Synthesis of Heterometallic Zinc-Gold and Lanthanide-Transition Metal Carbonyl Complexes and Reactivity Study of Pentaphosphaferrocene Towards Low-Valent Main Group Species PDF Download
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Author: Ravi Yadav
Publisher:
ISBN: 9783736971233
Category :
Languages : en
Pages : 170
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Book Description
The work reported in this thesis is divided into three parts. In the first part, the synthesis of Zn-Au heterometallic complexes is described by using bifunctional carboxy-phosphine ligands. The second part of this thesis focuses on redox reactions between divalent lanthanides (LnII) and transition metal (TM) carbonyl complexes for the synthesis of high nuclearity heterometallic complexes. The third and final part of this thesis focuses on reactivity studies of [Cp*Fe(Л5-P5)] with lowvalent main group compounds.
Author: Ravi Yadav
Publisher:
ISBN: 9783736971233
Category :
Languages : en
Pages : 170
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Book Description
The work reported in this thesis is divided into three parts. In the first part, the synthesis of Zn-Au heterometallic complexes is described by using bifunctional carboxy-phosphine ligands. The second part of this thesis focuses on redox reactions between divalent lanthanides (LnII) and transition metal (TM) carbonyl complexes for the synthesis of high nuclearity heterometallic complexes. The third and final part of this thesis focuses on reactivity studies of [Cp*Fe(Л5-P5)] with lowvalent main group compounds.
Author: Kathryn Mary Sanchez
Publisher:
ISBN:
Category : Transition metal catalysts
Languages : en
Pages : 514
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Book Description
Author: Stephan Enthaler
Publisher: John Wiley & Sons
ISBN: 3527675965
Category : Technology & Engineering
Languages : en
Pages : 326
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Book Description
Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.
Author: Thomas P. Fehlner
Publisher: Springer Science & Business Media
ISBN: 1489924590
Category : Science
Languages : en
Pages : 409
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Book Description
There is a certain fascination associated with words. The manipulation of strings of symbols according to mutually accepted rules allows a language to express history as well as to formulate challenges for the future. But language changes as old words are used in a new context and new words are created to describe changing situations. How many words has the computer revolution alone added to languages? "Inorganometallic" is a word you probably have never encountered before. It is one created from old words to express a new presence. A strange sounding word, it is also a term fraught with internal contradiction caused by the accepted meanings of its constituent parts. "In organic" is the name of a discipline of chemistry while "metallic" refers to a set of elements constituting a subsection of that discipline. Why then this Carrollian approach to entitling a set of serious academic papers? Organic, the acknowledged doyenne of chemistry, is distinguished from her brother, inorganic, by the prefix "in," i. e. , he gets everything not organic. Organometallic refers to compounds with carbon-metal bonds. It is simple! Inorganometallic is everything else, i. e. , compounds with noncarbon-metal element bonds. But why a new term? Is not inorganic sufficient? By virtue of training, limited time, resources, co-workers, and so on, chemists tend to work on a specific element class, on a particular compound type, or in a particular phase. Thus, one finds element-oriented chemists (e. g.
Author: Gregory L. Geoffroy
Publisher: John Wiley & Sons
ISBN: 0470147431
Category : Science
Languages : en
Pages : 366
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Book Description
This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.
Author: Wilhelm Bartmann
Publisher: VCH Publishers
ISBN:
Category : Biochemistry
Languages : en
Pages : 354
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Book Description
Author: Herbert W. Roesky
Publisher: Wiley-VCH
ISBN: 9783527325467
Category : Science
Languages : en
Pages : 0
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Book Description
Encouraging a new attitude and approach to chemistry, this is the first such collection designed for lab courses and experimental teaching. Experts from around the globe present over 40 real-life teaching experiments, all clearly structured and divided into the five main principles of sustainable and green chemistry: catalysis, solvents, high yield and one-pot synthesis, limiting waste and exposure, as well as special topics. With a foreword by Nobel prize winner Jean Marie Lehn.
Author: Rainer Pöttgen
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110653729
Category : Science
Languages : en
Pages : 746
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Book Description
This work introduces into the chemistry, materials science and technology of Rare Earth Elements. The chapters by experienced lecturers describe comprehensively the recent studies of their characteristics, properties and applications in functional materials. Due to the broad range of covered topics as hydrogen storage materials, LEDs or permanent magnets this work gives an up-to-date presentation of this fascinating research.
Author: Dmitri B Papkovsky
Publisher: Royal Society of Chemistry
ISBN: 1788014553
Category : Science
Languages : en
Pages : 384
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Book Description
Significant progress has been made in recent years in quenched-phosphorescence oxygen sensing, particularly in the materials and applications of this detection technology that are open to commercialization, like uses in brain imaging and food packaging. Prompted by this, the editors have delivered a dedicated book that brings together these developments, provides a comprehensive overview of the different detection methodologies, and representative examples and applications. This book is intended to attract new researchers from various disciplines such as chemistry, physics, biology and medicine, stimulate further progress in the field and assist in developing new applications. Providing a concise summary at the cutting edge, this practical guide for current experts and new potential users will increase awareness of this versatile sensing technology.
Author: Sjoerd Harder
Publisher: John Wiley & Sons
ISBN: 3527344489
Category : Technology & Engineering
Languages : en
Pages : 400
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Book Description
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
