Oxidation of Organic Compounds

Oxidation of Organic Compounds PDF Author: N. M. Emanuel
Publisher: Elsevier
ISBN: 1483145115
Category : Science
Languages : en
Pages : 628

Get Book Here

Book Description
Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.

Oxidation of Organic Compounds

Oxidation of Organic Compounds PDF Author: N. M. Emanuel
Publisher: Elsevier
ISBN: 1483145115
Category : Science
Languages : en
Pages : 628

Get Book Here

Book Description
Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.

Oxidation in Organic Synthesis

Oxidation in Organic Synthesis PDF Author: V. K. Ahluwalia
Publisher: CRC Press
ISBN: 9781466506015
Category : Science
Languages : en
Pages : 323

Get Book Here

Book Description
Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions.

Oxidation and Antioxidants in Organic Chemistry and Biology

Oxidation and Antioxidants in Organic Chemistry and Biology PDF Author: Evgeny T. Denisov
Publisher: CRC Press
ISBN: 142003085X
Category : Medical
Languages : en
Pages : 1020

Get Book Here

Book Description
Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information

Metal-Catalyzed Oxidations of Organic Compounds

Metal-Catalyzed Oxidations of Organic Compounds PDF Author: Roger Sheldon
Publisher: Elsevier
ISBN: 0323150047
Category : Science
Languages : en
Pages : 447

Get Book Here

Book Description
Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Basic Principles of Organic Chemistry

Basic Principles of Organic Chemistry PDF Author: John D. Roberts
Publisher:
ISBN: 9780805383218
Category : Chemistry, Organic
Languages : en
Pages : 1596

Get Book Here

Book Description
Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Chromium Oxidations in Organic Chemistry

Chromium Oxidations in Organic Chemistry PDF Author: G. Cainelli
Publisher: Springer Science & Business Media
ISBN: 3642693628
Category : Science
Languages : en
Pages : 272

Get Book Here

Book Description
Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .

Oxidation and Reduction of Organic Compounds

Oxidation and Reduction of Organic Compounds PDF Author: Kenneth L. Rinehart
Publisher: Prentice Hall
ISBN:
Category : Science
Languages : en
Pages : 164

Get Book Here

Book Description


Methods for the Oxidation of Organic Compounds

Methods for the Oxidation of Organic Compounds PDF Author: Alan H. Haines
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 416

Get Book Here

Book Description
Methods for the Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes is an account of the different methods used for the controlled oxidation of alkanes, alkenes, alkynes, and arenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of five chapters and begins with a discussion on alkanes, alkyl groups, and hydrocarbon residues. The formation of alkenes, alcohols, hydroperoxides, dialkyl peroxides, cyclic peroxides, ethers, and esters as well as aldehydes, ketones, and carboxylic ...

Oxidizing and Reducing Agents

Oxidizing and Reducing Agents PDF Author: Steven D. Burke
Publisher: Handbook of Reagents for Organ
ISBN:
Category : Science
Languages : en
Pages : 576

Get Book Here

Book Description
Oxidizing and Reducing Agents S. D. Burke University of Wisconsin at Madison, USA R. L. Danheiser Massachusetts Institute of Technology, Cambridge, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. Handbook of Reagents for Organic Synthesis: Oxidizing and Reducing Agents, provides the synthetic chemist with a convenient compendium of information concentrating on the most important and frequently employed reagents for the oxidation and reduction of organic compounds, extracted and updated from EROS. The inclusion of a bibliography of reviews and monographs, a compilation of Organic Syntheses procedures with tested experimental details and references to oxidizing and reducing agents will ensure that this handbook is both comprehensive and convenient.

Design of Thermal Oxidation Systems for Volatile Organic Compounds

Design of Thermal Oxidation Systems for Volatile Organic Compounds PDF Author: David A Lewandowski
Publisher: CRC Press
ISBN: 1351455710
Category : Nature
Languages : en
Pages : 370

Get Book Here

Book Description
Controlling the emission of volatile organic compounds (VOC) became a very prominent environmental issue with the passage of the 1990 Clean Air Act Amendments, and will continue to be an environmental priority through the next decade. No single technology has played as important a role in the control of VOC emissions as thermal oxidation. It has the ability to destroy VOCs in a one-step process that produces innocuous by-products. Design of Thermal Oxidation Systems for Volatile Organic Compounds provides all the information needed for developing a thermal oxidation design in a single reference. It covers design, operation, and maintenance as well as the principles behind the classification of volatile organic compounds as hazardous waste. The author explores the primary purpose of thermal oxidizers and discusses their limitations. The book provides: practical, complete, and concise thermal oxidizer design principles an outline of state-of-the-art design principles a practical rather than theoretical approach real industrial examples in each chapter With the new regulations that affect VOC emissions, engineers from such diverse fields as oil refining, chemical distillation and separation processes, and pharmaceutical industries will need to design and implement thermal oxidation systems. Design of Thermal Oxidation Systems for Volatile Organic Compounds provides a reference to the entire design process, from conceptualization to operation and maintenance.