Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes

Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes PDF Author: Rania Elhadi Adam
Publisher: Linköping University Electronic Press
ISBN: 9179298788
Category :
Languages : en
Pages : 107

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Book Description
Nanostructured materials for visible light driven photo-processes such as photodegradation of organic pollutants and photoelectrochemical (PEC) water oxidation for hydrogen production are very attractive because of the positive impact on the environment. Metal oxides-based nanostructures are widely used in these photoprocesses due to their unique properties. But single nanostructured metal oxide material might suffer from low efficiency and instability in aqueous solutions under visible light. These facts make it important to have an efficient and reliable nanocomposite for the photo-processes. The combination of different nanomaterials to form a composite configuration can produce a material with new properties. The new properties which are due to the synergetic effect, are a combination of the properties of all the counterparts of the nanocomposite. Zinc oxides (ZnO) have unique optical and electrical properties which grant it to be used in optoelectronics, sensors, solar cells, nanogenerators, and photocatalysis activities. Although ZnO absorbs visible light from the sun due to the deep level band, it mainly absorbs ultraviolet wavelengths which constitute a small portion of the whole solar spectrum range. Also, ZnO has a problem with the high recombination rate of the photogenerated electrons. These problems might reduce its applicability to the photo-process. Therefore, our aim is to develop and investigate different nanocomposites materials based on the ZnO nanostructures for the enhancement of photocatalysis processes using the visible solar light as a green source of energy. Two photo-processes were applied to examine the developed nanocomposites through photocatalysis: (1) the photodegradation of organic dyes, (2) PEC water splitting. In the first photo-process, we used the ZnO nanoparticles (NPs), Magnesium (Mg)-doped ZnO NPs, and plasmonic ZnO/graphene-based nanocomposite for the decomposition of some organic dyes that have been used in industries. For the second photo-process, ZnO photoelectrode composite with different silver-based semiconductors to enhance the performance of the ZnO photoelectrode was used for PEC reaction analysis to perform water splitting. The characterization and photocatalysis experiment results showed remarkable enhancement in the photocatalysis efficiency of the synthesized nanocomposites. The observed improved properties of the ZnO are due to the synergetic effects are caused by the addition of the other nanomaterials. Hence, the present thesis attends to the synthesis and characterization of some nanostructured materials composite with ZnO that are promising candidates for visible light-driven photo-processes.

Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes

Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes PDF Author: Rania Elhadi Adam
Publisher: Linköping University Electronic Press
ISBN: 9179298788
Category :
Languages : en
Pages : 107

Get Book Here

Book Description
Nanostructured materials for visible light driven photo-processes such as photodegradation of organic pollutants and photoelectrochemical (PEC) water oxidation for hydrogen production are very attractive because of the positive impact on the environment. Metal oxides-based nanostructures are widely used in these photoprocesses due to their unique properties. But single nanostructured metal oxide material might suffer from low efficiency and instability in aqueous solutions under visible light. These facts make it important to have an efficient and reliable nanocomposite for the photo-processes. The combination of different nanomaterials to form a composite configuration can produce a material with new properties. The new properties which are due to the synergetic effect, are a combination of the properties of all the counterparts of the nanocomposite. Zinc oxides (ZnO) have unique optical and electrical properties which grant it to be used in optoelectronics, sensors, solar cells, nanogenerators, and photocatalysis activities. Although ZnO absorbs visible light from the sun due to the deep level band, it mainly absorbs ultraviolet wavelengths which constitute a small portion of the whole solar spectrum range. Also, ZnO has a problem with the high recombination rate of the photogenerated electrons. These problems might reduce its applicability to the photo-process. Therefore, our aim is to develop and investigate different nanocomposites materials based on the ZnO nanostructures for the enhancement of photocatalysis processes using the visible solar light as a green source of energy. Two photo-processes were applied to examine the developed nanocomposites through photocatalysis: (1) the photodegradation of organic dyes, (2) PEC water splitting. In the first photo-process, we used the ZnO nanoparticles (NPs), Magnesium (Mg)-doped ZnO NPs, and plasmonic ZnO/graphene-based nanocomposite for the decomposition of some organic dyes that have been used in industries. For the second photo-process, ZnO photoelectrode composite with different silver-based semiconductors to enhance the performance of the ZnO photoelectrode was used for PEC reaction analysis to perform water splitting. The characterization and photocatalysis experiment results showed remarkable enhancement in the photocatalysis efficiency of the synthesized nanocomposites. The observed improved properties of the ZnO are due to the synergetic effects are caused by the addition of the other nanomaterials. Hence, the present thesis attends to the synthesis and characterization of some nanostructured materials composite with ZnO that are promising candidates for visible light-driven photo-processes.

