Author: G. Porter
Publisher: Elsevier
ISBN: 1483195007
Category : Science
Languages : en
Pages : 400
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Book Description
Progress in Reaction Kinetics discusses the main themes of chemical kinetics. It covers such topics as the reactions of halogen atoms and methylenes, mercury photosensitized reactions, anionic polymerization, cis trans-isomerisation, and protolytic reactions. The book provides a good illustration of the quantitative rate studies in biochemical systems. The experiments to determine the relative rate constants are shown and analyzed. The process of photosensitization involves absorption of light energy by a strongly absorbing substance. The methods to identify the reactions of carbonyl compounds, organic acids and esters are presented as well as the reactions of alcohols, ethers, and epoxides. The degree of reaction of some haem compounds is explained. A chapter of the book focuses on the kinetic treatment of processes that takes place in a series of steps. Such procedures are called consecutive processes. A sample of these is the rate-determining step approximation. The book will provide useful information to chemists, chemical engineers, students, and researchers.
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Languages : en
Pages : 0
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Book Description
Author: K. R. Jennings
Publisher: Elsevier
ISBN: 148314612X
Category : Science
Languages : en
Pages : 302
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Book Description
Progress in Reaction Kinetics, Volume 6 covers various aspects of kinetics. It presents quantitative data on the reaction rates observed in hydrocarbon-active nitrogen systems, noble gases, acids and bases, and rare gas metastable atoms. Comprised of six chapters, the volume begins by discussing the reactions of nitrogen atoms with hydrocarbons. It then illustrates the development of flash protolysis techniques and moves on to chemi-ionization and chemical applications of rare gases. The text concludes by describing salt and medium effects in ionic reactions in aqueous solutions. Students and scientists who wish to increase their understanding of reactions occurring in various chemical reaction systems will find this volume invaluable.
Author: K. R. Jennings
Publisher: Elsevier
ISBN: 148316389X
Category : Science
Languages : en
Pages : 315
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Book Description
Progress in Reaction Kinetics, Volume 8 explores the rates of chemical processes of different elements and compounds. In this volume, a review of significant developments in both gas and solution kinetics is given, followed by the relating of current work to earlier studies. Studied in this volume are the reactions of atomic oxygen with organic compounds; the kinetics of gaseous fluorine reactions and proton-transfer reaction in aprotic solvents; the chemical aspects of homogeneous liquid phase inorganic oscillatory reactions; and the mechanisms for the photochemical production of hydrocarbons in gaseous hydrocarbon systems. The book is highly recommended for those who study and practice in the different fields of chemistry, especially those who specifically wish to learn more about reaction kinetics.
Author: G. Porter
Publisher: Elsevier
ISBN: 1483224953
Category : Science
Languages : en
Pages : 532
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Book Description
Progress in Reaction Kinetics, Volume 4 is a 10-chapter text that focuses on the reactions of nitrogen atoms in the gas phase and some chemical factors in the kinetics of processes at electrodes. This volume describes first the free radical reactions dealing with halogenomethyl and alkoxyl radicals. The next chapters deal with electronically excited states, proton transfer, and kinetics of electrode processes. These topics are followed by discussions on the primary processes in the gas phase photochemistry of carbonyl compounds, as well as the mechanisms and rates of radiationless energy transfer. This book also looks into the methods used for the measurement of fluorescence lifetimes of aromatic compounds. A chapter examines the chemiluminescence in the oxidation of organic compounds and for other liquid-phase reactions. The last chapters discuss the role of the solvent in proton transfer reactions and some aspects of developments in the field of electrode processes. This book is of great value to reaction kinetics scientists and researchers.
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Languages : en
Pages : 0
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Book Description
Author: G. Porter
Publisher: Elsevier
ISBN: 148314531X
Category : Science
Languages : en
Pages : 476
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Book Description
Progress in Reaction Kinetics
Author: G. Porter
Publisher: Elsevier
ISBN: 1483213722
Category : Science
Languages : en
Pages : 524
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Book Description
Progress in Reaction Kinetics, Volume 3 presents articles about advances in reaction kinetics. The book begins with a theoretical review of bimolecular reactions, such as the relation between free energy and potential energy surfaces. The text describes reactions of hydrogen atoms in the gas phase; the hot atom chemistry of gas-phase systems; the inhibition of gaseous free radical chain reactions; and vibrational relaxation in gases. Articles about pulse radiolysis; the effects of dose-rate and linear energy transfer in radiation chemistry; and the electronic spectra and kinetics of aromatic free radicals are also considered. The book further tackles the kinetics of polymerization of vinyl monomers by lithium alkyls as well as radical polymerization in solutions. Chemists and professionals dealing with radiation, physical, and industrial chemistry will find the book invaluable.
Author: K. R. Jennings
Publisher: Elsevier
ISBN: 1483146111
Category : Science
Languages : en
Pages : 198
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Book Description
Progress in Reaction Kinetics, Volume 7 is a three-chapter book that first discusses the ion association in proton transfer reactions. Chapter 2 details the use of ESR for the quantitative determination of gas phase atom and radical concentrations. The last chapter centers on the modulation techniques in chemical kinetics.
Author: K. R. Jennings
Publisher: Elsevier
ISBN: 1483145956
Category : Science
Languages : en
Pages : 391
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Book Description
Progress in Reaction Kinetics, Volume 9 summarizes recent advances that have been made with regards to reaction kinetics. Kinetic applications of nuclear magnetic resonance spectroscopy are described, and tunneling reactions of solvated electrons in liquids and glasses are discussed. The reactions of free radicals generated by organic compounds are also considered. This volume consists of three chapters and begins with a discussion of basic NMR theory, including the NMR phenomenon and nuclear spin relaxation processes. Special attention is paid to the dynamic characteristics of chemical exchange reactions which occur in a system at equilibrium, along with techniques for determining chemical exchange parameters from time domain spectra and time dependent frequency domain spectra. The reader is then introduced to tunneling reactions of solvated electrons in liquids and glasses, with emphasis on the mode of transport by which the electron induces such a reaction. A model of diffusion-controlled reactions incorporating a tunneling reaction mechanism is described. A chapter analyzing the use of radiation to produce reactions of free radicals from organic compounds in aqueous solution, including hydrocarbons and carbonyl compounds, concludes the book. This book will be of interest to scientists, students, and researchers working in the fields of chemistry and the molecular sciences.
