Author: Zvi Rappoport
Publisher: John Wiley & Sons
ISBN: 1118438736
Category : Science
Languages : en
Pages : 1158
Book Description
The first book in the PATAI Series was published in 1964 and the Series will celebrate its 50th Anniversary in 2014. This "Golden Jubilee" is accompanied by the publication of the first volume on the chemistry of organogold. In the history of the PATAI Series there was, so far, no volume dedicated to gold alone. In 1999 we published a volume on The Chemistry of Gold and Silver Compounds. Since then a lot of new chemistry using gold has been developed and it is timely to focus a volume on methods and applications of organogold compounds in organic synthesis, reflecting the enormous progress which has been made in the use of gold compounds as reagents and catalysts. A second area of great importance covered in the book is the use of gold surfaces in the synthesis of peptides, proteins and other natural products. A whole range of applications in the area of biochemistry has resulted from these developments. A third area of interest is the synthesis and engineering of nanostructures, where organogold chemistry has opened the door for a wide range of methods and applications in the field of nanoscience and materials science. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
The Chemistry of Organogold Compounds, 2 Volume Set
Author: Zvi Rappoport
Publisher: John Wiley & Sons
ISBN: 1118438736
Category : Science
Languages : en
Pages : 1158
Book Description
The first book in the PATAI Series was published in 1964 and the Series will celebrate its 50th Anniversary in 2014. This "Golden Jubilee" is accompanied by the publication of the first volume on the chemistry of organogold. In the history of the PATAI Series there was, so far, no volume dedicated to gold alone. In 1999 we published a volume on The Chemistry of Gold and Silver Compounds. Since then a lot of new chemistry using gold has been developed and it is timely to focus a volume on methods and applications of organogold compounds in organic synthesis, reflecting the enormous progress which has been made in the use of gold compounds as reagents and catalysts. A second area of great importance covered in the book is the use of gold surfaces in the synthesis of peptides, proteins and other natural products. A whole range of applications in the area of biochemistry has resulted from these developments. A third area of interest is the synthesis and engineering of nanostructures, where organogold chemistry has opened the door for a wide range of methods and applications in the field of nanoscience and materials science. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Publisher: John Wiley & Sons
ISBN: 1118438736
Category : Science
Languages : en
Pages : 1158
Book Description
The first book in the PATAI Series was published in 1964 and the Series will celebrate its 50th Anniversary in 2014. This "Golden Jubilee" is accompanied by the publication of the first volume on the chemistry of organogold. In the history of the PATAI Series there was, so far, no volume dedicated to gold alone. In 1999 we published a volume on The Chemistry of Gold and Silver Compounds. Since then a lot of new chemistry using gold has been developed and it is timely to focus a volume on methods and applications of organogold compounds in organic synthesis, reflecting the enormous progress which has been made in the use of gold compounds as reagents and catalysts. A second area of great importance covered in the book is the use of gold surfaces in the synthesis of peptides, proteins and other natural products. A whole range of applications in the area of biochemistry has resulted from these developments. A third area of interest is the synthesis and engineering of nanostructures, where organogold chemistry has opened the door for a wide range of methods and applications in the field of nanoscience and materials science. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
The Chemistry of Organoboron Compounds, 2 Volume Set
Author:
Publisher: John Wiley & Sons
ISBN: 1119518040
Category : Science
Languages : en
Pages : 1205
Book Description
Das führende Referenzwerk für die bororganische Chemie Professor Mark Gandelman und seine Kollegen tauchen tief in die Theorie, Struktur, Analyse, Synthese und Reaktionen der bororganischen Chemie ein. Bororganische Verbindungen kommen als hocheffiziente Reagenzien bei vielen Reaktionen zum Einsatz, darunter bei Kreuzkupplungen und Radikal-Reaktionen. Die renommierten Autoren führen ihr Wissen der organischen und physikalischen Chemie in einem Werk zusammen. In der Regel stammen diese Informationen aus unterschiedlichen Quellen. Dieses Buch konzentriert sich auf vollständig biologisch abbaubare Reagenzien als Gegenpart zu umweltschädlichen Schwermetallkatalysatoren. The Chemistry of Organoboron Compounds bietet umfassende und ausführliche Informationen zu - dem Verhalten bororganischer Verbindungen, - dem Einsatz bororganischer Verbindungen in der organischen Synthese, - kommerziellen Anwendungen bororganischer Verbindungen. The Chemistry of Organoboron Compounds aus der gefeierten Reihe Patai's Chemistry of Functional Groups bietet alle Merkmale, die Leser von der Reihe gewohnt sind, auch ein ausführliches Stichwortverzeichnis.
