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Author: Mohamed S. El-Aasser
Publisher: Springer Science & Business Media
ISBN: 9400981147
Category : Science
Languages : en
Pages : 250
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Book Description
It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.
Author: Mohamed S. El-Aasser
Publisher: Springer Science & Business Media
ISBN: 9400981147
Category : Science
Languages : en
Pages : 250
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Book Description
It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.
Author: Yildirim H. Erbil
Publisher: CRC Press
ISBN: 142003880X
Category : Science
Languages : en
Pages : 338
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Book Description
The versatility of the emulsion copolymerization reaction and the ability to control the properties of the final latices have led to rapid expansion both in the quantity of polyvinylacetate and vinyl acetate-acrylic copolymer latices and in their applications. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers provides
Author: Mohamed S El-Aasser
Publisher:
ISBN: 9789400981157
Category :
Languages : en
Pages : 308
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Book Description
Author: V. I. Eliseeva
Publisher: Springer Science & Business Media
ISBN: 1468416413
Category : Technology & Engineering
Languages : en
Pages : 231
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Book Description
There is a large body of Soviet work on emulsion polymerization, spanning a period of over three decades, that has been published primarily in the Russian language. Most of this has remained untranslated into English and hence un available to most other scientists. The value of this book lies primarily in the fact that it brings together the most important of these Soviet contributions, along with comment and analysis by the authors, who may be considered among the foremost authorities in this field in the Soviet Union. But the hundreds of literature citations go far beyond the borders of the Soviet Union and serve as an excellent bibliography of the world literature on emulsion polymerization up to the time this book was written. The book covers both fundamental and applied aspects. In the former are included discussions of particle formation mechanisms, a comprehensive theory of emulsion polymerization, copolymerization of polar monomers, and particle morphology and its implications with regard to derived film properties. Among the applied aspects are discussions of continuous emulsion polymerization, both tubular reactors and continuous stirred tank cascades, and various aspects con cerning the manufacture of some of the most important monomers, such as styrene, butadiene, vinyl acetate, methyl methacrylate, acrylonitrile, and chloroprene. This book will be an indispensable reference source for scientists who are entering the field as well as those who are experienced and who have wanted a ready access to this large body of literature.
Author: A. M. van Herk
Publisher: John Wiley & Sons
ISBN: 1405171782
Category : Technology & Engineering
Languages : en
Pages : 328
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Book Description
Emulsion polymerisation produces high value polymers in a low cost, environmentally friendly process. The drive to develop environmentally benign production methods for polymers has resulted in widespread development and implementation of the emulsion polymerisation technique. In addition, when combined with novel polymerisation mechanisms the process can give rise to a range of polymer products with particularly useful properties. Emulsion polymerisation is a complex process, governed by the interplay of both chemical and physical properties including polymerisation kinetics and dispersion stability. Successful industrial application relies on understanding and controlling those properties. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, Chemistry and Technology of Emulsion Polymerisation provides a practical and intuitive explanation of emulsion polymerisation. In the development of industrial processes, coupling that understanding with everyday practice can be a further difficult step, so the book emphasises a clear, comprehensive and straightforward discussion to illustrate how the principles relate to practical application. Written for research chemists, technologists and engineers in the polymer, fine and specialty chemicals industries, and in university or government laboratories, this book will be particularly valuable to those early on in their careers. The comprehensive and straightforward coverage will also ensure it is an important resource for advanced courses in emulsion polymerisation.
Author: Chorng-Shyan Chern
Publisher: John Wiley & Sons
ISBN: 0470377933
Category : Science
Languages : en
Pages : 268
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Book Description
Up-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials. Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal phenomena in emulsion polymerization Important end-use properties of emulsion polymer (latex) products Information on industrial applications in paints, coatings, adhesives, paper and board, and more This is a hands-on reference for graduate students and professionals in polymerchemistry, chemical engineering, and materials science who are involved in researchon coatings, adhesives, rubber, latex, paints, finishes, and other materials that can becreated using various methods of emulsion polymerization.
Author: George Odian
Publisher: John Wiley & Sons
ISBN: 0471274003
Category : Technology & Engineering
Languages : en
Pages : 850
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Book Description
The new edition of a classic text and reference The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: * Metallocene and post-metallocene polymerization catalysts * Living polymerizations (radical, cationic, anionic) * Dendrimer, hyperbranched, brush, and other polymer architectures and assemblies * Graft and block copolymers * High-temperature polymers * Inorganic and organometallic polymers * Conducting polymers * Ring-opening polymer ization * In vivo and in vitro polymerization Appropriate for both novice and advanced students as well as professionals, this comprehensive yet accessible resource enables the reader to achieve an advanced, up-to-date understanding of polymer synthesis. Different methods of polymerization, reaction parameters for synthesis, molecular weight, branching and crosslinking, and the chemical and physical structure of polymers all receive ample coverage. A thorough discussion at the elementary level prefaces each topic, with a more advanced treatment following. Yet the language throughout remains straightforward and geared towards the student. Extensively updated, Principles of Polymerization, Fourth Edition provides an excellent textbook for today's students of polymer chemistry, chemical engineering, and materials science, as well as a current reference for the researcher or other practitioner working in these areas.
Author: Masayoshi Okubo
Publisher: Springer Science & Business Media
ISBN: 9783540229230
Category : Technology & Engineering
Languages : en
Pages : 388
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Book Description
In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.
