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Author: I. Bertini
Publisher: Springer Science & Business Media
ISBN: 9400970498
Category : Science
Languages : en
Pages : 397
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Book Description
Assembling a program in bioinorganic chemistry that is scientifi cally relevant, well defined, and self-consistent is not an easy task. In this attempt we decided to consider zinc enzymes, copper oxidases, cytochromes and cytochrome oxidase. The choice is in part due to the great attention that the current specialized literature devotes to these topics, which are now debated among chemists, biochemists, biophysicists, etc .. We believe that hydration reactions, hydrolytic and oxidative processes have much in common from the point of view of the reaction mechanisms, the comprehension of which represents a frontier of science. For these reasons these topics have been the subject of the NATO-ASI held at San Miniato, Pisa, Italy, from May 28 to June 8, 1982. We hope we can transfer here the main conclusions of what (we believe) was a very stimulating scientific meeting. We would like to thank the local saving bank, Cassa di Risparmio di San Miniato, for helping in many ways. The financial contribution from the European Research Office of the US Army, and from the Bruker Spectrospin s.r.l., Italy, is also acknowledged. The National Science Foundation of the United States has provided a travel grant to one of the participants from the U.S.A. We are grateful to the NATO Scientific Affairs Division which provided a grant to finance this Institute.
Author: I. Bertini
Publisher: Springer Science & Business Media
ISBN: 9400970498
Category : Science
Languages : en
Pages : 397
Get Book Here
Book Description
Assembling a program in bioinorganic chemistry that is scientifi cally relevant, well defined, and self-consistent is not an easy task. In this attempt we decided to consider zinc enzymes, copper oxidases, cytochromes and cytochrome oxidase. The choice is in part due to the great attention that the current specialized literature devotes to these topics, which are now debated among chemists, biochemists, biophysicists, etc .. We believe that hydration reactions, hydrolytic and oxidative processes have much in common from the point of view of the reaction mechanisms, the comprehension of which represents a frontier of science. For these reasons these topics have been the subject of the NATO-ASI held at San Miniato, Pisa, Italy, from May 28 to June 8, 1982. We hope we can transfer here the main conclusions of what (we believe) was a very stimulating scientific meeting. We would like to thank the local saving bank, Cassa di Risparmio di San Miniato, for helping in many ways. The financial contribution from the European Research Office of the US Army, and from the Bruker Spectrospin s.r.l., Italy, is also acknowledged. The National Science Foundation of the United States has provided a travel grant to one of the participants from the U.S.A. We are grateful to the NATO Scientific Affairs Division which provided a grant to finance this Institute.
Author: Ivano Bertini
Publisher: Springer My Copy UK
ISBN: 9789400970502
Category : Coordination compounds
Languages : en
Pages : 416
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Book Description
Author: BERTINI, I (ED.)
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Joseph J. Stephanos
Publisher: John Wiley & Sons
ISBN: 1118801520
Category : Science
Languages : en
Pages : 500
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Book Description
Addresses the full gamut of questions in metalloprotein science Formatted as a question-and-answer guide, this book examines all major families of metal binding proteins, presenting our most current understanding of their structural, physicochemical, and functional properties. Moreover, it introduces new and emerging medical applications of metalloproteins. Readers will discover both the underlying chemistry and biology of this important area of research in bioinorganic chemistry. Chemistry of Metalloproteins features a building block approach that enables readers to master the basics and then advance to more sophisticated topics. The book begins with a general introduction to bioinorganic chemistry and metalloproteins. Next, it covers: Alkali and alkaline earth cations Metalloenzymes Copper proteins Iron proteins Vitamin B12 Chlorophyll Chapters are richly illustrated to help readers fully grasp all the chemical concepts that govern the biological action of metalloproteins. In addition, each chapter ends with a list of suggested original research articles and reviews for further investigation of individual topics. Presenting our most current understanding of metalloproteins, Chemistry of Metalloproteins is recommended for students and researchers in coordination chemistry, biology, and medicine. Each volume of the Wiley Series in Protein and Peptide Science addresses a specific facet of the field, reviewing the latest findings and presenting a broad range of perspectives. The volumes in this series constitute essential reading for biochemists, biophysicists, molecular biologists, geneticists, cell biologists, and physiologists as well as researchers in drug design and development, proteomics, and molecular medicine with an interest in proteins and peptides.