Publisher: John Wiley & Sons
ISBN: 1119518040
Category : Science
Languages : en
Pages : 1205
Book Description
Das führende Referenzwerk für die bororganische Chemie Professor Mark Gandelman und seine Kollegen tauchen tief in die Theorie, Struktur, Analyse, Synthese und Reaktionen der bororganischen Chemie ein. Bororganische Verbindungen kommen als hocheffiziente Reagenzien bei vielen Reaktionen zum Einsatz, darunter bei Kreuzkupplungen und Radikal-Reaktionen. Die renommierten Autoren führen ihr Wissen der organischen und physikalischen Chemie in einem Werk zusammen. In der Regel stammen diese Informationen aus unterschiedlichen Quellen. Dieses Buch konzentriert sich auf vollständig biologisch abbaubare Reagenzien als Gegenpart zu umweltschädlichen Schwermetallkatalysatoren. The Chemistry of Organoboron Compounds bietet umfassende und ausführliche Informationen zu - dem Verhalten bororganischer Verbindungen, - dem Einsatz bororganischer Verbindungen in der organischen Synthese, - kommerziellen Anwendungen bororganischer Verbindungen. The Chemistry of Organoboron Compounds aus der gefeierten Reihe Patai's Chemistry of Functional Groups bietet alle Merkmale, die Leser von der Reihe gewohnt sind, auch ein ausführliches Stichwortverzeichnis.
The Chemistry of Hypervalent Halogen Compounds, 2 Volume Set
Author: Berit Olofsson
Publisher: John Wiley & Sons
ISBN: 1119352304
Category : Science
Languages : en
Pages : 1068
Book Description
Für das Verständnis der organischen Chemie muss man wissen, worum es sich bei funktionalen Gruppen handelt. Dieses Fachbuch steht ganz in der Tradition der Reihe Patai's Chemistry of Functional Groups. Jeder Band deckt sämtliche Aspekte funktionaler Gruppen ab und behandelt dabei theoretische, analytische, synthetische, biologische Aspekte sowie Belange der Industrie. Hypervalente Halogenverbindungen, insbesondere Jodverbindungen, sind überaus effiziente und selektive Oxidantien für eine Vielzahl funktionaler Gruppen. Die elektrophilen Eigenschaften dieser Reagenzien können auch für die Einführung anderer Funktionalisierungen verwendet werden. Dieser Band ist der erste in der Reihe, die die Eigenschaften und das chemische Verhalten von hypervalentem Jod und Brom, deren Einsatz in der organischen Synthese sowie deren industrielle Anwendung untersucht. Wie bei allen neuen Bänden, werden die Kapitel zunächst online in Patai's Chemistry of Functional Groups veröffentlicht. Wenn ein Band online vervollständigt ist, erfolgt die Herausgabe als Printversion. Die Printfassung entspricht der Qualität, die man von der Patai-Reihe kennt, und bietet auch einen umfassenden Index.
Publisher: John Wiley & Sons
ISBN: 1119352304
Category : Science
Languages : en
Pages : 1068
Book Description
Für das Verständnis der organischen Chemie muss man wissen, worum es sich bei funktionalen Gruppen handelt. Dieses Fachbuch steht ganz in der Tradition der Reihe Patai's Chemistry of Functional Groups. Jeder Band deckt sämtliche Aspekte funktionaler Gruppen ab und behandelt dabei theoretische, analytische, synthetische, biologische Aspekte sowie Belange der Industrie. Hypervalente Halogenverbindungen, insbesondere Jodverbindungen, sind überaus effiziente und selektive Oxidantien für eine Vielzahl funktionaler Gruppen. Die elektrophilen Eigenschaften dieser Reagenzien können auch für die Einführung anderer Funktionalisierungen verwendet werden. Dieser Band ist der erste in der Reihe, die die Eigenschaften und das chemische Verhalten von hypervalentem Jod und Brom, deren Einsatz in der organischen Synthese sowie deren industrielle Anwendung untersucht. Wie bei allen neuen Bänden, werden die Kapitel zunächst online in Patai's Chemistry of Functional Groups veröffentlicht. Wenn ein Band online vervollständigt ist, erfolgt die Herausgabe als Printversion. Die Printfassung entspricht der Qualität, die man von der Patai-Reihe kennt, und bietet auch einen umfassenden Index.
