Procedures for the Rheological Characterization of the Nonlinear Behaviour of Complex Fluids in Shear and Squeeze Flows PDF Download
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Author: Daniela Georgeta Coblaş
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
This paper was dedicated exclusively to the rheological characterization of simple and complex fluids and a detailed analyze of available rheometric testing procedures. Throughout this thesis the rheological behavior of both simple and complex fluids has been studied and modeled in both shear and the complex motions (shear tests and squeezing tests). By linking conventional experimental test methods with numerical simulations of real flows, this thesis introduces a new concept in rheology: Computational Rheometry. All experimental investigations carried out in this study for the squeezing flows were accompanied by numerical simulations. For the oscillatory squeezing flow the influence of initial film thikness, oscillatory amplitude and frequency, computational time step was investigated by comparison with the theoretical predictions of squeeze force and a Genrealized Reynolds Equation inclued in a finite element code in Fortran. A validity domain was established for the analitical formulation of squeezing force. The constant velocity squeeze flow was investigated also using a quasi-steady approximation of the motion, which brings a significant reduction of the computational time, and a very good correlation with the transient (deformable mesh) approximation and the analytical predictions. The investigation of free surface influence on the distribution of normal force in both constant velocity and oscillatory squeeze flow was analyzed. In the case of constant velocity squeeze flow, the numerical simulations coupled with the free surface evolution and measured normal force during experimental investigations are suggesting the presence of a partial slip during the experimen.
Author: Daniela Georgeta Coblaş
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
This paper was dedicated exclusively to the rheological characterization of simple and complex fluids and a detailed analyze of available rheometric testing procedures. Throughout this thesis the rheological behavior of both simple and complex fluids has been studied and modeled in both shear and the complex motions (shear tests and squeezing tests). By linking conventional experimental test methods with numerical simulations of real flows, this thesis introduces a new concept in rheology: Computational Rheometry. All experimental investigations carried out in this study for the squeezing flows were accompanied by numerical simulations. For the oscillatory squeezing flow the influence of initial film thikness, oscillatory amplitude and frequency, computational time step was investigated by comparison with the theoretical predictions of squeeze force and a Genrealized Reynolds Equation inclued in a finite element code in Fortran. A validity domain was established for the analitical formulation of squeezing force. The constant velocity squeeze flow was investigated also using a quasi-steady approximation of the motion, which brings a significant reduction of the computational time, and a very good correlation with the transient (deformable mesh) approximation and the analytical predictions. The investigation of free surface influence on the distribution of normal force in both constant velocity and oscillatory squeeze flow was analyzed. In the case of constant velocity squeeze flow, the numerical simulations coupled with the free surface evolution and measured normal force during experimental investigations are suggesting the presence of a partial slip during the experimen.
Author: Abhijit P. Deshpande
Publisher: Springer Science & Business Media
ISBN: 1441964940
Category : Technology & Engineering
Languages : en
Pages : 259
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Book Description
The aim of the School on Rheology of Complex fluids is to bring together young researchers and teachers from educational and R&D institutions, and expose them to the basic concepts and research techniques used in the study of rheological behavior of complex fluids. The lectures will be delivered by well-recognized experts. The book contents will be based on the lecture notes of the school.
Author: Michel A. Beaulne
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
The behaviour of complex materials, the main study of rheology, is investigated in this work. In an effort to better understand these materials, a two-step process was undertaken. First, the nonlinear behaviour of such materials was determined in a laboratory. Second, experimental measurements were extracted from the literature with respect to shear-free flows of complex materials and simulations were performed for the shear-five flows in question. These flows involve uniaxial extension in the case of fiber spinning and film casting, and biaxial extension in the caw of film blowing. Rheological experiments were conducted on polymer solutions, namely poly(ethylene oxide) and polyacrylamide, at room temperature and on a polypropylene (PP) polymer melt at high temperature, with a Weissenberg rheogoniometer in a laboratory. The shear viscosity and first normal stress difference were measured at varying shear rates. An integral constitutive equation of the K-BKZ type was used to predict the nonlinear behaviour of these materials. Transient regression was performed to find the parameters of the K-BKZ model for the U-Stamylan low-density polyethylene (LDPE), and predictions for steady-state materials functions were given. Fiber-spinning simulations were undertaken for a series of complex materials at a wide range of operating conditions. Film-casting simulations were also undertaken for a series of complex materials. (Abstract shortened by UMI.).
