Author: Sven Schneider
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ISBN:
Category :
Languages : en
Pages : 292
Book Description
Small Molecule Activation by Cooperative Transition Metal Amido Complexes
Author: Sven Schneider
Publisher:
ISBN:
Category :
Languages : en
Pages : 292
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 292
Book Description
Transition Metal Complexes in Cooperative Lewis Pairs for Small Molecule Activation
Author: Krishna Mistry
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Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Bifunctional Transition Metal Amido Complexes
Author: Anja Friedrich
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Category :
Languages : en
Pages : 237
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 237
Book Description
Ice Cubes
Author:
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Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The Catalytic Activation of Small Molecules by Transition Metal Complexes
Author: Edward Mason Gordon
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ISBN:
Category :
Languages : en
Pages : 456
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 456
Book Description
Bio-inspired First-row Transition Metal Complexes for Small Molecule Activation
Author: Yun Ji Park
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Category :
Languages : en
Pages :
Book Description
Publisher:
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Category :
Languages : en
Pages :
Book Description
Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation
Author: Veeranna Yempally
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ISBN:
Category :
Languages : en
Pages :
Book Description
The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
A Computational Study of Small Molecule Activation in Transition Metal Complexes
Author: Gemma Joy Christian
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Category : Metal activation
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category : Metal activation
Languages : en
Pages :
Book Description
Computational Study of Small Molecule Activation Via Low-coordinate Late First-row Transition Metal Complexes
Author: Aaron Pierpont
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ISBN:
Category : Methane
Languages : en
Pages : 116
Book Description
Publisher:
ISBN:
Category : Methane
Languages : en
Pages : 116
Book Description
Activation of Small Molecules by Transition Metal Complexes Via Computational Methods
Author: Ahmad Najafian
Publisher:
ISBN:
Category : Activation (Chemistry)
Languages : en
Pages : 113
Book Description
Publisher:
ISBN:
Category : Activation (Chemistry)
Languages : en
Pages : 113
Book Description