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Author: Guokui Liu
Publisher: Springer Science & Business Media
ISBN: 3540282092
Category : Science
Languages : en
Pages : 567
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Book Description
Aimed at researchers and graduate students, this book provides up-to-date information about the electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties covers electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions of materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.
Author: Guokui Liu
Publisher: Springer Science & Business Media
ISBN: 3540282092
Category : Science
Languages : en
Pages : 567
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Book Description
Aimed at researchers and graduate students, this book provides up-to-date information about the electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties covers electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions of materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.
Author: Vinny R. Sastri
Publisher: Elsevier
ISBN: 0080536689
Category : Science
Languages : en
Pages : 1005
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Book Description
In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitled Handbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications. The present title consists of twelve chapters. 1. Introduction2. General aspects3. Stability of complexes4. Lanthanide complexes5. Structural chemistry of lanthanide compounds6. Organometallic complexes7. Kinetics and mechanisms of rare earths complexation8. Spectroscopy of lanthanide complexes9. Photoelectron spectroscopy of rare earths10. Lanthanide NMR shift reagents11. Environmental ecological biological aspects12. Applications The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.
Author: Brian G. Wybourne
Publisher:
ISBN:
Category : Earths, Rare
Languages : en
Pages : 258
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Book Description
Author: Uygun V. Valiev
Publisher: Scientific Research Publishing, Inc. USA
ISBN: 1618960547
Category : Science
Languages : en
Pages : 146
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Book Description
A comparison of theory with experiment is made for rare-earth compounds with garnet structure and orthoaluminate whose optical, magnetic and magnetooptical features have been studied sufficiently well by now.
Author: Ch. Kerekes
Publisher: Elsevier
ISBN: 148315520X
Category : Science
Languages : en
Pages : 73
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Book Description
Atlas and Tables for Emission Spectrographic Analysis of Rare Earth Elements focuses on the analysis of rare earths with the Zeiss Q 24 spectrograph or with instruments of similar dispersion. The book first offers information on the division of the spectra of rare earth elements and Sc and Y into three groups. The spectra of Ce, Pr, Nd, Gd, Tb, Dy, Ho, and Er have lines that, however, do not form characteristic line groups. The text underscores that in preparing the Atlas, the spectral pure-grade rare earth oxides sold by the Johnson & Matthey Co. were considered. Through the help of their spectra, the usable analysis lines and the wavelength values of the interfering spectral lines are created. The operating and photographic conditions are tabulated. The book stresses that for each rare earth, the analysis lines are provided in order of decreasing wavelength. The number located in the lower left corner for each analysis line indicates its relative intensity. The fifteen columns contain the interfering lines of other rare earths and of Sc and Y. The interfering lines are created through the use of the double projector of the Optica Milano Co. and the Gatterer Spectrum. The text is a great source of information for readers wanting to analyze rare earths with the Zeiss Q 24 spectrograph or with instruments of similar dispersion.
Author:
Publisher: Elsevier
ISBN: 008054858X
Category : Science
Languages : en
Pages : 559
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Book Description
Optical spectroscopy has been instrumental in the discovery of many lanthanide elements. In return, these elements have always played a prominent role in lighting devices and light conversion technologies (Auer mantles, incandescent lamps, lasers, cathode-ray and plasma displays). They are also presently used in highly sensitive luminescent bio-analyses and cell imaging. This volume of the Handbook on the Physics and Chemistry of Rare Earths is entirely devoted to the photophysical properties of these elements. It is dedicated to the late Professor William T (Bill) Carnall who has pioneered the understanding of lanthanide spectra in the 1960's and starts with a Dedication to this scientist. The following five chapters describe various aspects of lanthanide spectroscopy and its applications. Chapters 231 presents state-of-the-art theoretical calculations of lanthanide energy levels and transition intensities. It is followed by a review (Chapter 232) on both theoretical and experimental aspects of f-d transitions, a less well known field of lanthanide spectroscopy, yet very important for the design of new optical materials. Chapter 233 describes how confinement effects act on the photophysical properties of lanthanides when they are inserted into nanomaterials, including nanoparticles, nanosheets, nanowires, nanotubes, insulating and semiconductor nanocrystals. The use of lanthanide chelates for biomedical analyses is presented in Chapter 234; long lifetimes of the excited states of lanthanide ions allow the use of time-resolved spectroscopy, which leads to highly sensitive analyses devoid of background effect from the autofluorescence of the samples. The last review (Chapter 235) provides a comprehensive survey of near-infrared (NIR) emitting molecular probes and devices, spanning an all range of compounds, from simple chelates to macrocyclic complexes, heterometallic functional edifices, coordination polymers and other extended structures. Applications ranging from telecommunications to light-emitting diodes and biomedical analyses are assessed.- Provides a comprehensive look at optical spectroscopy and its applications- A volume in the continuing authoritative series which deals with the chemistry, materials science, physics and technology of the rare earth elements
