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Author: John R. Chipperfield
Publisher: Oxford University Press on Demand
ISBN: 9780198502593
Category : Science
Languages : en
Pages : 86
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Book Description
Solvents other than water are used in chemical analysis, chemical manufacturing, and in specialized syntheses. This book covers the principles and uses of non-aqueous solvents at a level suitable for first or second-year undergraduates. The book first discusses the general properties of solvents, and introduces the necessary concepts for making rational choices of solvents for different applications. There is a discussion of the various chemical interactions between solvents and the substances dissolved in them, and how solvents change the course of reactions. The chemistry of 16 common solvents is discussed, emphasizing the advantages and disadvantages of each. The book concludes with an account of the chemistry of molten salts and discusses the use of low melting temperature compounds as synthetic media. The book expands on the brief treatment of non-aqueous solvents given in many textbooks while avoiding the complexities introduced in research treatises. It is the only book currently available that provides an in-depth treatment accessible to undergraduates.
Author: John R. Chipperfield
Publisher: Oxford University Press on Demand
ISBN: 9780198502593
Category : Science
Languages : en
Pages : 86
Get Book Here
Book Description
Solvents other than water are used in chemical analysis, chemical manufacturing, and in specialized syntheses. This book covers the principles and uses of non-aqueous solvents at a level suitable for first or second-year undergraduates. The book first discusses the general properties of solvents, and introduces the necessary concepts for making rational choices of solvents for different applications. There is a discussion of the various chemical interactions between solvents and the substances dissolved in them, and how solvents change the course of reactions. The chemistry of 16 common solvents is discussed, emphasizing the advantages and disadvantages of each. The book concludes with an account of the chemistry of molten salts and discusses the use of low melting temperature compounds as synthetic media. The book expands on the brief treatment of non-aqueous solvents given in many textbooks while avoiding the complexities introduced in research treatises. It is the only book currently available that provides an in-depth treatment accessible to undergraduates.
Author: Kosuke Izutsu
Publisher: John Wiley & Sons
ISBN: 9783527629169
Category : Science
Languages : en
Pages : 432
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Book Description
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Author: Victor Gutmann
Publisher: Springer Science & Business Media
ISBN: 3709181941
Category : Science
Languages : en
Pages : 181
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Book Description
Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.
Author: K. Burger
Publisher: Elsevier
ISBN: 0444597514
Category : Science
Languages : en
Pages : 269
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Book Description
Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
Author: Arthur Kenneth Holliday
Publisher: Pergamon
ISBN:
Category : Science
Languages : en
Pages : 172
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Book Description
Author: B. Trémillon
Publisher: Springer Science & Business Media
ISBN: 9401021236
Category : Science
Languages : en
Pages : 291
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Book Description
Arising no doubt from its pre-eminence as a natural liquid, water has always been considered by chemists as the original solvent in which very varied chemical reactions can take place, both for preparational and for analytical purposes. This explains the very long-standing interest shown in the study of aqueous solutions. In this con nection, it must be stressed that the theory of Arrhenius and Ostwald (1887-1894) on electrolytic dissociation, was originally devised solely for solutions in water and that the first true concept of acidity resulting from this is linked to the use of this solvent. The more recent development of numerous physico-chemical measurement methods has made possible an increase of knowledge in this area up to an extremely advanced degree of systematization. Thus today we have available both a very large amount of experimental data, together with very refined methods of deduction and of quantitative treatment of chemical reactions in solution which enable us to make the fullest use of this data. Nevertheless, . it appears quite evident at present that there are numerous chemical processes which cannot take place in water, and that its use as a solvent imposes 2 INTRODUCTION limitations. In order to overcome these limitations, it was natural that interest should be attracted to solvents other than water and that the new possibilities thus opened up should be explored.
Author: P.G.T. Fogg
Publisher: Elsevier
ISBN: 1483287432
Category : Science
Languages : en
Pages : 502
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Book Description
Solubility Data Series, Volume 50: Carbon Dioxide in Non-Aqueous Solvents at Pressures Less Than 200 kPa contains evaluated data for the solubility in non-aqueous solvents of carbon dioxide at a partial pressure not greater than 200 kPa. The Solubility Data Series is a project of Commission V.8 (Solubility Data) of the International Union of Pure and Applied Chemistry (IUPAC). The text has as its goal the preparation of a comprehensive and critical compilation of data on solubilities in all physical systems, including gases, liquids and solids. Chapters are devoted to providing data on the solubility of carbon dioxide in compounds such as alkanes, cyclic alkanes and alkenes, alcohols, solvents, other than alcohols, containing carbon, hydrogen and oxygen, and animal and vegetable oils and fats. Chemists will find the text extremely useful.
Author: Thomas C. Waddington
Publisher:
ISBN: 9780177717000
Category : Nonaqueous solvents
Languages : en
Pages : 88
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Book Description
Author: A. Covington
Publisher: Springer Science & Business Media
ISBN: 1468419595
Category : Science
Languages : en
Pages : 821
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Book Description
We believe this to be the first monograph devoted to the physicochemical properties of solutions in organic solvent systems. Although there have 1 been a number of books on the subject of non-aqueous solvents - 4, they have been devoted, almost entirely, to inorganic solvents such as liquid ammonia, liquid sulphur dioxide, etc. A variety of new solvents such as dimethylformamide, dimethylsulphoxide and propylene carbonate have become commercially available over the last twenty years. Solutions in these solvents are of technological interest in connection with novel battery systems and chemical synthesis, while studies of ion solvation and transport properties have fostered academic interest. This monograph is primarily concerned with electrolytic solutions although discussion of non-electrolyte solutions has not been excluded. We have deliberately omitted consideration of the important area of solvent extraction, since this has been adequately covered elsewhere. Our contributors were asked to review and discuss their respective areas with particular reference to differences in technique necessitated by use of non-aqueous solvents while not reiterating facts well-known from experience with aqueous solutions. We have striven to build their contributions into a coherent and consistent whole. We thank our con tributors for following our suggestions so ably and for their forebearance in the face of our editorial impositions.
Author: Peter Stilbs
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110551659
Category : Technology & Engineering
Languages : en
Pages : 482
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Book Description
Diffusion and Eletrophoretic NMR experiments resolve chemical compounds based on their molecular motion. This publication introduces the basics of these methods and explains how they can be used to measure the size of molecules and aggregates, to determine degree of polymerization and to solve other chemical problems. Supplied with many case studies, the book is a must-have for students and researchers who work with practical NMR measurements.