Author: A.A. Collyer
Publisher: Springer Science & Business Media
ISBN: 9401728984
Category : Technology & Engineering
Languages : en
Pages : 653
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Book Description
In many cases rheological measurements are carried out in the simplest of geometries, but the interpretation involved in obtaining the rheological parameters of the test fluids from these measurements is surprisingly complex. The purpose of this book is to emphasise the points on which most workers in the field agree, and to let the authors deal with the contentious points according to their own beliefs and experience. This work represents a summary of the current thought on rheological meas urement by experts in the various techniques. When making measurements and obtaining from them parameters that describe the flow behaviour of the test fluids, it is essential that the experimentalist understands the underlying theory and shortcomings of the measurement technique, that he is aware of the likely microstructure of the fluid, and that from this he can appreciate how the fluid and the measuring system will interact with each other. It is this interaction that gives both the required rheological parameters of the fluids and the artefacts that confuse the issue. This book covers the main rheological measurement techniques from capillary, slit and stretching flows to rotational and oscillatory rheometry in various geometries including sliding plate measurements. These topics are backed up by chapters on more practical aspects, such as commercial instruments, and on computer control and data acquisition. The chapters deal with the basic methods, how the measurements are taken, and what assumptions and interpretations are made to obtain valid data on the test fluids.
Author: Christopher Joseph Hershey
Publisher:
ISBN: 9780438329324
Category : Electronic dissertations
Languages : en
Pages : 116
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Book Description
Author: Abhijit P. Deshpande
Publisher:
ISBN: 9781441964953
Category :
Languages : en
Pages : 272
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Book Description
Author: R. P. Chhabra
Publisher: Butterworth-Heinemann
ISBN: 0080951600
Category : Technology & Engineering
Languages : en
Pages : 535
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Book Description
This book bridges the gap between the theoretical work of the rheologist, and the practical needs of those who have to design and operate the systems in which these materials are handled or processed. It is an established and important reference for senior level mechanical engineers, chemical and process engineers, as well as any engineer or scientist who needs to study or work with these fluids, including pharmaceutical engineers, mineral processing engineers, medical researchers, water and civil engineers. This new edition covers a considerably broader range of topics than its predecessor, including computational fluid dynamics modelling techniques, liquid/solid flows and applications to areas such as food processing, among others. - Written by two of the world's leading experts, this is the only dedicated non-Newtonian flow reference in print. - Since first publication significant advances have been made in almost all areas covered in this book, which are incorporated in the new edition, including developments in CFD and computational techniques, velocity profiles in pipes, liquid/solid flows and applications to food processing, and new heat/mass transfer methods and models. - Covers both basic rheology and the fluid mechanics of NN fluids - a truly self-contained reference for anyone studying or working with the processing and handling of fluids
Author: Bavand Keshavarz
Publisher:
ISBN:
Category :
Languages : en
Pages : 337
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Book Description
The fragmentation and breakup of complex fluids are fundamental elements of many industrial and biological processes. The fracture of food gels, atomization of paints, combustion of fuels containing anti-misting agents and application of pharmaceutical and agricultural sprays, as well as involuntary physiological processes such as sneezing, are common examples in which the atomized/fractured material contains synthetic or biological macromolecules that result in viscoelastic fluid characteristics. For many of these processes the effects of varying the rheological properties on the dynamics of fragmentation or fracture are still poorly understood. In this thesis, we investigate some of the underlying complexities associated with varying the rheology of such materials in both shear and elongation. The complex nonlinear rheology of these complex fluids under representative conditions of large strain and deformation rate is difficult to quantify experimentally and is a known challenge for existing constitutive models. The contribution of this thesis is therefore to develop and exploit several new experimental tools that enable precise rheological measurements under appropriate test conditions. A better experimental understanding of the dynamics of fragmentation/fracture in complex fluids will also help guide the development of new theoretical models that can quantitatively predict the mechanical response of complex fluids in such flows. Two distinct classes of model fluids/gels are studied in this thesis. First, a series of model viscoelastic solutions composed of a flexible homopolymer, poly(ethylene oxide) or PEO, dissolved in a water/glycerol mixture. These dilute solutions are known to behave very similarly to their Newtonian solvent in shearing deformations but exhibit markedly different extensional rheological properties due to the onset of a coil-stretch transition in the solvated microstructure at high elongation rates. Secondly we also consider a family of biopolymer