Author: NPCS Board of Consultants & Engineers
Publisher: NIIR PROJECT CONSULTANCY SERVICES
ISBN: 8190568531
Category : Emulsions
Languages : en
Pages : 426
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Book Description
Emulsifier is an organic compound that encompasses in the same molecule two dissimilar structural groups e.g. water soluble and a water insoluble moiety. It is the ingredient which binds the water and oil in a cream or lotion together permanently. The composition, solubility properties, location and relative sizes of these dissimilar groups in relation to the overall molecular configuration determine the surface activity of a compound. Emulsifiers are classified on the basis of their hydrophilic or solubilizing groups in to four categories anionic, non ionic, cationics and amphoterics. Emulsifier is utilized in various industries; agriculture, building and construction, elastomers & plastics, food & beverages, industrial cleaning, leather, metals, paper, textiles paints & protective coatings etc. An emulsion is an ideal formulation for the administration. The emulsion form allows uniform application of a small amount of active ingredient on the surface of the skin. Some of the important emulsions in different field are pharmaceutical emulsions, rosin & rubber emulsion, textile emulsions, pesticide emulsions, food emulsions, emulsion in paint industry, emulsion in polish industry, leather & paper treatment emulsions etc. Various cosmetics creams, such as moisturizers, contain emulsifiers. Lighter, less greasy feeling creams are oil in water emulsions; heavier creams used to treat rough skin are water in oil emulsions, with oil as the main ingredient. Liquid soaps, toothpastes and other body care products also contain emulsifiers. Emulsifiers have the ability to optimize the concentration of certain nutrients in an emulsion. For example, in hair conditioners, some conditioning agents can damage hair if not properly diluted in the solution. Emulsifiers are among the most frequently used types of food additives. Emulsifiers can help to make a food appealing. Emulsifiers have a big effect on the structure and texture of many foods. Increasing demand for low fat food among health conscious consumers is gradually driving the market for emulsifiers. Besides stabilizing emulsions, emulsifiers derived from non hydrogenated fats help in maintaining sensory characteristics of food such as texture, flavor, and taste that are often lost due to fat reduction. This characteristic of making healthier products similar in taste to fat containing versions has enabled emulsifiers in gaining widespread acceptance in the market. The global food industry is also witnessing increase in demand for multipurpose emulsifiers that perform functions of both stabilization and emulsification. Some of the fundamentals of the book are characteristics and application of emulsifiers, wetting and detergent structures in emulsifier, effect of surfactant on the properties of solutions, wetting characteristics of emulsifiers, formulated emulsifiers, non surfactant functional additives, inert fillers, functional surfactant additives, uses of emulsifiers, household and personal products, industrial uses of emulsifier, anionic surfactants, non ionic surfactants, cationic, amphoteric and enzyme, alkylolamides, vinylarene polymers, alkyl sulfates, ethoxylation processes, application of emulsifiers, etc. The present book contains manufacturing processes of various types of emulsifiers which have applications in different industries. This is a resourceful book for scientists, technologists, entrepreneurs and ingredients suppliers. TAGS applications of emulsifier, Book on emulsifier, emulsifier Based Small Scale Industries, emulsifier examples, emulsifier in food, Emulsifier Processing Industry in India, emulsifiers list, Emulsifiers with Uses, Formulae and Processes, Emulsion - Uses of Emulsions, Emulsion Surface Area, Emulsions in Polish Industry, Food Emulsifier Applications, Food Emulsifiers and Their Applications, formulation and stability of emulsions with polymeric emulsifiers, Formulation of emulsifiers, Formulation of Emulsion Paints manufacturing process, Formulation of Textile emulsions manufacturing process, function of emulsifier in cosmetics, function of emulsifier in food, how to manufacture emulsifiers, How to start an emulsifier Production Business, How to Start Emulsifier Processing Industry in India, Industrial Applications of Emulsion Technology, Industrial Uses of Emulsifier, Leather and Paper Treatment Emulsions manufacturing process, Manufacturing process of emulsifier, Most Profitable emulsifier Processing Business Ideas, Nature and use of emulsifiers in foods, new small scale ideas in emulsifier processing industry, pharmaceutical application of emulsion, Procedure for Emulsification of Oil in Water Using Surfactants, Process of Polish Emulsions, Process technology book on emulsifier, role of emulsifier in emulsion, role of surfactant in emulsion, Starting an emulsifier Processing Business, types of food emulsifiers, Uses of emulsifiers, What is an Emulsifier?
Author: Peter A. Lovell
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 858
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Book Description
Emulsion Polymerization and Emulsion Polymers Edited by Peter A. Lovell Manchester Materials Science Centre, UMIST, Manchester, UK and Mohamed S. El-Aasser Emulsion Polymers Institute and Department of Chemical Engineering, Lehigh University, Bethlehem, PA, USA Emulsion polymerization is a technologically and commercially important reaction used to produce synthetic polymers and latexes for a wide range of applications. It is the basis of a massive global industry that is expanding due to the versatility of the reaction and the greater realization of the ability to control properties of the polymer latexes produced. Emulsion Polymerization and Emulsion Polymers provides an up-to-date treatment of both academic and industrial aspects of the subject in a single self-contained volume. Established knowledge is integrated with latest developments and introductory chapters to give a state-of-the-art summary which is also suitable as a broad based introduction to the field. The individual chapters have been written by specialists from academia and industry and are presented in a way which ensures that the book will be of equal value to experienced researchers and students.