The Chemistry of Peroxides, Volume 3
Author:
Publisher: John Wiley & Sons
ISBN: 1118412710
Category : Science
Languages : en
Pages : 957
Book Description
The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Publisher: John Wiley & Sons
ISBN: 1118412710
Category : Science
Languages : en
Pages : 957
Book Description
The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Chemistry of Precious Metals
Author: S.A. Cotton
Publisher: Springer Science & Business Media
ISBN: 9400914636
Category : Science
Languages : en
Pages : 386
Book Description
Some 20 years ago, I was privileged to share in writing a book on the descriptive chemistry of the 4d, 5d, 4f and 5f metals that included these eight elements within its compass (S.A. Cotton and F.A. Hart, The Heavy Transition Elements, Macmillan, 1975). This volume shares the same aim of covering the descriptive chemistry of silver, gold and the six platinum metals in some detail at a level suitable for advanced undergraduate and postgraduate study. It does not attempt to be a comprehensive treatise on the chemistry of these metals. It attempts to fill a slot between the general text and the in-depth review or monograph. The organometallic chemistry is confined to a-bonded com pounds in normal oxidation states; compounds with IT-bonding ligands are generally excluded. Their inclusion would have increased the length of the book considerably and, moreover, their recent chemistry has been extensively and expertly reviewed in the new Comprehensive Organometallic Chemistry, II, eds G. Wilkinson, F.G.A. Stone and E.W. Abel, Pergamon, Oxford, 1995.
Publisher: Springer Science & Business Media
ISBN: 9400914636
Category : Science
Languages : en
Pages : 386
Book Description
Some 20 years ago, I was privileged to share in writing a book on the descriptive chemistry of the 4d, 5d, 4f and 5f metals that included these eight elements within its compass (S.A. Cotton and F.A. Hart, The Heavy Transition Elements, Macmillan, 1975). This volume shares the same aim of covering the descriptive chemistry of silver, gold and the six platinum metals in some detail at a level suitable for advanced undergraduate and postgraduate study. It does not attempt to be a comprehensive treatise on the chemistry of these metals. It attempts to fill a slot between the general text and the in-depth review or monograph. The organometallic chemistry is confined to a-bonded com pounds in normal oxidation states; compounds with IT-bonding ligands are generally excluded. Their inclusion would have increased the length of the book considerably and, moreover, their recent chemistry has been extensively and expertly reviewed in the new Comprehensive Organometallic Chemistry, II, eds G. Wilkinson, F.G.A. Stone and E.W. Abel, Pergamon, Oxford, 1995.
The Chemistry of Organocobalt Compounds
Author: Corinne Gosmini
Publisher: John Wiley & Sons
ISBN: 1119692016
Category : Science
Languages : en
Pages : 580
Book Description
The Chemistry of Organocobalt Compounds R–Co PATAI’s Chemistry of Functional Groups The Chemistry of Organocobalt Compounds A series of advanced treatises founded by Professor Saul Patai and now under the general editorship of Professors Ilan Marek and Joel F. Liebman PATAI’s Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical, and environmental aspects. To date, over 150 volumes have been published in the series. Recently Published Titles The Chemistry of Cyclobutanes (2 parts) The Chemistry of Peroxides (Volume 2, 2 parts) The Chemistry of Organozinc Compounds (2 parts) The Chemistry of Anilines (2 parts) The Chemistry of Organomagnesium Compounds (2 parts) The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (2 volumes, 4 parts) The Chemistry of Metal Enolates (2 parts) The Chemistry of Organocopper Compounds (2 parts) The Chemistry of Organomanganese Compounds The Chemistry of Organic Selenium and Tellurium Compounds (Volume 3, 2 parts) The Chemistry of Organic Selenium and Tellurium Compounds (Volume 4, 2 parts) The Chemistry of Organoiron Compounds The Chemistry of Metal Phenolates The Chemistry of Peroxides (Volume 3, 2 parts) The Chemistry of Organogold Compounds (2 parts) The Chemistry of Organoaluminum Compounds The Chemistry of Metal Enolates (Volume 2) The Chemistry of Metal Phenolates (Volume 2) The Chemistry of Hypervalent Halogen Compounds (2 parts) The Chemistry of Nitrogen-rich Functional Groups The Chemistry of Organoboron Compounds (2 parts) Forthcoming Titles The Chemistry of Nitrogen-rich Functional Groups (Volume 2) The Chemistry of Organofluorine Compounds PATAI Online PATAI’s Chemistry of Functional Groups is available in electronic format on Wiley Online Library.