networks: acid-induced casein gels. These canonical protein gels display a multiscale microstructure that is responsible for their gel-like viscoelastic properties. Upon external deformation, these soft viscoelastic solids exhibit a generic power-law rheological response followed by pronounced stress- or strain-stiffening prior to irreversible damage and failure, most often through macroscopic fractures. We study the dynamics of fragmentation for the dilute PEO solutions in different canonical flows: air-assisted atomization, drop impact on a small target, jet impact atomization and rotary spraying. We also study the fracture of the casein protein gels under conditions of both constant applied stress and constant applied shear rate. Through quantitative study of these high strain and high deformation rate phenomena, we reach several conclusions about how the rheological properties of these materials can affect their mechanical behavior in fragmentation/fracture. First, for dilute viscoelastic solutions, the breakup and atomization of these fluids is markedly different than the analogous processes in a simple Newtonian fluid. The average droplet diameter shows a monotonic increase with added viscoelasticity, which is precisely monitored by accurate measurements of elongational relaxation times through a novel characterization method we have developed; Rayleigh Ohnesorge Jet Elongational Rheometry (ROJER). Based on our measurements of the material relaxation time scale a new theoretical model for the evolution in the average droplet diameter is developed for viscoelastic sprays. Second, the size distributions measured in each viscoelastic fragmentation process show a systematic broadening from the Newtonian solvent. In each case the droplet sizes are well described by Gamma distributions that correspond to an underlying fragmentation/coalescence scenario. We show that this broadening results from the pronounced change in the corrugated shape of viscoelastic ligaments as they separate from the liquid core. These corrugations saturate in amplitude and the measured distributions for viscoelastic liquids in each process are given by a universal probability density function, corresponding to a Gamma distribution with nmin = 4. The breadth of this size distribution for viscoelastic filaments is shown to be constrained by a geometrical limit, which can not be exceeded in ligament-mediated fragmentation phenomena. Third, in the fracture of the model acid-induced protein gels, we show that the fractal network of the underlying microstructure leads to a very broad power-law behavior in their linear viscoelastic response that can be precisely modeled by a simple model based on fractional calculus. We show that specific geometric properties of the microstructure set the value of the parameters that are used in the fractional model. The nonlinear viscoelastic properties of the gel can be described in terms of a 'damping function' that enables quantitative prediction of the gel mechanical response up to the onset of macroscopic failure. Using a nonlinear integral constitutive equation - built upon the experimentally-measured damping function in conjunction with power-law linear viscoelastic response - we derive the form of the stress growth in the gel following the start up of steady shear. We also couple the shear stress response with Bailey's durability criteria for brittle solids in order to predict the critical values of the stress and strain for failure of the gel, and show how they scale with the applied shear rate. This provides a generalized failure criterion for biopolymer gels across a range of different deformation histories. Results from this work are of relevance to many processes that involve breakup and rupture of complex fluids such as failure of viscoelastic gels, emulsification, spray painting and even biological processes such as pathogen transfer resulting from violent expiration. By investigating the linear and nonlinear behavior of two distinct classes of soft matter that lie on two ends of the viscoelasticity spectrum, one close to Newtonian liquids and one close to elastic solids, we provide key physical insights that can be generalized to broad classes of different complex fluids that undergo fracture and fragmentation processes.
Author: Joshua David John Rathinaraj
Publisher:
ISBN:
Category :
Languages : en
Pages : 177
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Book Description
Temporal changes in microstructure and relaxation dynamics are ubiquitously observed in materials such as hydrogels, food products and drilling fluids. These materials are in general known as mutating materials and the build-up or breakdown of microstructure is commonly both time- and shear-rate (or shear-stress)-dependent resulting in a range of complex phenomena collected under the term thixotropy. It is becoming increasingly im- portant to develop time-resolved rheometric techniques to quantify the behavior of mutating materials accurately. In the present study we first discuss the introduction of better time-resolved techniques in superposition rheometry. Conventional superposition rheometry consists of combining Small Amplitude Oscillatory Shear (SAOS) with a steady unidirectional shear rate to gain insight into the shear-induced changes to the viscoelastic properties of a complex fluid. Orthogonal superposition (OSP), in which the two modes of deformation are perpendicular, has been preferred over parallel superposition to avoid non-linear cross-coupling of the steady shear and oscillatory deformation fields. This cross coupling can lead to unphysi- cal sign changes in the measured material properties, and makes it difficult to interpret the flow-induced mechanical properties. Recently, orthogonal superposition has been used to investigate the shear-induced anisotropy taking place in colloidal gels by