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Author: Adrien Albert
Publisher: Springer Science & Business Media
ISBN: 9400955480
Category : Science
Languages : en
Pages : 223
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Book Description
This practical manual is devised for organic chemists and biochemists who, in the course of their researches and without previous experience, need to determine an ionization constant. We are gratified that earlier editions were much used for this purpose and that they also proved adequate for the in service training of technicians and technical officers to provide a Department with a pK service. The features of previous editions that gave this wide appeal have been retained, but the subject matter has been revised, extended, and brought up to date. We present two new chapters, one of which describes the determination of the stability constants of the complexes which organic ligands form with metal cations. The other describes the use of more recently introduced techniques for the determination of ionization constants, such as Raman and nuclear magnetic resonance spectroscopy, thermometric titrations, and paper electro phoresis. Chapter 1 gives enhanced help in choosing between alternative methods for determining ionization constants. The two chapters on potentiometric methods have been extensively revised in the light of newer understanding of electrode processes and of the present state of the art in instrumen tation.
Author: Adrien Albert
Publisher: Springer Science & Business Media
ISBN: 9400955480
Category : Science
Languages : en
Pages : 223
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Book Description
This practical manual is devised for organic chemists and biochemists who, in the course of their researches and without previous experience, need to determine an ionization constant. We are gratified that earlier editions were much used for this purpose and that they also proved adequate for the in service training of technicians and technical officers to provide a Department with a pK service. The features of previous editions that gave this wide appeal have been retained, but the subject matter has been revised, extended, and brought up to date. We present two new chapters, one of which describes the determination of the stability constants of the complexes which organic ligands form with metal cations. The other describes the use of more recently introduced techniques for the determination of ionization constants, such as Raman and nuclear magnetic resonance spectroscopy, thermometric titrations, and paper electro phoresis. Chapter 1 gives enhanced help in choosing between alternative methods for determining ionization constants. The two chapters on potentiometric methods have been extensively revised in the light of newer understanding of electrode processes and of the present state of the art in instrumen tation.
Author: Institute for Numerical Analysis (U.S.)
Publisher:
ISBN:
Category : Approximate computation
Languages : en
Pages : 228
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Book Description
Author: J.W. Gorrod
Publisher: Elsevier
ISBN: 0080525512
Category : Science
Languages : en
Pages : 773
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Book Description
This book provides for the first time a single comprehensive source of information on the analytical chemistry of nicotine and related alkaloids. The editors have brought together scientists from academia and the tobacco industry to describe the state-of-the-art of the chemistry and analytical methods for measurement of nicotine. Both the scope and detail of the book are impressive. Chapters describe the history, pharmacology and toxicology of nicotine, the biosynthesis of nicotine and other alkaloids in the tobacco plant, the general chemistry of nicotine and the analytical methodologies that have been used to measure nicotine and related alkaloids in biological specimens, in tobacco and pharmaceutical products and in tobacco smoke. There is also a comprehensive review of the chemistry and toxicology of nicotine-derived nitrosamines, an important class of tobacco carcinogens.
Author: Ernö Pretsch
Publisher: Springer Science & Business Media
ISBN: 3662224550
Category : Science
Languages : en
Pages : 325
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Book Description
Although numerical data are, in principle, universal, the compilations presented in this book are extensively annotated and interleaved with text. This translation of the second German edition has been prepared to facilitate the use of this work, with all its valuable detail, by the large community of English-speaking scientists. Translation has also provided an opportunity to correct and revise the text, and to update the nomenclature. Fortunately, spectroscopic data and their relationship with structure do not change much with time so one can predict that this book will, for a long period of time, continue to be very useful to organic chemists involved in the identification of organic compounds or the elucidation of their structure. Klaus Biemann Cambridge, MA, April 1983 Preface to the First German Edition Making use of the information provided by various spectroscopic tech niques has become a matter of routine for the analytically oriented organic chemist. Those who have graduated recently received extensive training in these techniques as part of the curriculum while their older colleagues learned to use these methods by necessity. One can, therefore, assume that chemists are well versed in the proper choice of the methods suitable for the solution of a particular problem and to translate the experimental data into structural information.