Author: Alexander D. Garnovskii
Publisher: CRC Press
ISBN: 9780203911525
Category : Science
Languages : en
Pages : 536
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Book Description
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Author: D. A. Brown
Publisher: Butterworth-Heinemann
ISBN: 1483155765
Category : Science
Languages : en
Pages : 131
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Book Description
Coordination Chemistry XVI is a compendium of papers that deals with structured absorption band, intra-molecular electron transfer, and the influence of natural and synthetic ligands on the transport and function of metal ions in the environment. Experiments show that the chemical, spectral and kinetic results of the physical state of an enzyme can be a significant experimental variable that will change function-related-conformations. Another paper points out the dangers of assigning weakly structured bands to partially resolved vibrations, to lower symmetry, to spin-orbit coupling, and to the Jahn-Teller effects. One paper deals with intra-molecular electron transfer in three manifestations: 1) in traditional oxidation-reduction reactions; 2) in induced electron transfer; and 3) in mixed valence complexes. Another paper discusses the reactivity of polynuclear metal complexes involving metal-metal bonds with simple inorganic and organic molecules, particularly, polynuclear aggregates' basic structural forms and polynuclear's fluxional nature. One paper investigates the environmental effects of coordination compounds that disturb the natural balance and levels of metal ions and metal complexes in the ecosystem. The paper cites examples of pollutions caused by abnormal amounts of metal salts and metal complexes introduced in the ecosystem, and the presence of synthetic ligands or abnormal levels of natural ligands in the environment. The compendium is suitable for analytical and organic chemists, chemical engineers, environmentalists, and students of biochemistry.
Author: John L Burmeister
Publisher: World Scientific
ISBN: 9814488003
Category : Science
Languages : en
Pages : 654
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Book Description
This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Author: Fred Basolo
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 200
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Book Description
Author: P. L. Soni
Publisher: CRC Press
ISBN: 9781466500501
Category : Science
Languages : en
Pages : 0
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Book Description
This book has been written in a simple and lucid language to help students understand the intricate theories of co-ordination chemistry. Divided into two parts, the first part reviews all the recent developments in the fields of organometallics and co-ordination chemistry. The second part deals with transition and inner transition metals including the study of f-block elements. It was developed with a focus on the need to demystify coordination complexes and transition metals.
Author: Geoffrey A. Lawrance
Publisher: Wiley
ISBN: 9781394190713
Category : Science
Languages : en
Pages : 0
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Book Description
An accessible introduction to one of the primary fields of study in Inorganic Chemistry, revised to incorporate contemporary topics and applications Written in a highly readable, descriptive, and accessible style, Introduction to Coordination Chemistry examines and explains the interaction between metals and molecules that bind as ligands and the consequences of this assembly process. The book describes the chemical and physical properties and behavior of these complex assemblies and their applications The contents of this book tell a story, taking the reader from fundamentals, including metal ions, ligands, metal-ligand bonding, and structure, to key concepts, such as stability, synthesis and mechanisms, properties, and characterization. Subsequent chapters address applications involving metals in biology, medicine, and industrial chemistry. Written by two highly qualified academics, this newly revised Second Edition of Introduction to Coordination Chemistry has been thoroughly updated to include full-color images throughout, as well as now including: Information on instrument-based experimental methods to reflect the increasing use of sophisticated, commercially available instruments in laboratory teaching An expansion of the chapter Metals in Biology showing key developments in the vast field of metalloproteins and metalloenzymes An updated description of polymetallic compounds and new discussions of metal-containing nanomolecules pertinent to advancements in nanotechnology An expanded discussion of organometallic compounds and catalysts and updating of Concept Keys to summarize key topics and further reading at the end of each chapter Introduction to Coordination Chemistry is an ideal textbook resource for undergraduate inorganic chemistry students in their second or third year or at the intermediate level who have completed a general introductory chemistry course and are moving to a first specialist course in coordination chemistry.