Publisher: John Wiley & Sons
ISBN: 1119692016
Category : Science
Languages : en
Pages : 580
Book Description
The Chemistry of Organocobalt Compounds R–Co PATAI’s Chemistry of Functional Groups The Chemistry of Organocobalt Compounds A series of advanced treatises founded by Professor Saul Patai and now under the general editorship of Professors Ilan Marek and Joel F. Liebman PATAI’s Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical, and environmental aspects. To date, over 150 volumes have been published in the series. Recently Published Titles The Chemistry of Cyclobutanes (2 parts) The Chemistry of Peroxides (Volume 2, 2 parts) The Chemistry of Organozinc Compounds (2 parts) The Chemistry of Anilines (2 parts) The Chemistry of Organomagnesium Compounds (2 parts) The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (2 volumes, 4 parts) The Chemistry of Metal Enolates (2 parts) The Chemistry of Organocopper Compounds (2 parts) The Chemistry of Organomanganese Compounds The Chemistry of Organic Selenium and Tellurium Compounds (Volume 3, 2 parts) The Chemistry of Organic Selenium and Tellurium Compounds (Volume 4, 2 parts) The Chemistry of Organoiron Compounds The Chemistry of Metal Phenolates The Chemistry of Peroxides (Volume 3, 2 parts) The Chemistry of Organogold Compounds (2 parts) The Chemistry of Organoaluminum Compounds The Chemistry of Metal Enolates (Volume 2) The Chemistry of Metal Phenolates (Volume 2) The Chemistry of Hypervalent Halogen Compounds (2 parts) The Chemistry of Nitrogen-rich Functional Groups The Chemistry of Organoboron Compounds (2 parts) Forthcoming Titles The Chemistry of Nitrogen-rich Functional Groups (Volume 2) The Chemistry of Organofluorine Compounds PATAI Online PATAI’s Chemistry of Functional Groups is available in electronic format on Wiley Online Library.
Sb Organoantimony Compounds
Author: Marlies Mirbach
Publisher: Springer Science & Business Media
ISBN: 3662063123
Category : Science
Languages : en
Pages : 421
Book Description
This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatment of pentavalent compounds with three Sb-C bonds began in Part 4 with the RSbX type and is now completed with types RSb(X)Y, RR'SbX, RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX (Section 2.5.1) and the corresponding bi- and trinuclear compounds (Sec 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote different organic groups bonded through carbon to the antimony atom. X and Y represent inorganic or organic groups that are bonded to antimony by an atom other than carbon. R, X, and/or Y can also be chelating ligands. The remaining part of the volume completeLy covers all pentavalent antimony compounds containing two Sb-C bonds (RSbX, RSb(X)Y, RR'SbX, RR'Sb(X)Y, bi- and tetranucLear 2 3 2 2 3 2 compounds, Chapter 2.6, p. 134) and those containing one Sb-C bond (RSbX, RSb(X)Y, 4 3 RSb(X)Y, bi- and trinucLear compounds, Chapter 2.7, p. 237). These compounds form ad 2 2 ducts with Lewis bases (symbol D) and form many ionic compLexes by the addition of saLts such as amine hydrochLorides (symbol MZ). The adducts and ionic compLexes are described immediately after the parent substances. The volume concludes with an Empirical Formula Index (p. 318) and a Ligand Formula Index (p. 357).