comparing the transient evolution of orthogonal moduli with the parallel moduli immediately after cessa- tion of shear. However, probing transient evolution using the OSP technique can be chal- lenging for rapidly mutating complex materials which evolve on time scales comparable to the time scale of the experiment. Using a weakly associated alginate gel, we demonstrate the potential of superimposing fast optimally windowed chirp (OWCh) deformations or- thogonally to the shear deformation which substantially reduces the measurement time. We evaluate the changes in the rate-dependent relaxation spectrum in the direction of applied unidirectional shear rate and in the orthogonal direction deduced from the damping function and orthogonal moduli data respectively. We measure systematic changes between the two spectra measured in orthogonal directions thus revealing and quantifying flow-induced anisotropy in the alginate gel. Secondly, we develop a signal processing technique to monitor accurate temporal evolution of the complex modulus for a specified deformation frequency. Oscillatory rheometric techniques such as Small Amplitude Oscillatory Shear (SAOS) and, more recently, Large Amplitude Oscillatory Shear (LAOS) are now quite widely used for rheological characterization of the viscoelastic properties of complex fluids. However, the conventional application of Fourier transforms for analyzing oscillatory data assume the signals are time- translation invariant, which constrains the rate of mutation of the material to be extremely small. This constraint makes it difficult to accurately study shear-induced microstructural changes in thixotropic and gelling materials. We explore applications of the Gabor transform (a Short Time Fourier Transform (STFT) combined with a Gaussian window), for providing optimal joint time-frequency resolution of a mutating material's viscoelastic properties. First, we show using simple analytic models that application of the STFT enables extraction of useful data from the initial transient response following the inception of oscillatory flow. Secondly, using measurements on a Bentonite clay we show that using a Gabor transform enables us to more accurately measure rapid changes in both the storage and loss modulus with time, and also extract a characteristic thixotropic/aging time scale for the material. Finally, we consider extension of the Gabor transform to non-linear oscillatory deformations using an amplitude-modulated input strain signal, in order to track the evolution of the Fourier-Chebyshev coefficients characterizing thixotropic fluids at a specified deformation frequency. We show that there is a trade-off between frequency and time resolution (effectively a rheological uncertainty principle). We refer to the resulting test proto col as Gaborheometry and construct an operability diagram in terms of the imposed ramp rate and the mutation time of the material. This unconventional, but easily implemented, rheometric approach facilitates both SAOS and LAOS studies of time-evolving materials, reducing the number of required experiments and the data post-processing time significantly. Finally, we use the time-resolved techniques developed in this thesis to understand the thixotropic aging behavior of bentonite dispersions. In soft glassy materials such as ben- tonite clays, the relaxation dynamics and the microstructure slowly but continuously evolve with time to progressively form more stable structures. We investigate and quantify this complex aging behavior of bentonite dispersions by measuring the evolution in the linear viscoelastic behavior at different age times and temperatures. We model the linear viscoelastic properties using a material time domain transformation and a fractional Maxwell gel model which allows us to develop a rheological master curve to quantify and predict the aging behavior of this soft glass over a range of temperatures and time scales. The time-resolved rheometric techniques and procedures for quantifying the rheology of rapidly mutating complex fluids can be extended to a wide range of soft materials and allows us to obtain insight into how microstructural changes drive the evolution in the bulk rheological behavior for thixotropic and aging materials.
Author: Giovanni Astarita
Publisher: Springer Science & Business Media
ISBN: 1468437437
Category : Science
Languages : en
Pages : 646
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Book Description
At the VIIth International Congress on Rheology, which was held in Goteborg in 1976, Proceedings were for the first time printed in advance and distributed to all participants at the time of the Congress. Although of course we Italians would be foolish to even try to emulate our Swedish friends as far as efficiency of organization is concerned, we decided at the very beginning that, as far as the Proceedings were concerned, the VIIIth International Congress on Rheology in Naples would follow the standards of time liness set by the Swedish Society of Rheology. This book is the result we have obtained. We wish to acknowledge the cooperation of Plenum Press in producing it within the very tight time schedule available. Every four years, the International Congress on Rheology represents the focal point where all rheologists meet, and the state of the art is brought up to date for everybody interested; the Proceedings represent the written record of these milestones of scientific progress in rheology. We have tried to make use of the traditions of having invited lectures, and of leaving to the organizing committee the freedom to choose the lecturers as they see fit, in order to collect a group of invited lectures which gives as broad as possible a landscape of the state of the art in every relevant area of rheology. The seventeen invited lectures are collected in the first volume of the proceedings.
