou
Publisher: Springer Science & Business Media
ISBN: 3662044145
Category : Science
Languages : en
Pages : 242
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Book Description
Based on the authors’ successful theory for extended irreversible thermodynamics, the book analyzes the thermodynamic aspects of several phenomena induced by the flow in fluid systems.
