Author: Emily Catherine Chong
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages :
Book Description
A quasiracemate is the cocrystallization of two similarly shaped but chemically distinct molecules of opposite handedness. There has been limited to no work regarding quasiracemates in the field of inorganic chemistry. The goal of this study was to prepare various metal based enantiomers, racemates, and quasiracemates using N-benzoylalanines with imidazole or N-methylimidazole as ligands bound to copper to form a metal complex. In this study, we developed a method to prepare substituted N-benzoylalanines and its copper complexes. We also prepared one co-crystal between two differently substituted N-benzoylalanines. This work reports the successful synthesis and crystal structure analysis of an organic quasiracemate, (D-4-nitro-N-benzoylalanine)(L-4-methyl-N-benzoylalanine), an inorganic quasiracemate, bis(N-methylimidazole)(D-4-nitro-N-benzoylalanine)(L-4- methyl-N-benzoylalanine)copper(TT), and a racemate bis(N-methylimidazole)bis(D,L-4-nitro-N-benzoylalanine)copper(TT).
Preparation and Crystal Structures of Racemic and Quasiracemic Imidazole Or N-methyl Imidazole Copper Complexes Containing Substituted N-benzoylalanines
Author: Emily Catherine Chong
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages :
Book Description
A quasiracemate is the cocrystallization of two similarly shaped but chemically distinct molecules of opposite handedness. There has been limited to no work regarding quasiracemates in the field of inorganic chemistry. The goal of this study was to prepare various metal based enantiomers, racemates, and quasiracemates using N-benzoylalanines with imidazole or N-methylimidazole as ligands bound to copper to form a metal complex. In this study, we developed a method to prepare substituted N-benzoylalanines and its copper complexes. We also prepared one co-crystal between two differently substituted N-benzoylalanines. This work reports the successful synthesis and crystal structure analysis of an organic quasiracemate, (D-4-nitro-N-benzoylalanine)(L-4-methyl-N-benzoylalanine), an inorganic quasiracemate, bis(N-methylimidazole)(D-4-nitro-N-benzoylalanine)(L-4- methyl-N-benzoylalanine)copper(TT), and a racemate bis(N-methylimidazole)bis(D,L-4-nitro-N-benzoylalanine)copper(TT).
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages :
Book Description
A quasiracemate is the cocrystallization of two similarly shaped but chemically distinct molecules of opposite handedness. There has been limited to no work regarding quasiracemates in the field of inorganic chemistry. The goal of this study was to prepare various metal based enantiomers, racemates, and quasiracemates using N-benzoylalanines with imidazole or N-methylimidazole as ligands bound to copper to form a metal complex. In this study, we developed a method to prepare substituted N-benzoylalanines and its copper complexes. We also prepared one co-crystal between two differently substituted N-benzoylalanines. This work reports the successful synthesis and crystal structure analysis of an organic quasiracemate, (D-4-nitro-N-benzoylalanine)(L-4-methyl-N-benzoylalanine), an inorganic quasiracemate, bis(N-methylimidazole)(D-4-nitro-N-benzoylalanine)(L-4- methyl-N-benzoylalanine)copper(TT), and a racemate bis(N-methylimidazole)bis(D,L-4-nitro-N-benzoylalanine)copper(TT).
Preparation and Crystal Structures of Chiral and Non-chiral Mixed Ligand Copper Complexes Containing N-methyl Imidazole and Various N-phthaloylalanines
Author: Hiral Patel
Publisher:
ISBN:
Category : Chirality
Languages : en
Pages : 110
Book Description
Publisher:
ISBN:
Category : Chirality
Languages : en
Pages : 110
Book Description
Preparation and X-ray Crystallographic Studies of Copper N-methylimidazole Complexes with Substituted N-phthaloylalanine Ligands
Author: Mohit Singhal
Publisher:
ISBN:
Category : Enantiomers
Languages : en
Pages : 164
Book Description
Publisher:
ISBN:
Category : Enantiomers
Languages : en
Pages : 164
Book Description