Photocatalytic Semiconductors

Photocatalytic Semiconductors PDF Author: Aracely Hernández-Ramírez
Publisher: Springer
ISBN: 3319109995
Category : Science
Languages : en
Pages : 298

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Book Description
This critical volume examines the different methods used for the synthesis of a great number of photocatalysts, including TiO2, ZnO and other modified semiconductors, as well as characterization techniques used for determining the optical, structural and morphological properties of the semiconducting materials. Additionally, the authors discuss photoelectrochemical methods for determining the light activity of the photocatalytic semiconductors by means of measurement of properties such as band gap energy, flat band potential and kinetics of hole and electron transfer. Photocatalytic Semiconductors: Synthesis, Characterization and Environmental Applications provide an overview of the semiconductor materials from first- to third-generation photocatalysts and their applications in wastewater treatment and water disinfection. The book further presents economic and toxicological aspects in the production and application of photocatalytic materials.

Chalcogenide-Based Nanomaterials as Photocatalysts

Chalcogenide-Based Nanomaterials as Photocatalysts PDF Author: Mohammad Mansoob Khan
Publisher: Elsevier
ISBN: 0128209178
Category : Technology & Engineering
Languages : en
Pages : 378

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Book Description
Chalcogenide-Based Nanomaterials as Photocatalysts deals with the different types of chalcogenide-based photocatalytic reactions, covering the fundamental concepts of photocatalytic reactions involving chalcogenides for a range of energy and environmental applications. Sections focus on nanostructure control, synthesis methods, activity enhancement strategies, environmental applications, and perspectives of chalcogenide-based nanomaterials. The book offers guidelines for designing new chalcogenide-based nanoscale photocatalysts at low cost and high efficiency for efficient utilization of solar energy in the areas of energy production and environment remediation. - Provides information on the development of novel chalcogenide-based nanomaterials - Outlines the fundamentals of chalcogenides-based photocatalysis - Includes techniques for heterogeneous catalysis based on chalcogenide-based nanomaterials

TiO2 Nanoparticles

TiO2 Nanoparticles PDF Author: Aiguo Wu
Publisher: John Wiley & Sons
ISBN: 3527825452
Category : Science
Languages : en
Pages : 255

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Book Description
A unique book that summarizes the properties, toxicology, and biomedical applications of TiO2-based nanoparticles Nanotechnology is becoming increasingly important for products used in our daily lives. Nanometer-sized titanium dioxide (TiO2) are widely used in industry for different purposes, such as painting, sunscreen, printing, cosmetics, biomedicine, and so on. This book summarizes the advances of TiO2 based nanobiotechnology and nanomedicine, covering materials properties, toxicological research, and biomedical application, such as antibacter, biosensing, and cancer theranostics. It uniquely integrates the TiO2 applications from physical properties, toxicology to various biomedical applications, and includes black TiO2 based cancer theranostics. Beginning with a comprehensive introduction to the properties and applications of nanoparticles, TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine offers chapters on: Toxicity of TiO2 Nanoparticles; Antibacterial Applications of TiO2 Nanoparticles; Surface Enhanced Raman Spectrum of TiO2 Nanoparticle for Biosensing (TiO2 Nanoparticle Served as SERS Sensing Substrate); TiO2 as Inorganic Photosensitizer for Photodynamic Therapy; Cancer Theranostics of Black TiO2 Nanoparticles; and Neurodegenerative Disease Diagnostics and Therapy of TiO2-Based Nanoparticles. This title: Blends the physical properties, toxicology of TiO2 nanoparticles to the many biomedical applications Includes black TiO2 based cancer theranostics in its coverage Appeals to a broad audience of researchers in academia and industry working on nanomaterials-based biosensing, drug delivery, nanomedicine TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine is an ideal book for medicinal chemists, analytical chemists, biochemists, materials scientists, toxicologists, and those in the pharmaceutical industry.