Publisher: Springer Science & Business Media
ISBN: 3662063123
Category : Science
Languages : en
Pages : 421
Book Description
This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatment of pentavalent compounds with three Sb-C bonds began in Part 4 with the RSbX type and is now completed with types RSb(X)Y, RR'SbX, RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX (Section 2.5.1) and the corresponding bi- and trinuclear compounds (Sec 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote different organic groups bonded through carbon to the antimony atom. X and Y represent inorganic or organic groups that are bonded to antimony by an atom other than carbon. R, X, and/or Y can also be chelating ligands. The remaining part of the volume completeLy covers all pentavalent antimony compounds containing two Sb-C bonds (RSbX, RSb(X)Y, RR'SbX, RR'Sb(X)Y, bi- and tetranucLear 2 3 2 2 3 2 compounds, Chapter 2.6, p. 134) and those containing one Sb-C bond (RSbX, RSb(X)Y, 4 3 RSb(X)Y, bi- and trinucLear compounds, Chapter 2.7, p. 237). These compounds form ad 2 2 ducts with Lewis bases (symbol D) and form many ionic compLexes by the addition of saLts such as amine hydrochLorides (symbol MZ). The adducts and ionic compLexes are described immediately after the parent substances. The volume concludes with an Empirical Formula Index (p. 318) and a Ligand Formula Index (p. 357).
Ni Organonickel Compounds
Author: Peter W. Jolly
Publisher: Springer Science & Business Media
ISBN: 3662075334
Category : Science
Languages : en
Pages : 394
Book Description
This volume starts the updating of the information on organonickel chemistry, one of the most active areas of modern organometallic chemistry. It covers all mononuclear compounds containing one nickel-to-carbon bond. The main part is devoted to the family of planar NiII compounds, RNi(D)2X, which within 20 years has increased from about 250 to more than 1000 members. This research interest has been stimulated by the fact that many compounds insert various unsaturated species into the Ni-C bond to create new organonickel species. Moreover, these compounds are important as intermediates in many catalytic processes involving organic halides. Compounds containing h*2-bonded heteroalkene molecules including the C1 fragments CO2 and CS2, and related metallocyclic compounds are also emphasized in this volume. These types of compounds play an important role in a number of nickel-catalyzed co-oligomerization reactions involving unsaturated organic compounds. Most of the compounds are well-characterized by modern spectroscopic techniques. The various types of compounds are in most cases confirmed by X-ray diffraction. The author of these volumes, a member of the M lheim group, has made many contributions of his own and is eminently qualified to critically review this area of research.
Publisher: Springer Science & Business Media
ISBN: 3662075334
Category : Science
Languages : en
Pages : 394
Book Description
This volume starts the updating of the information on organonickel chemistry, one of the most active areas of modern organometallic chemistry. It covers all mononuclear compounds containing one nickel-to-carbon bond. The main part is devoted to the family of planar NiII compounds, RNi(D)2X, which within 20 years has increased from about 250 to more than 1000 members. This research interest has been stimulated by the fact that many compounds insert various unsaturated species into the Ni-C bond to create new organonickel species. Moreover, these compounds are important as intermediates in many catalytic processes involving organic halides. Compounds containing h*2-bonded heteroalkene molecules including the C1 fragments CO2 and CS2, and related metallocyclic compounds are also emphasized in this volume. These types of compounds play an important role in a number of nickel-catalyzed co-oligomerization reactions involving unsaturated organic compounds. Most of the compounds are well-characterized by modern spectroscopic techniques. The various types of compounds are in most cases confirmed by X-ray diffraction. The author of these volumes, a member of the M lheim group, has made many contributions of his own and is eminently qualified to critically review this area of research.
Ge Organogermanium Compounds
Author: John E. Drake
Publisher: Springer Science & Business Media
ISBN: 3662063247
Category : Science
Languages : en
Pages : 378
Book Description
The present volume in the organogermanium series describes mononuclear compounds containing only germanium-carbon and germanium-hydrogen bonds (Chapter 1.3). Germanium hydrides with other additional non-carbon ligands, such as halogen or oxygen bonded groups, appear in later chapters according to the Gmelin principle of the last posi tion. Compounds with Ge-H and Ge-O bonds have already been described in Volume 5, Section 1.5.1.4, pp. 50/62. The present volume covers the literature to the end of 1992 and includes many references up to 1994. The nomenclature recommended by IUPAC has been generally adhered to. However, compound names were largely avoided, as most of the compounds are presented in tables and are only identified by their formulas. Many of the data in the tables appear in abbreviated form without units; general explanations are given on pp. X/XI. The volume contains an empirical formula index (p. 327) and a ligand formula index (p.341). The editor wishes to express his gratitude to the former author, Professor J. E. Drake, and to Professor J. Satge for his kind advice and fruitful collaboration. Thanks are due also to Dr. A. R. Pebler for editing the English text and to Mr. H.-G. Karrenberg for drawing the numerous formulas and molecular structures.