Author: Hy Almond
Publisher:
ISBN:
Category : Geochemical prospecting
Languages : en
Pages : 376
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Book Description
Author: Heinrich Klüver
Publisher:
ISBN:
Category : Eidetic imagery
Languages : en
Pages : 636
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Book Description
Author: Régis Gras
Publisher: CRC Press
ISBN: 100381302X
Category : Mathematics
Languages : en
Pages : 259
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Book Description
This book summarizes the methods and concepts of Statistical Implicative Analysis (SIA), created by Régis Gras in the 1980s to study, in a new way, the behavioural responses of French pupils to mathematics tests. Using a multidimensional, non-symmetrical data analysis method, SIA crosses a set of subjects or objects with a set of variables. It effectively complements traditional correlational and psychometric methods. SIA, through its various extensions, is today presented as a broad Artificial Intelligence method aimed at extracting trends and possible causalities in the form of rules, from a set of variables. It is based on the unlikeliness of the existence of these relationships, i.e. on the relative weakness of their counter-examples compared to what chance alone would produce. It establishes a dual topological relationship between the set of subjects and the set of variables. Many applications of this approach, driving forces or crucibles for the development of SIA, have concerned and still concern various fields such as didactics, evaluation and assessment, psychology, sociology, medicine, biology, economics, art history, and others. Key Features: Presents the foundations and representations of SIA. Provides extensions of variable sets and subjects. Includes a bonus exercise.
Author: United States
Publisher:
ISBN:
Category : Law
Languages : en
Pages : 1390
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Book Description
Author: Dan Gabriel Cacuci
Publisher: Springer Nature
ISBN: 3030963640
Category : Science
Languages : en
Pages : 373
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Book Description
The computational models of physical systems comprise parameters, independent and dependent variables. Since the physical processes themselves are seldom known precisely and since most of the model parameters stem from experimental procedures which are also subject to imprecisions, the results predicted by these models are also imprecise, being affected by the uncertainties underlying the respective model. The functional derivatives (also called “sensitivities”) of results (also called “responses”) produced by mathematical/computational models are needed for many purposes, including: (i) understanding the model by ranking the importance of the various model parameters; (ii) performing “reduced-order modeling” by eliminating unimportant parameters and/or processes; (iii) quantifying the uncertainties induced in a model response due to model parameter uncertainties; (iv) performing “model validation,” by comparing computations to experiments to address the question “does the model represent reality?” (v) prioritizing improvements in the model; (vi) performing data assimilation and model calibration as part of forward “predictive modeling” to obtain best-estimate predicted results with reduced predicted uncertainties; (vii) performing inverse “predictive modeling”; (viii) designing and optimizing the system. This 3-Volume monograph describes a comprehensive adjoint sensitivity analysis methodology, developed by the author, which enables the efficient and exact computation of arbitrarily high-order sensitivities of model responses in large-scale systems comprising many model parameters. The qualifier “comprehensive” is employed to highlight that the model parameters considered within the framework of this methodology also include the system’s uncertain boundaries and internal interfaces in phase-space. The model’s responses can be either scalar-valued functionals of the model’s parameters and state variables (e.g., as customarily encountered in optimization problems) or general function-valued responses. Since linear operators admit bona-fide adjoint operators, responses of models that are linear in the state functions (i.e., dependent variables) can depend simultaneously on both the forward and the adjoint state functions. Hence, the sensitivity analysis of such responses warrants the treatment of linear systems in their own right, rather than treating them as particular cases of nonlinear systems. This is in contradistinction to responses for nonlinear systems, which can depend only on the forward state functions, since nonlinear operators do not admit bona-fide adjoint operators (only a linearized form of a nonlinear operator may admit an adjoint operator). Thus, Volume 1 of this book presents the mathematical framework of the nth-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Response-Coupled Forward/Adjoint Linear Systems (abbreviated as “nth-CASAM-L”), which is conceived for the most efficient computation of exactly obtained mathematical expressions of arbitrarily-high-order (nth-order) sensitivities of a generic system response with respect to all of the parameters underlying the respective forward/adjoint systems. Volume 2 of this book presents the application of the nth-CASAM-L to perform a fourth-order sensitivity and uncertainty analysis of an OECD/NEA reactor physics benchmark which is representative of a large-scale model comprises many (21,976) uncertain parameters, thereby amply illustrating the unique potential of the nth-CASAM-L to enable the exact and efficient computation of chosen high-order response sensitivities to model parameters. Volume 3 of this book presents the “nth-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Nonlinear Systems” (abbreviation: nth-CASAM-N) for the practical, efficient, and exact computation of arbitrarily-high order sensitivities of responses to model parameters for systems that are also nonlinear in their underlying state functions. Such computations are not feasible with any other methodology. The application of the nth-CASAM-L and the nth-CASAM-N overcomes the so-called “curse of dimensionality” in sensitivity and uncertainty analysis, thus revolutionizing all of the fields of activities which require accurate computation of response sensitivities. Since this monograph includes many illustrative, fully worked-out, paradigm problems, it can serve as a textbook or as supplementary reading for graduate courses in academic departments in the natural sciences and engineering.
Author: Iowa Engineering Experiment Station
Publisher:
ISBN:
Category : Engineering
Languages : en
Pages : 610
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Book Description
