Studies Directed Toward the Total Synthesis of Salvilenone PDF Download
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Author: HuiWon Choi
Publisher:
ISBN:
Category :
Languages : en
Pages : 94
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Book Description
Model studies on the total synthesis of salvilenone, a phenalenone diterpene found in the roots of Salvia miltiorrhiza Bunge, are reported via a double annulation strategy. The key steps in the proposed synthesis involve a regiocontrolled benzannulation involving the photochemical Wolff rearrangement of an a-diazo ketone and an alkoxy acetylene moiety which assembles an aromatic ring in one step from acyclic precursors followed by an intramolecular [4 + 2] cycloaddition of a conjugated enyne and benzyne intermediate.
Author: HuiWon Choi
Publisher:
ISBN:
Category :
Languages : en
Pages : 94
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Book Description
Model studies on the total synthesis of salvilenone, a phenalenone diterpene found in the roots of Salvia miltiorrhiza Bunge, are reported via a double annulation strategy. The key steps in the proposed synthesis involve a regiocontrolled benzannulation involving the photochemical Wolff rearrangement of an a-diazo ketone and an alkoxy acetylene moiety which assembles an aromatic ring in one step from acyclic precursors followed by an intramolecular [4 + 2] cycloaddition of a conjugated enyne and benzyne intermediate.
Author: Cheryl Faye Lichti
Publisher:
ISBN:
Category : Alkaloids
Languages : en
Pages : 186
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Author: Dennis Joseph Golob
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ISBN:
Category : Alkaloids
Languages : en
Pages : 312
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Author: Thomas Elliott Jacks
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Category :
Languages : en
Pages : 406
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Author: Pamela Cleary
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Category : Asymmetric synthesis
Languages : en
Pages : 254
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Author: Keith Hornberger
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Category :
Languages : en
Pages : 452
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Author: James William Malecha
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Category :
Languages : en
Pages :
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Author: David N. Ridge
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Category :
Languages : en
Pages : 344
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Author: Pierre D. Kary
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Category :
Languages : en
Pages :
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Author: Paiboon Ngernmeesri
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Category :
Languages : en
Pages :
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