Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions PDF Download
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Author: Norihiro Matubayasi
Publisher: CRC Press
ISBN: 1439880875
Category : Science
Languages : en
Pages : 226
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Book Description
Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a detailed and systematic analysis of the properties of ions at the air/water interface. Unifying older and newer theories and measurements, this book emphasizes the contributions of simple ions to surface tension behavior, and the practical consequences. It begins with a general discussion on Gibbs surface thermodynamics, offering a guide to his theoretical insight and formulation of the boundary between fluids. The text then discusses the thermodynamic formulae that are useful for practical experimental work in the analysis of fluid/fluid interfaces. Chapters cover surface tension of pure water at air/water and air/oil interfaces, surface tension of solutions and the thermodynamic quantities associated with the adsorption and desorption of solutes, and surface tension of simple salt solutions. They also address adsorption of ions at the air/water interface, surface tension of solutions and the effect of temperature, adsorption from mixed electrolyte solutions, and thermodynamic properties of zwitterionic amino acids in the surface region. Focusing on the thermodynamic properties of ions at air/fluid interfaces, this book gives scientists a quantitative, rigorous, and objectively experimental methodology they can employ in their research.
Author: Norihiro Matubayasi
Publisher: CRC Press
ISBN: 1439880875
Category : Science
Languages : en
Pages : 226
Get Book Here
Book Description
Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a detailed and systematic analysis of the properties of ions at the air/water interface. Unifying older and newer theories and measurements, this book emphasizes the contributions of simple ions to surface tension behavior, and the practical consequences. It begins with a general discussion on Gibbs surface thermodynamics, offering a guide to his theoretical insight and formulation of the boundary between fluids. The text then discusses the thermodynamic formulae that are useful for practical experimental work in the analysis of fluid/fluid interfaces. Chapters cover surface tension of pure water at air/water and air/oil interfaces, surface tension of solutions and the thermodynamic quantities associated with the adsorption and desorption of solutes, and surface tension of simple salt solutions. They also address adsorption of ions at the air/water interface, surface tension of solutions and the effect of temperature, adsorption from mixed electrolyte solutions, and thermodynamic properties of zwitterionic amino acids in the surface region. Focusing on the thermodynamic properties of ions at air/fluid interfaces, this book gives scientists a quantitative, rigorous, and objectively experimental methodology they can employ in their research.
Author: Jennifer A. Faust
Publisher: Elsevier
ISBN: 0128136421
Category : Science
Languages : en
Pages : 492
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Book Description
Physical Chemistry of Gas-Liquid Interfaces, the first volume in the Developments in Physical & Theoretical Chemistry series, addresses the physical chemistry of gas transport and reactions across liquid surfaces. Gas–liquid interfaces are all around us, especially within atmospheric systems such as sea spry aerosols, cloud droplets, and the surface of the ocean. Because the reaction environment at liquid surfaces is completely unlike bulk gas or bulk liquid, chemists must readjust their conceptual framework when entering this field. This book provides the necessary background in thermodynamics and computational and experimental techniques for scientists to obtain a thorough understanding of the physical chemistry of liquid surfaces in complex, real-world environments. - 2019 PROSE Awards - Winner: Category: Chemistry and Physics: Association of American Publishers - Provides an interdisciplinary view of the chemical dynamics of liquid surfaces, making the content of specific use to physical chemists and atmospheric scientists - Features 100 figures and illustrations to underscore key concepts and aid in retention for young scientists in industry and graduate students in the classroom - Helps scientists who are transitioning to this field by offering the appropriate thermodynamic background and surveying the current state of research
Author: Yury A. Budkov
Publisher: Springer Nature
ISBN: 3031683641
Category :
Languages : en
Pages : 298
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Book Description
Author: Rajinder Pal
Publisher: CRC Press
ISBN: 149870445X
Category : Science
Languages : en
Pages : 430
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Book Description
In the design, processing, and applications of composite materials, a thorough understanding of the physical properties is required. It is important to be able to predict the variations of these properties with the kind, shape, and concentration of filler materials. The currently available books on composite materials often emphasize mechanical pro
Author: Yihan Liu
Publisher: CRC Press
ISBN: 1498715567
Category : Science
Languages : en
Pages : 388
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Book Description
Silicone is an important class of materials used in applications that range from industrial assembly to everyday consumer products. Silicones are often delivered and synthesized in dispersion forms, the most common being liquid-in-liquid (emulsion), solid-in-liquid (suspension), air-in-liquid (foam) and solid-in air (powder). This book compiles a carefully selected number of topics that are essential to the understanding, creative design and production of silicone dispersions. As such, it provides the first unified description of silicone dispersions in the literature.