Publisher: Springer Science & Business Media
ISBN: 3662063247
Category : Science
Languages : en
Pages : 378
Book Description
The present volume in the organogermanium series describes mononuclear compounds containing only germanium-carbon and germanium-hydrogen bonds (Chapter 1.3). Germanium hydrides with other additional non-carbon ligands, such as halogen or oxygen bonded groups, appear in later chapters according to the Gmelin principle of the last posi tion. Compounds with Ge-H and Ge-O bonds have already been described in Volume 5, Section 1.5.1.4, pp. 50/62. The present volume covers the literature to the end of 1992 and includes many references up to 1994. The nomenclature recommended by IUPAC has been generally adhered to. However, compound names were largely avoided, as most of the compounds are presented in tables and are only identified by their formulas. Many of the data in the tables appear in abbreviated form without units; general explanations are given on pp. X/XI. The volume contains an empirical formula index (p. 327) and a ligand formula index (p.341). The editor wishes to express his gratitude to the former author, Professor J. E. Drake, and to Professor J. Satge for his kind advice and fruitful collaboration. Thanks are due also to Dr. A. R. Pebler for editing the English text and to Mr. H.-G. Karrenberg for drawing the numerous formulas and molecular structures.
Be Organoberyllium Compounds
Author: Hubert Schmidbaur
Publisher: Springer Science & Business Media
ISBN: 3662060248
Category : Science
Languages : en
Pages : 261
Book Description
The present volume describes organoberyllium compounds containing at least one berylli um-carbon bond, except the beryllium carbides and cyanides. It covers the literature com pletely to the end of 1986 and includes most of the references up to mid-1987. This Gmelin volume is different from all other volumes of the series on organometallic compounds in that it is dedicated to an area of research which has virtually come to a complete standstill. Organoberyllium chemistry has never been a very popular field, and only few workers have contributed to its slow growth, as is seen by the relatively small number of publications in the field. This very modest development became stagnant in the early 1970's and was followed by a rapid decline. This exceptional fate of a branch of organometallic chemistry is only partly due to the very limited number of potential application~ of beryllium and its compounds. The compounds of this element are, in principle, at least as interesting and intriguing to scientists as those of other metals in the Periodic Table. No doubt the main reason for the apparent ban of all experimental organoberyllium chemistry is to be found in the established, and alleged, hazardous properties of beryllium compounds. Although similar hazards have been established for other organometallics where active research is still in process, e. g. , mercury and lead, these observations were absolutely lethaI for organoberyllium research.
Publisher: Springer Science & Business Media
ISBN: 3662060248
Category : Science
Languages : en
Pages : 261
Book Description
The present volume describes organoberyllium compounds containing at least one berylli um-carbon bond, except the beryllium carbides and cyanides. It covers the literature com pletely to the end of 1986 and includes most of the references up to mid-1987. This Gmelin volume is different from all other volumes of the series on organometallic compounds in that it is dedicated to an area of research which has virtually come to a complete standstill. Organoberyllium chemistry has never been a very popular field, and only few workers have contributed to its slow growth, as is seen by the relatively small number of publications in the field. This very modest development became stagnant in the early 1970's and was followed by a rapid decline. This exceptional fate of a branch of organometallic chemistry is only partly due to the very limited number of potential application~ of beryllium and its compounds. The compounds of this element are, in principle, at least as interesting and intriguing to scientists as those of other metals in the Periodic Table. No doubt the main reason for the apparent ban of all experimental organoberyllium chemistry is to be found in the established, and alleged, hazardous properties of beryllium compounds. Although similar hazards have been established for other organometallics where active research is still in process, e. g. , mercury and lead, these observations were absolutely lethaI for organoberyllium research.