Syntheses and Studies on Transition Metal Complexes Involving Phosphine and Thioether Ligands PDF Download
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Author: Alexander Gibson
Publisher:
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Category :
Languages : en
Pages :
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Author: Alexander Gibson
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Category :
Languages : en
Pages :
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Author: Julie Christine Connolly
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Category :
Languages : en
Pages :
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Author: Simon Johnathan Albert Pope
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Category :
Languages : en
Pages :
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Author: Eva Neumann
Publisher: Cuvillier Verlag
ISBN: 3736918011
Category : Science
Languages : en
Pages : 244
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The term ligand [latin, ligare = bind] has its origin in coordination chemistry. It denotes a molecule that is able to bind to a metal center in most cases via one or several free electron pairs.[1] Ligands can be described by the number of electron-pair donor atoms as monodentate, bidentate, tridentate etc. ligands. The latter are also called chelating ligands [greek, chele = (crab’s) claw]. A typical classification of ligands is according to their electronic properties. They serve either as a σ-donating, σ-donating/π-accepting, or σ,π-donating/π-accepting ligands.[2] A more practical, often encountered approach is the classification of ligands according to their donor atoms, especially when larger molecules and molecules containing heteroatoms are regarded (compare 1.2). Coordination chemistry was already established in the 19th century. In 1893 Alfred Werner suggested an octahedral arrangement of ligands coordinated to a central metal ion for many compounds. This explained, for example, the appearance and reactivity of four different cobalt(III) complexes (Figure 1.1), when CoCl2 is dissolved in aqueous ammonia and then oxidized by air to the +3 oxidation state. The formulas of these complexes can be written as depicted in Figure 1.1. Werner’s work was rewarded with the Nobel prize in 1913.[3]
Author: Stephen D. Robinson
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 4
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Author: Ricardo Alejandro Delgado
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 316
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Author: Hon-man Lee
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 314
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Author:
Publisher: John Wiley & Sons
ISBN: 0470132825
Category : Science
Languages : en
Pages : 223
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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Author: Weiqing Weng
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 424
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 157
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