Applications of Nanomaterials

Applications of Nanomaterials PDF Author: Sneha Bhagyaraj
Publisher: Woodhead Publishing
ISBN: 0081019726
Category : Technology & Engineering
Languages : en
Pages : 492

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Book Description
Applications of Nanomaterials: Advances and Key Technologies discusses the latest advancements in the synthesis of various types of nanomaterials. The book's main objective is to provide a comprehensive review regarding the latest advances in synthesis protocols that includes up-to-date data records on the synthesis of all kinds of inorganic nanostructures using various physical and chemical methods. The synthesis of all important nanomaterials, such as carbon nanostructures, Core-shell Quantum dots, Metal and metal oxide nanostructures, Nanoferrites, polymer nanostructures, nanofibers, and smart nanomaterials are discussed, making this a one-stop reference resource on research accomplishments in this area. Leading researchers from industry, academia, government and private research institutions across the globe have contributed to the book. Academics, researchers, scientists, engineers and students working in the field of polymer nanocomposites will benefit from its solutions for material problems. - Provides an up-to-date data record on the synthesis of all kinds of organic and inorganic nanostructures using various physical and chemical methods - Presents the latest advances in synthesis protocols - Includes the latest techniques used in the physical and chemical characterization of nanomaterials - Covers the characterization of all the important materials groups, such as carbon nanostructures, core-shell quantum dots, metal and metal oxide nanostructures, nanoferrites, polymer nanostructures and nanofibers

2D Functional Nanomaterials

2D Functional Nanomaterials PDF Author: Ganesh S. Kamble
Publisher: John Wiley & Sons
ISBN: 3527346775
Category : Technology & Engineering
Languages : en
Pages : 452

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Book Description
2D Functional Nanomaterials Outlines the latest developments in 2D heterojunction nanomaterials with energy conversion applications In 2D Functional Nanomaterials: Synthesis, Characterization, and Applications, Dr. Ganesh S. Kamble presents an authoritative overview of the most recent progress in the rational design and synthesis of 2D nanomaterials and their applications in semiconducting catalysts, biosensors, electrolysis, batteries, and solar cells. This interdisciplinary volume is a valuable resource for materials scientists, electrical engineers, nanoscientists, and solid-state physicists looking for up-to-date information on 2D heterojunction nanomaterials. The text summarizes the scientific contributions of international experts in the fabrication and application of 2D nanomaterials while discussing the importance and impact of 2D nanomaterials on future economic growth, novel manufacturing processes, and innovative products. Provides thorough coverage of graphene chemical derivatives synthesis and applications, including state-of-the-art developments and perspectives Describes 2D/2D graphene oxide-layered double hydroxide nanocomposites for immobilization of different radionuclides Covers 2D nanomaterials for biomedical applications and novel 2D nanomaterials for next-generation photodetectors Discusses applications of 2D nanomaterials for cancer therapy and recent trends ingraphene-latex nanocomposites Perfect for materials scientists, inorganic chemists, and electronics engineers, 2D Functional Nanomaterials: Synthesis, Characterization, and Applications is also an essential resource for solid-state physicists seeking accurate information on recent progress in two-dimensional heterojunction materials with energy conversion applications.

Nanomaterials in Biomass Conversion

Nanomaterials in Biomass Conversion PDF Author: Komal Rizwan
Publisher: Elsevier
ISBN: 0443135010
Category : Technology & Engineering
Languages : en
Pages : 534

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Book Description
Nanomaterials in Biomass Conversion: Advances and Applications for Bioenergy, Biofuels and Bio-based Products critically reviews the basic principles through to the latest advances in the emerging field of nanotechnology for the production of biofuels and bioenergy. Divided into 3 parts, the first five chapters explain the fundamentals of nanomaterials, their properties, characterization, and basic processes for synthesis. Part 2, which constitutes the majority of the book, reviews the various methods and technologies for the conversion of biomass to bioenergy, biofuels, and value-added products using nanomaterials. This includes homogeneous and heterogeneous nano-catalytic systems, nano-photocatalytic conversion, nanomaterial-assisted anaerobic digestion, nanoparticles-immobilized enzymes conversion, the production of biogas, volatile fatty acids, and value-added products, and in carbon capture and conversion to sustainable energy products, as well as the potential of nano-biochar, nano-cellulose, and other nanomaterials in microbial fuel cells, bioelectrochemical systems, and batteries. Finally, Part 3 addresses the techno-economics and financial viability in the context of the circular economy, risk related to toxicology, stability, and environmental impacts, and considers the various challenges and future opportunities of biomass conversion through nanomaterials. Nanomaterials in Biomass Conversion is an invaluable resource for researchers and engineers involved in the production of bioenergy, biofuel, and bioproducts, and will also be of benefit to those interested in environmental remediation, pollution management, and cleaner energy production. - Critically examines the role of nanomaterials in the management of waste biomass as applied to bioenergy and biofuels - Explains various nanotechnological methods for the conversion of waste biomass into value-added products - Discusses the basic principles, operational aspects, ongoing developments, and future perspectives related to the applications of nanotechnologies and nanomaterials in biomass conversion - Provides solutions to the key challenges of nanotechnologies and nanomaterials in the conversion of biomass, along with future challenges and risks

