Synthesis of Acrylate- and Methacrylate-substituted Titanium and Zirconium Oxoclusters and Their Incorporation in Organic Polymers PDF Download
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Author: Bogdan Adrian Moraru
Publisher:
ISBN:
Category :
Languages : en
Pages : 412
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Book Description
Author: Bogdan Adrian Moraru
Publisher:
ISBN:
Category :
Languages : en
Pages : 412
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Book Description
Author: Ilan Marek
Publisher: Wiley-VCH Verlag GmbH
ISBN: 9783527304288
Category : Science
Languages : en
Pages : 512
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Book Description
During the last years, the role of titanium and zirconium in organic synthesis has dramatically increased and nowadays, no synthetic chemist can afford to be without a sound knowledge of this fascinating organometal chemistry. This unique book, edited by Ilan Marek, thus summarizes the numerous applications and developments of these two group 4 early transition metal complexes. A plethora of internationally renowned experts and leading scientists in this field cover all the significant aspects of this increasingly important part of organic chemistry and bring the reader up to date. A particularly attractive and useful feature is the inclusion of typical experimental procedures, chosen for broad utility and application. This comprehensive demonstrates the diversity and the applications of these important compounds and is a must-have for all chemists working in organometallic or synthetic organic chemistry.
Author: Sébastien Cochet
Publisher:
ISBN:
Category :
Languages : en
Pages : 219
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Book Description
The synthesis and characterization of aromatic substituted titanium oxo-entities as well as their utilization in hybrid materials is presented. Two main routes have been chosen for the synthesis, in respect to the structure and morphology of the obtained entities: - The first one is the reaction of titanium alkoxide with a slightly excess of carboxylic acid, which yields in well-defined titanium oxo-alkoxo clusters of formula Ti6O4(C6H5COO)8(OR)8 (with R = Et, Prn or Bun) or TixOy(CH2=CH-C6H4COO)z(OPri)z. - The second route is the reaction carried out with a large excess of carboxylic acid to remove all isopropoxide groups. Therefore well-defined oxo-carboxo cluster of formula Ti8O8(C6H5COO)16.(C6H5COOH)2.H2O, or titanium oxo-entities functionalized with amino, nitro and hydroxy groups could be obtained. Afterward the use of the former synthesized products in organic and/or inorganic-organic hybrid materials, particularly for modification of thermal and optical properties, is outlined.
Author: Hoa N. Nguyen
Publisher:
ISBN:
Category :
Languages : en
Pages : 196
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Book Description
Author: Anatolii D. Pomogailo
Publisher: Springer Science & Business Media
ISBN: 3642105742
Category : Technology & Engineering
Languages : en
Pages : 311
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Book Description
Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically in this monograph. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are also considered.
Author: Stefan Kaskel
Publisher: John Wiley & Sons
ISBN: 3527693084
Category : Science
Languages : en
Pages : 904
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Book Description
Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.
Author: N.Y. Turova
Publisher: Springer Science & Business Media
ISBN: 0306476576
Category : Science
Languages : en
Pages : 574
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Book Description
This book is devoted to general questions of the chemistry of metal alkoxides – including physiochemical properties, structure, specific features of single groups of alkoxides, theoretical principles of their use, and major applications of this method in the preparation of functional materials.
Author: Gabriela Guillena
Publisher: Springer
ISBN: 3319430513
Category : Science
Languages : en
Pages : 393
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Book Description
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Author: Pedro Gómez-Romero
Publisher: John Wiley & Sons
ISBN: 3527605193
Category : Technology & Engineering
Languages : en
Pages : 434
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Book Description
Functional Hybrid Materials consist of both organic and inorganic components, assembled for the purpose of generating desirable properties and functionalities. The aim is twofold: to bring out or enhance advantageous chemical, electrochemical, magnetic or electronic characteristics and at the same time to reduce or wholly suppress undesirable properties or effects. Another target is the creation of entirely new material behavior. The vast number of hybrid material components available has opened up a wide and diversified field of fascinating research. In this book, a team of highly renowned experts gives an in-depth overview, illustrating the superiority of well-designed hybrid materials and their potential applications.
Author: Guido Kickelbick
Publisher: John Wiley & Sons
ISBN: 3527610480
Category : Science
Languages : en
Pages : 516
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Book Description
Hybrid materials have currently a great impact on numerous future developments including nanotechnology. This book presents an overview about the different types of materials, clearly structured into synthesis, characterization and applications. A perfect starting point for everyone interested in the field, but also for the specialist as a source of high quality information.