Author: Ashok K. Vaseashta
Publisher: Springer Science & Business Media
ISBN: 9781402035609
Category : Technology & Engineering
Languages : en
Pages : 446
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Book Description
The principal aim of this NATO Advanced Study Institute (ASI) "Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology" was to present a contemporary overview of the field of nanostructured and advanced electronic materials. Nanotechnology is an emerging scientific field receiving significant worldwide attention. On a nanometer scale, materials or structures may possess new and unique physical properties. Some of these are now known to the scientific community, but there may well be many properties not yet known to us, rendering it as a fascinating area of research and a suitable subject for a NATO ASI. Yet another aspect of the field is the possibility for creating meta-stable phases with unconventional properties and the ultra-miniaturization of current devices, sensors, and machines. Such nanotechnological and related advanced materials have an extremely wide range of potential applications, viz. nanoscale electronics, sensors, optoelectronics, photonics, nano-biological systems, na- medicine, energy storage systems, etc. This is a wide-ranging subject area and therefore requires the formation of multi-disciplinary teams of physicists, chemists, materials scientists, engineers, molecular biologists, pharmacologists, and others to work together on the synthesis and processing of materials and structures, the understanding of their physical properties, the design and fabrication of devices, etc. Hence, in formulating our ASI, we adopted an int- disciplinary approach, bringing together recognised experts in the various fields while retaining a level of treatment accessible to those active in specific individual areas of research and development.
Author: Benli Huang
Publisher: Royal Society of Chemistry
ISBN: 1847550126
Category : Science
Languages : en
Pages : 260
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Book Description
Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) has been widely adopted as a routine analytical technique for elemental analysis in both industry and academia. However, spectral interference can be a major problem, particularly with such line-rich elements as the rare earth elements. An Atlas of High Resolution Spectra of Rare Earth Elements, which comes complete with a CD of spectra in full colour, is a reference source suitable for all analytical spectroscopists. Using some previously unpublished high resolution spectra, this atlas enables users of ICP-AES to select the best lines of any single rare earth element matrix. Clear instructions for the use of the accompanying CD are provided, which allows all adjacent interferent spectral profiles to be displayed and superimposed. Up-to-date and informative, this unique book will be welcomed as a practical and indispensable reference guide by all those who use ICP-AES for the analysis of rare earth elements.
Author: A. A. Kapli͡anskiĭ
Publisher: North Holland
ISBN:
Category : Science
Languages : en
Pages : 776
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Book Description
Spectroscopy of Crystals Containing Rare Earth Ions'' contains chapters on some key problems selected from a broad range of spectroscopic studies of RE-activated solids including both crystalline and glassy materials. Progress in crystal field theory is surveyed, an area which is basic to our understanding of the energy levels. The treatment of dynamical properties includes studies of coherence phenomena in isolated ions, energy transfer between ions and co-operative phenomena associated with ion-ion and ion-lattice interactions. In addition, the role of electron spins and nuclear spins is studied by light scattering and double resonance techniques. The presence of inhomogeneous broadening of spectral lines is observed and studied in many contexts, leading to new insights into general problems of the disordered state. Considerable attention is devoted to describing new experimental techniques whose development is of prime importance for progress in the spectroscopy of RE-activated solids. Many of these rely on the development and application of tunable lasers. At the moment this is a very active field of spectroscopy with more exciting developments likely to occur in the future.
Author: J. McCarthy
Publisher: Springer Science & Business Media
ISBN: 1461334063
Category : Science
Languages : en
Pages : 582
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Book Description
The Fifteenth Rare Earth Research Conference was held June 15-18, 1981 on the Rolla campus of th.e University of Missouri. The conference was hosted by the Graduate Center for Materials Research, the College of Arts and Science, and the School of Mines and Metallurgy. It was expected that the conference would provide a forum for critical examination and review of the current and important trends in rare earth science and technology. To this end, over 170 papers were presented in both oral and poster sessions by researchers representing some nineteen countries. The program committee was particularly gratified to see the diversity of effort being devoted to rare earth research by different disciplines allover the world. The collection of refereed papers in this volume attests to the fact that the objectives of the program committee were indeed realized. A high point of the meeting was the presentation of the Frank n. Spedding Award to a most distinguished colleague, Professor Georg Busch, Eidgenossische Technische Hochschule, Zurich. Prof essor W. Edward hi"allace, University of Pittsburgh, recipient of the first Frank H. Spedding Award made the presentation to Professor Busch who then gave the Plenary Address.