Author: Victor M. Starov
Publisher: CRC Press
ISBN: 0429013744
Category : Science
Languages : en
Pages : 495
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Book Description
Wetting and Spreading Dynamics explains how surface forces acting at the three-phase contact line determine equilibrium, hysteresis contact angles, and other equilibrium and kinetics features of liquids when in contact with solids or with other immiscible liquids. It examines the interaction of surface forces, capillary forces, and properties of the transition zone between the bulk liquid and solid substrate. Significantly revised and updated, the Second Edition features new chapters that cover spreading of non-Newtonian liquids over porous substrates, hysteresis of contact angles on smooth homogeneous substrates, equilibrium and hysteresis contact angles on deformable substrates, and kinetics of simultaneous spreading and evaporation. Drawing together theory and experimental data while presenting over 150 figures to illustrate the concepts, Wetting and Spreading Dynamics, Second Edition is a valuable resource written for both newcomers and experienced researchers.
Author: Noémi M. Nagy
Publisher: CRC Press
ISBN: 100046511X
Category : Science
Languages : en
Pages : 273
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Book Description
Knowledge of the basic interactions that take place between geological materials and different substances is the first step in understanding the effects of adsorption and other interfacial processes on the quality of rocks and soils, and on driving these processes towards a beneficial or neutral result. Interfacial Chemistry of Rocks and Soils examines the different processes at solid and liquid interfaces of soil and rock, presenting a complete analysis that emphasizes the importance of chemical species on these interactions. This Second Edition features novel results in the field and expanded coverage of the kinetics of interfacial processes. New content includes models of heterogeneous isotope exchange, sorption isotherms for heterovalent cation exchange, as well as sorption of anions by chemically modified clays. Summarizing the results and knowledge of the authors’ research in this field over several decades, this volume: Explores the individual components of the studied systems: the solid, the solution, and the interface Discusses the characteristics and thermodynamics of the interface Profiles the most important analytical methods in the study of interfacial processes Demonstrates transformations initiated by interfacial processes Outlines avenues of treatment that may solve geological, soil science, and environmental problems Drawn chiefly from the authors’ years of research at the Imre Lajos Isotope Laboratory in the Department of Physical Chemistry at the University of Debrecen in Hungary, this book discusses chemical reactions on the surfaces/interfaces of soils and rocks; examines the role of these processes in environmental, colloid and geochemistry; and explores the effects on agricultural, environmental and industrial applications.
Author: Saeed Ahmad Khan
Publisher: Springer Nature
ISBN: 3030849775
Category : Medical
Languages : en
Pages : 302
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Book Description
Essentials of Industrial Pharmacy is an attempt to comprehensively present, in a single book, various pharmaceutical processes and equipment that are frequently used for production of pharmaceutical dosage forms, along with quality control tests of these dosage forms. Pictorial/graphical illustrations provide easier understanding of complex pharmaceutical concepts, manufacturing processes of pharmaceutical dosage forms. Since it is imperative for pharmacy students to have a clear understanding of the basic concepts used in development of drugs into suitable and stable dosage forms. This book offers a wealth of information regarding basic aspects of pharmaceutical processes and dosage forms, in a single book, for undergraduate pharmacy students or science students (with no pharmacy background) intended to work in the pharmaceutical Industry.
Author: Yizhak Marcus
Publisher: Springer Science & Business Media
ISBN: 9400746474
Category : Science
Languages : en
Pages : 224
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Book Description
Over the past decade, numerous books have attempted to explain ions in aqueous solutions in relation to biophysical phenomena. Ions in Water and Biophysical Implications, from Chaos to Cosmos offers a physicochemical point of view of the spread of this matter and suggests innovative solutions that will challenge the biophysics research establishment. Starting with a throughout discussion of the properties of liquid water, in particular as a structured liquid with an extensive hydrogen bonded structure, the book examines water as a solvent for gases, non-electrolytes, and electrolytes and reviews the properties, sizes and thermodynamics of isolated and aqueous ions, as well as their interactions, including those of polyelectrolytes. The effects of ions on water structure, including those on solvent dynamics and certain thermodynamic quantities, are presented. This volume investigates water surfaces with its vapour, with another liquid, and with a solid, as well as the effects of solutes, including simple ions and the water-miscible non-electrolytes. Surfaces are relevant to biomolecular and colloidal systems and the book discusses briefly surfactants, micelles and vesicles. Finally, the book concludes with a review of the various biophysical implications involving chaotropic and kosmotropic ions in homogeneous solutions and the Hofmeister series for ions concerning biomolecular and colloidal systems and some aspects of protein hydration and K+/Na+ selectivity in ion channels. Ions in Water and Biophysical Implications, from Chaos to Cosmos will appeal to physical chemists, biophysicists, biochemists, as well as to all students and researchers involved in the study of aqueous solutions.
Author: Joseph F. Zemaitis, Jr.
Publisher: John Wiley & Sons
ISBN: 0470938404
Category : Technology & Engineering
Languages : en
Pages : 876
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Book Description
Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.
