Synthesis, Physical Properties and Crystal and Molecular Structures of a Binuclear Copper(II) Complex Incorporating 3-methylprazolyl-gallate Ligands PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Synthesis, Physical Properties and Crystal and Molecular Structures of a Binuclear Copper(II) Complex Incorporating 3-methylprazolyl-gallate Ligands PDF full book. Access full book title Synthesis, Physical Properties and Crystal and Molecular Structures of a Binuclear Copper(II) Complex Incorporating 3-methylprazolyl-gallate Ligands by . Download full books in PDF and EPUB format.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 76
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 76
Get Book Here
Book Description
Author: Michael Andrew Oakley
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: Abhay Kumar Patel
Publisher:
ISBN:
Category :
Languages : en
Pages : 35
Get Book Here
Book Description
New copper(II) hydrazone complexes with (Z)-2-(phenyl(2-(pyridin-2-yl)hydrazono)methyl)pyridine (L) were synthesized and characterized using various physicochemical methods. The geometry of complexes can be classified as mononuclear and binuclear. The complex 1 [Cu(L)Cl2] is mononuclear whereas solid-state structures of complex 2 contains a mixture of co-crystals of mono- and binuclear complexes 2a [Cu(L)(H2O)(SO4)] and 2b [(L)Cu-(SO4)2-Cu(L)]. The molecular structure of 2 contains two units of mononuclear complex 2a and two units of binuclear complex 2b. Copper contains in all mono- and binuclear complexes are in a distorted square pyramidal geometry. The present study indicates that complexes having different nuclearities and geometries can be achieved by changing synthetic conditions and methods. Variable temperature magnetic susceptibility measurements of the complexes have shown a weak anti-ferromagnetic interaction. The presence of weak anti-ferromagnetic interactions is mediated by intermolecular hydrogen bonding in 1 and by symmetric sulfate bridge in 2, respectively. The Epr spectra in polycrystalline state of 1 and 2 exhibited a broad signal at 2.149 due to the spin-spin interactions between two copper(II) ions. The cyclic voltammograms of complexes 1 and 2 in DMSO gave two irreversible redox waves. Density functional theory (DFT) calculations were evaluated in the study involved the molecular specification for the use of B3LYP/LANL2DZ formalism for copper atom and B3LYP/6-31G for the remaining atoms. Both complexes catalyzed the dismutation of superoxide ( 02). Furthermore, copper complexes and ligand were tested to explore the anticancer properties. Promising cytotoxicity of synthesized compounds was observed on the selected cancerous cell line of neuroblastoma, lung carcinoma, hepatocellular carcinoma and breast cancer.
Author:
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 194
Get Book Here
Book Description
Author: Tadashi Sugano
Publisher:
ISBN:
Category :
Languages : en
Pages : 28
Get Book Here
Book Description
![Two New Copper(Ii) Binuclear Complexes with Azo Functionalized 2-[(E)-(Pyridine-2yl-Hydrazono)Methyl]Phenol PDF](https://books.google.com/books/content/images/frontcover/uCrxzgEACAAJ?fife=w80-h100)
Author: Prof. R. N. Patel
Publisher:
ISBN:
Category :
Languages : en
Pages : 31
Get Book Here
Book Description
