Synthesis, Characterization, and Reactivity of Prochiral Ruthenium Clusters and Bimetallic Rhenium Complexes with an Unsymmetrical Diphosphine and Hard-Soft Donor Ligands

Synthesis, Characterization, and Reactivity of Prochiral Ruthenium Clusters and Bimetallic Rhenium Complexes with an Unsymmetrical Diphosphine and Hard-Soft Donor Ligands PDF Author: Darrell D. Mayberry
Publisher:
ISBN:
Category :
Languages : en
Pages : 110

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Synthesis, Reactivity, and Characterization of Bimetallic Rhenium Complexes

Synthesis, Reactivity, and Characterization of Bimetallic Rhenium Complexes PDF Author: Daniel James Sullivan
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 128

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Synthesis, Characterization, and Reactivity of Ruthenium Phosphine and Rhodium Heterobimetallic P-N-P- Complexes

Synthesis, Characterization, and Reactivity of Ruthenium Phosphine and Rhodium Heterobimetallic P-N-P- Complexes PDF Author: Robert John McNair
Publisher:
ISBN:
Category :
Languages : en
Pages : 502

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Ruthenium Chemistry

Ruthenium Chemistry PDF Author: Ajay Kumar Mishra
Publisher: CRC Press
ISBN: 1351616501
Category : Science
Languages : en
Pages : 386

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This book will describe Ruthenium complexes as chemotherapeutic agent specifically at tumor site. It has been the most challenging task in the area of cancer therapy. Nanoparticles are now emerging as the most effective alternative to traditional chemotherapeutic approach. Nanoparticles have been shown to be useful in this respect. However, in view of organ system complicacies, instead of using nanoparticles as a delivery tool, it will be more appropriate to synthesize a drug of nanoparticle size that can use blood transport mechanism to reach the tumor site and regress cancer. Due to less toxicity and effective bio-distribution, ruthenium (Ru) complexes are of much current interest. Additionally, lumiscent Ru-complexes can be synthesized in nanoparticle size and can be directly traced at tissue level. The book will contain the synthesis, characterization, and applications of various Ruthenium complexes as chemotherapeutic agents. The book will also cover the introduction to chemotherapy, classification of Ru- complexes with respect to their oxidation states and geometry, Ruthenium complexes of nano size: shape and binding- selectivity, binding of ruthenium complexes with DNA, DNA cleavage studies and cytotoxicity. The present book will be more beneficial to researchers, scientists and biomedical. Current book will empower specially to younger generation to create a new world of ruthenium chemistry in material science as well as in medicines. This book will be also beneficial to national/international research laboratories, and academia with interest in the area of coordination chemistry more especially to the Ruthenium compounds and its applications.

Synthesis, Characterization, and Reactivity of Hexanuclear Rhenium Clusters Containing Nitrogen-donor Ligands

Synthesis, Characterization, and Reactivity of Hexanuclear Rhenium Clusters Containing Nitrogen-donor Ligands PDF Author: Jessica L. Durham
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 214

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Ruthenium in Organic Synthesis

Ruthenium in Organic Synthesis PDF Author: Shun-Ichi Murahashi
Publisher: John Wiley & Sons
ISBN: 3527605797
Category : Science
Languages : en
Pages : 398

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In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)

The Synthesis, Characterization and Reactivity of Ruthenium Coordination Complexes

The Synthesis, Characterization and Reactivity of Ruthenium Coordination Complexes PDF Author: Carol A. Bessel
Publisher:
ISBN:
Category :
Languages : en
Pages : 314

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Design, Synthesis and Characterization of Ruthenium(ii) and Rhenium(i) Complexes with Functionalized Ligands for Photo-And Electrochemi- Luminescence, Solvatochromism, Molecular Recognition and HPLC Separation Studies

Design, Synthesis and Characterization of Ruthenium(ii) and Rhenium(i) Complexes with Functionalized Ligands for Photo-And Electrochemi- Luminescence, Solvatochromism, Molecular Recognition and HPLC Separation Studies PDF Author: Meijin Li
Publisher: Open Dissertation Press
ISBN: 9781361428276
Category :
Languages : en
Pages :

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This dissertation, "Design, Synthesis and Characterization of Ruthenium(II) and Rhenium(I) Complexes With Functionalized Ligands for Photo-and Electrochemi- Luminescence, Solvatochromism, Molecular Recognition and HPLC Separation Studies" by Meijin, Li, 李梅金, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled DESIGN, SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM(II) AND RHENIUM(I) COMPLEXES WITH FUNCTIONALIZED LIGANDS FOR PHOTO- AND ELECTROCHEMI- LUMINESCENCE, SOLVATOCHROMISM, MOLECULAR RECOGNITION AND HPLC SEPARATION STUDIES Submitted by LI MEIJIN for the degree of Doctor of Philosophy at The University of Hong Kong in July 2006 A series of ruthenium(II) and rhenium(I) diimine complexes containing thia-, selena- and aza-crowns derived from 1,10-phenanthroline, [Ru(bpy) (phen-3S)](ClO ) 2 4 2 (phen-3S = 1,13-dioxa-4,7,10-trithiacyclopentadecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-2S)](ClO ) (phen-2S = 1,7,10,16-tetraoxa-4,13-dithiacyclohexa- 2 4 2 dodecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-S)](ClO ) (phen-S = 1,4,10,13- 2 4 2 tetraoxa-7-thiacyclopentadecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-Se)](ClO ) 2 4 2 (phen-Se = 1,4,10,13-tetraoxa-7-selenacyclopentadecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-OEt](ClO ) (phen-OEt = 5,6-diethoxy-[1,10]phenanthroline), 2 4 2 [Ru(bpy) (phen-2NH)](ClO ) (phen-2NH = 1,13-diaxa-4,7,10-trioxacyclopenta- 2 4 2 decano[2,3-f][1,10]phenanthroline), [Re(CO) (py)(phen-3S)]PF, [Re(CO) (py)(phen-S)]OTf 3 6 3 and [Re(CO) (py)(phen-Se)]OTf have been synthesized and characterized, and their photophysics, electrogenerated chemiluminescence (ECL) and electrochemistry were studied. Their interaction with metal ions was investigated by UV-vis, luminescence, NMR spectroscopy and ECL. [Ru(bpy) (phen-3S)](ClO ) and [Re(CO) (py)(phen-3S)]

The Synthesis, Characterization and Catalytic Properties of Ruthenium and Rhodium Phosphine Complexes

The Synthesis, Characterization and Catalytic Properties of Ruthenium and Rhodium Phosphine Complexes PDF Author: Michael Francis McGuiggan
Publisher:
ISBN:
Category :
Languages : en
Pages : 388

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The Synthesis, Characterization, and Reactivity of Nitro(phosphine)ruthenium(III) Complexes

The Synthesis, Characterization, and Reactivity of Nitro(phosphine)ruthenium(III) Complexes PDF Author: Randolph A. Leising
Publisher:
ISBN:
Category :
Languages : en
Pages : 432

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