Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 20
Get Book Here
Book Description
In the first two years of this project, we focused on the membrane synthesis, characterization and optimization. In the past year, we have concentrated on the product development for improving the efficiency of hydrogen recovery from coal gasifier off-gas via water-gas-shift (WGS) reaction. A mathematical simulation study has been performed to compare the performance of the membrane reactor (MR) vs conventional packed bed rector for WGS reaction. Our result demonstrates that>99.999% conversion can be accomplished via WGS-MR using the hydrogen selective membrane developed by us. Further, water/CO ratio can be reduced, and>97% hydrogen recovery and
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 438
Get Book Here
Book Description
Author: Panagiotis Smirniotis
Publisher: Elsevier
ISBN: 0444633537
Category : Technology & Engineering
Languages : en
Pages : 280
Get Book Here
Book Description
Water Gas Shift Reaction: Research Developments and Applications outlines the importance of hydrogen as a future fuel, along with the various hydrogen production methods. The book explains the development of catalysts for Water Gas Shift (WGS) reaction at different temperatures and steam/CO ratios, and also discussing the effect of different dopants on the WGS activity of iron oxide and the promotion and inhibition roles of the dopants on the WGS activity of iron oxide are explained. In addition, the book describes extensive characterization of modified ferrite catalysts, especially with Mossbauer spectroscopy and its advantage in understanding properties of metal doped ferrite catalysts, the exact dopant location, and its effect on electron hopping capability and WGS activity of Fe redox couple. - Outlines the importance of the Water Gas Shift Reaction and its application for hydrogen production - Provides detailed information on potential catalysts, their development, and their pros and cons, giving the reader insights on how modified ferrite catalysts work at different temperatures and different steam to CO ratios - Reviews hydrogen technology, its current importance, and production methods - Presents a clear presentation of the topics with many graphics and tables - Offers basic and advanced knowledge of catalysts characterization instrumental techniques
Author: Mehmet Sankir
Publisher: John Wiley & Sons
ISBN: 1119283655
Category : Science
Languages : en
Pages : 653
Get Book Here
Book Description
Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
Author: National Academy of Engineering
Publisher: National Academies Press
ISBN: 0309091632
Category : Science
Languages : en
Pages : 257
Get Book Here
Book Description
The announcement of a hydrogen fuel initiative in the President's 2003 State of the Union speech substantially increased interest in the potential for hydrogen to play a major role in the nation's long-term energy future. Prior to that event, DOE asked the National Research Council to examine key technical issues about the hydrogen economy to assist in the development of its hydrogen R&D program. Included in the assessment were the current state of technology; future cost estimates; CO2 emissions; distribution, storage, and end use considerations; and the DOE RD&D program. The report provides an assessment of hydrogen as a fuel in the nation's future energy economy and describes a number of important challenges that must be overcome if it is to make a major energy contribution. Topics covered include the hydrogen end-use technologies, transportation, hydrogen production technologies, and transition issues for hydrogen in vehicles.
Author: Jürgen Garche
Publisher: Newnes
ISBN: 0444527451
Category : Science
Languages : en
Pages : 4532
Get Book Here
Book Description
The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 7
Get Book Here
Book Description
This program is directed toward the development of a metal-membrane-based process for the economical production of hydrogen at elevated temperature by the reaction of carbon monoxide with steam--i.e., the water-gas shift (WGS) reaction. Key to achieving this objective is the development of an inexpensive and durable metal-membrane module. The specific program objectives include the following: design, fabrication, and demonstration of prototype membrane modules; improving the membrane composition to increase the hydrogen flux; demonstrating that membrane lifetime ≥2 years is likely to be achieved; and conducting engineering and economic analyses of the process. Results to date are given and discussed.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 302
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 388
Get Book Here
Book Description