Industrial Applications of Nanomaterials

Industrial Applications of Nanomaterials PDF Author: Sabu Thomas
Publisher: Elsevier
ISBN: 012815750X
Category : Technology & Engineering
Languages : en
Pages : 536

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Book Description
Industrial Applications of Nanomaterials explains the industry based applications of nanomaterials, along with their environmental impacts, lifecycle analysis, safety and sustainability. This book brings together the industrial applications of nanomaterials with the incorporation of various technologies and areas, covering new trends and challenges. Significant properties, safety and sustainability and environmental impacts of synthesis routes are also explored, as are major industrial applications, including agriculture, medicine, communication, construction, energy, and in the military. This book is an important information source for those in research and development who want to gain a greater understanding of how nanotechnology is being used to create cheaper, more efficient products. - Explains how different classes of nanomaterials are being used to create cheaper, more efficient products - Explores the environmental impacts of using a variety of nanomaterials - Discusses the challenges faced by engineers looking to integrate nanotechnology in new product development

Nanomaterials in Manufacturing Processes

Nanomaterials in Manufacturing Processes PDF Author: Dhiraj Sud
Publisher: CRC Press
ISBN: 1000630099
Category : Technology & Engineering
Languages : en
Pages : 308

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Book Description
In the manufacturing sector, nanomaterials offer promising outcomes for cost reduction in production, quality improvement, and minimization of environmental hazards. This book focuses on the application of nanomaterials across a wide range of manufacturing areas, including in paint and coatings, petroleum refining, textile and leather industries, electronics, energy storage devices, electrochemical sensors, as well as in industrial waste treatment. This book: Examines nanofluids and nanocoatings in manufacturing and their characterization. Discusses nanomaterial applications in fabricating lightweight structural components, oil refining, smart leather processing and textile industries, and the construction industry. Highlights the role of 3D printing in realizing the full potential of nanotechnology. Considers synthetic strategies with a focus on greener protocols for the fabrication of nanostructured materials with enhanced properties and better control, including these materials' characterization and significant properties for ensuring smart outputs. Offers a unique perspective on applications in industrial waste recycling and treatment, along with challenges in terms of safety, economics, and sustainability in industrial processes. This work is written for researchers and industry professionals across a variety of engineering disciplines, including materials, manufacturing, process, and industrial engineering.

Sustainable Materials and Green Processing for Energy Conversion

Sustainable Materials and Green Processing for Energy Conversion PDF Author: Kuan Yew Cheong
Publisher: Elsevier
ISBN: 0128230703
Category : Technology & Engineering
Languages : en
Pages : 506

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Book Description
Sustainable Materials and Green Processing for Energy Conversion provides a concise reference on green processing and synthesis of materials required for the next generation of devices used in renewable energy conversion and storage. The book covers the processing of bio-organic materials, environmentally-friendly organic and inorganic sources of materials, synthetic green chemistry, bioresorbable and transient properties of functional materials, and the concept of sustainable material design. The book features chapters by worldwide experts and is an important reference for students, researchers, and engineers interested in gaining extensive knowledge concerning green processing of sustainable, green functional materials for next generation energy devices. Additionally, functional materials used in energy devices must also be able to degrade and decompose with minimum energy after being disposed of at their end-of-life. Environmental pollution is one of the global crises that endangers the life cycles of living things. There are multiple root causes of this pollution, including industrialization that demands a huge supply of raw materials for the production of products related to meeting the demands of the Internet-of-Things. As a result, improvement of material and product life cycles by incorporation of green, sustainable principles is essential to address this challenging issue. - Offers a resourceful reference for readers interested in green processing of environmentally-friendly and sustainable materials for energy conversion and storage devices - Focuses on designing of materials through green-processing concepts - Highlights challenges and opportunities in green processing of renewable materials for energy devices