Synthesis and Reactivity Studies of Iridium Complexes with Tridentate Ligands PDF Download
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Author: Sara K. Buzak
Publisher:
ISBN:
Category : Iridium catalysts
Languages : en
Pages : 100
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Book Description
Author: Sara K. Buzak
Publisher:
ISBN:
Category : Iridium catalysts
Languages : en
Pages : 100
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Book Description
Author: Luis A. Oro
Publisher: John Wiley & Sons
ISBN: 3527623086
Category : Science
Languages : en
Pages : 424
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Book Description
Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
Author: Luis Alfredo Arizpe
Publisher:
ISBN:
Category :
Languages : en
Pages : 60
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Book Description
The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement for the oxidative addition of a substituted benzyl bromide and Me3SnBr with DPB as a ligand in place of triphenylphosphine. Two products from the oxidative addition of p-chlorobenzyl bromide have been isolated and structurally characterized.
Author: Wayne M. Rees
Publisher:
ISBN:
Category :
Languages : en
Pages : 578
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Author: Travis T. Lekich
Publisher:
ISBN:
Category :
Languages : en
Pages : 102
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Book Description
This thesis describes new syntheses of [superscript]Me4 PCP and [superscript]Me4 POCOP pincer ligands ([superscript]R4PCP = 1,3-bis(dialkylphosphinomethyl)-benzene; R4POCOP = 1,3-bis(dialkylphosphinito)-benzene), and the coordination chemistry of the corresponding iridium complexes. Bis(dimethyl)phosphine ligands have been difficult to synthesize because their precursors are expensive or dangerous to obtain. As such, they have not been as extensively studied as the larger [superscript]R4PCP (R = [superscript]t Bu, [superscript]i Pr) derivatives. Chapter 2 shows that aminophosphines, which can be safely synthesized on large scales, are excellent precursors to bis(dimethyl)phosphine ligands: Me4PCP, Me4POCOP, and DMPE. Iridium complexes of [superscript]Me4 PCP and [superscript]Me4 POCOP show similar and novel reactivity compared to that of larger analogs (R = [superscript]t Bu, [superscript]i Pr). Chapter 3 illustrates the steric environment of ([superscript]Me4 PCP)Ir(CO) through structure and reactivity comparisons. Chapter 4 describes the facile nature of H2 addition to (Me4PCP)Ir(CO) and subsequent isomerization. The nature of this reaction allowed us to investigate the isomerization mechanism and revealed that the isomerization likely proceeds through a CO insertion pathway. Chapter 4 also reports the surprising reactivity of DCM and silver acetate with ([superscript]Me4 PCP)Ir(CO), which likely is facilitated by the ligand’s reduced steric profile.
Author: MacLean Darren F.
Publisher:
ISBN:
Category :
Languages : en
Pages : 288
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Book Description
Author: Allen J. Bard
Publisher: CRC Press
ISBN: 1135535795
Category : Science
Languages : en
Pages : 707
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Book Description
The first source on this expanding analytical science, this reference explores advances in the instrumentation, design, and application of techniques with electrogenerated chemiluminescence (ECL), examining the use and impact of ECL-based assays in clinical diagnostics, life science research, environmental testing, food and water evaluation, and th
Author: Hartmut Yersin
Publisher: John Wiley & Sons
ISBN: 3527621318
Category : Science
Languages : en
Pages : 458
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Book Description
This monograph on organic light emitting diodes, edited by a pioneer, and written by front-line researchers from academia and industry, provides access to the latest findings in this rapidly growing field. More than ten contributions cover all areas -- from theory and basic principles, to different emitter materials and applications in production.
Author: Elisa E. Calimano
Publisher:
ISBN:
Category :
Languages : en
Pages : 552
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Author: Namadzavho Enos Sitabule
Publisher:
ISBN:
Category : Rhodium
Languages : en
Pages : 302
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Book Description
