Reactions of Nitrogen Dioxide with Organic Halogen Compounds PDF Download
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Languages : en
Pages :
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Languages : en
Pages :
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Author: D.V.E. George
Publisher:
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Category :
Languages : en
Pages : 268
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Author: K. Jones
Publisher: Elsevier
ISBN: 148313962X
Category : Science
Languages : en
Pages : 259
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The Chemistry of Nitrogen
Author: K.S.B. Addecott
Publisher:
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Category :
Languages : en
Pages : 216
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Author: L. Mázor
Publisher: Elsevier
ISBN: 1483160653
Category : Science
Languages : en
Pages : 292
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Analytical Chemistry of Organic Halogen Compounds presents the procedures applied in the analysis of organic halogen compounds. This book is composed of eight chapters that discuss the methods involved in the production and application of organic halogen compounds and in overcoming contamination problems caused by these compounds. After briefly dealing with the preparation, characteristics, and reactions of organic halogen compounds, this book goes on discussing the fundamental concepts of methods for the detection of halogens in organic compounds, namely, chlorine, bromine, iodine, and fluorine. The following chapter describes the characteristic features, advantages, and disadvantages of ultramicro and submicro chemical methods. A chapter also examines the qualitative and quantitative studies of organic halogen compounds based on the thermal and chemical stability of these compounds. The concluding chapters discuss the interference or interfering effects of halogens and their elimination in the determination of other elements. A list of physical constants of organic halogen compounds of general pharmaceutical and industrial significance is provided. This book is an ideal source for analytical chemists and other workers who are interested in the theoretical bases of the methods.
Author: Eugene Park Cofield
Publisher:
ISBN:
Category : Chemistry, Organic
Languages : en
Pages : 128
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Author: Air Pollution Technical Information Center
Publisher:
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Category : Air
Languages : en
Pages : 644
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Author: Thomas D. Allston
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 178
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"Infrared absorption spectroscopy was used to study the reaction of nitrogen dioxide with a number of halide salts: MX (s) + 2N02 (g), XNO (g) + MN03 (s), where M = metal and X = halogen (CI, Br). This reaction was observed for the chloride and bromide salts of sodium, potassium, calcium and magnesium. These reactions do not reach thermodynamic equilibrium, and evidence is presented that they are surface controlled. These reactions are very fast and evidence is reported for the relative rates of the chloride and bromide salts. The following mechanism may explain the observed experimental results: (M+X- )(s) + N02(g) (M+X-N02)(s) (M+x-N02)(s) (M+XN02- )(s) (M+XN02-N02)(s) + N02(g) (M+XN02-N02)(s) (M+XN02-N02)(s) (M+XNON03- )(s) (M+XNON03- )(s) (M+N03- )(s) + XNO(g), where (M X- ) (s), XNO (g), and the subscript "(s)" refer to the halide salt, nitrosyl halide, and the solid state respectively."--Abstract.
Author: United States. Dept. of Energy. Technical Information Center
Publisher:
ISBN:
Category :
Languages : en
Pages : 868
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Category :
Languages : en
Pages :
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