Ruthenium(II) Complexes with Ferrocene-modified Arene Ligands: Synthesis and Electrochemistry PDF Download
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Languages : en
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![Arene-ruthenium Complexes with Ferrocene-derived Ligands: Synthesis and Characterization of Complexes of the Type [Ru(η[sup]6[/sup]-arene)(NC[sub]5[/sub]H[sub]4[/sub]CH[sub]2[/sub]NHOC-C[sub]5[/sub]H[sub]4[/sub]FeC[sub]5[/sub]H[sub]5[/sub]Cl[sub]2[/sub] and [Ru(η[sup]6[/sup]-arene)(NC[sub]3[/sub]H[sub]3[/sub]N(CH[sub]2[/sub])[sub]2[/sub]O[sub]2[/sub]C-C[sub]5[/sub]H[sub]4[/sub]FeC[sub]5[/sub]H[sub]5[/sub])Cl[sub]2[/sub]] PDF](https://books.google.com/books/content/images/frontcover/R49kzQEACAAJ?fife=w80-h100)
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Languages : en
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Author: Pelokazi Nkombi
Publisher:
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Category : Ligands
Languages : en
Pages : 236
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Author: Y.Z. Voloshin
Publisher: Elsevier
ISBN: 0080529178
Category : Science
Languages : en
Pages : 433
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Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.
Author: Frances Weldon
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 270
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Author: Sanjay Kumar Singh
Publisher: LAP Lambert Academic Publishing
ISBN: 9783659360381
Category :
Languages : en
Pages : 180
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Scientific community has shown decent research interest in the field of organometallic complexes based on platinum group metals owing to their plausible use in synthetic and industrial chemistry. In this regard, transition metal complexes containing 6-arene, 5-Cp and Cp* have drawn special attention. In particular, arene complexes have emerged as versatile intermediate in organic synthesis as a consequence of the ease with which the arene ligand can be functionalized. The presence of a transition metal center and ancillary ligands on one face of the coordinated arene can serve as a valuable stereochemical element. The utility of 6-arene and 5-Cp and Cp* metal complexes emanates not only from the reactivity inherent to the coordinated ring but, also from the control over three facially disposed coordinated sites about a given metal center afforded by incorporation of an arene ligand. In search of new systems based on arene ruthenium chemistry which can behave as potential metallo-ligands, new 6-arene ruthenium and analogous 5-Cp complexes based on chelating N, N and N, O donor ligands and non-chelating nitrogen donor organic ligands has been synthesized and fully characterized.
Author: J. P. Dubey
Publisher: CRC Press
ISBN: 1420092375
Category : Medical
Languages : en
Pages : 336
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Found worldwide from Alaska to Australasia, Toxoplasma gondii knows no geographic boundaries. The protozoan is the source of one of the most common parasitic infections in humans, livestock, companion animals, and wildlife, and has gained notoriety with its inclusion on the list of potential bioterrorism microbes. In the two decades since the publi
Author: Selma Duhovic
Publisher:
ISBN:
Category :
Languages : en
Pages : 291
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This work culminates a systematic study of various uranium complexes supported by ferrocene diamide ligands. Chapter 1 reports the synthesis of 1,1'-ferrocene diamines and describes their electronic and steric properties in both neutral and oxidized forms. Chapter 2 describes an efficient synthesis of uranium dialkyl complexes supported by a single 1,1'- ferrocene diamide ligand, while Chapter 3 explores their reactivity with several aromatic heterocycles. Chapter 4 focuses on the electrochemical behavior of ferrocene-based uranium halide, alkyl, aryloxide, and amide ligands. Finally, Chapter 5 explains electrochemical, spectroscopic, and magnetic properties of uranium bis(1,1'-diamidoferrocene) complexes in an attempt to establish how well uranium mediates electronic communication between two iron centers.
Author: Petr Stepnicka
Publisher: Wiley
ISBN: 9780470035856
Category : Science
Languages : en
Pages : 0
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Ferrocene—the prototypical metallocene—is a fascinating molecule. Even though it was first discovered over fifty years ago, research into ferrocene-containing compounds continues apace, largely stimulated by their successful applications in catalysis, materials science and bioorganometallic chemistry. Ferrocene derivatives are now recognised as useful starting materials for the preparation of new organometallic complexes and functional materials, efficient catalyst components, as well as redox-active modifiers to biomolecules. Ferrocenes: Ligands, Materials and Biomolecules provides the reader with a background overview and describes recent advances in the development and application of ferrocene compounds, including: synthesis and catalytic utilisation of chiral and non-chiral ferrocene ligands ferrocene-based sensors electrooptical materials ferrocene polymers liquid-crystalline materials crystal engineering with ferrocene compounds the bioorganometallic chemistry of ferrocene Ferrocenes: Ligands, Materials and Biomolecules is an essential guide for anyone working in the fields of organometallic synthesis and catalysis, materials science and bioorganometallic chemistry.
Author: Frank Neil Feldmann
Publisher:
ISBN:
Category : Ruthenium
Languages : en
Pages : 286
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