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Author: Eric Block
Publisher: Academic Press
ISBN: 1483216438
Category : Science
Languages : en
Pages : 336
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Book Description
Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.
Author: Eric Block
Publisher: Academic Press
ISBN: 1483216438
Category : Science
Languages : en
Pages : 336
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Book Description
Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.
Author: N. Kharasch
Publisher: Elsevier
ISBN: 1483224856
Category : Science
Languages : en
Pages : 637
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Book Description
Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Author: Christopher T Walsh
Publisher: Royal Society of Chemistry
ISBN: 1839161442
Category : Science
Languages : en
Pages : 430
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Book Description
This volume aims to provide an in-depth view of the complete biochemistry of sulfur with an emphasis on aspects not covered elsewhere. Given its role in the formation of proteins and presence in the amino acids methionine and cysteine, sulfur is essential to life. Current literature on the biochemistry of sulfur is vast and widely dispersed, as such this volume is intended as a single-source for everything concerning sulfur biochemistry from metabolic roles of inorganic sulfur, to thiol and thioether chemical biology, to the university of cysteine chemistry in proteomes. Authored by a renowned biochemist and experienced writer and educator, this book is ideal for students and researchers in biochemistry, biology and the life sciences with an interest in sulfur and its role in life.
Author: S. Oae
Publisher: Springer Science & Business Media
ISBN: 1468420496
Category : Science
Languages : en
Pages : 714
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Book Description
In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: J. Drabowicz
Publisher: Springer Science & Business Media
ISBN: 3540665161
Category : Medical
Languages : en
Pages : 265
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Book Description
Embarking on a new millennium, the book in hands describes the recent developments of organsoselenium chemistry in all facets. Various distinguished scientists have contributed, with their skill and expertise, making this book a valuable source for synthetic oriented organic chemists and for those, who want to get a first insight into the chemistry of selenium.
Author: David J Triggle
Publisher: Elsevier
ISBN: 0080445136
Category : Medical
Languages : en
Pages : 9367
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Book Description
The first edition of Comprehensive Medicinal Chemistry was published in 1990 and was very well received. Comprehensive Medicinal Chemistry II is much more than a simple updating of the contents of the first edition. Completely revised and expanded, this new edition has been refocused to reflect the significant developments and changes over the past decade in genomics, proteomics, bioinformatics, combinatorial chemistry, high-throughput screening and pharmacology, and more. The content comprises the most up-to-date, authoritative and comprehensive reference text on contemporary medicinal chemistry and drug research, covering major therapeutic classes and targets, research strategy and organisation, high-throughput technologies, computer-assisted design, ADME and selected case histories. It is this coverage of the strategy, technologies, principles and applications of medicinal chemistry in a single work that will make Comprehensive Medicinal Chemistry II a unique work of reference and a single point of entry to the literature for pharmaceutical and biotechnology scientists of all disciplines and for many industry executives as well. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Comprehensively reviews - the strategies, technologies, principles and applications of modern medicinal chemistry Provides a global and current perspective of today's drug discovery process and discusses the major therapeutic classes and targets Includes a unique collection of case studies and personal assays reviewing the discovery and development of key drugs
Author: Thomas Wirth
Publisher: Springer
ISBN: 3540481710
Category : Science
Languages : en
Pages : 265
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Book Description
Embarking on a new millennium, the book in hands describes the recent developments of organsoselenium chemistry in all facets. Various distinguished scientists have contributed, with their skill and expertise, making this book a valuable source for synthetic oriented organic chemists and for those, who want to get a first insight into the chemistry of selenium.
Author: Tse-Lok Ho
Publisher: Elsevier
ISBN: 0323140963
Category : Science
Languages : en
Pages : 222
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Book Description
Hard and Soft Acids and Bases Principle in Organic Chemistry deals with various phenomena in organic chemistry that are directly related to or derived from the hard and soft acids and bases (HSAB) principle. Topics covered range from chemical reactivity to displacement reactions, along with various HSAB principle applications. This text consists of 11 chapters and begins with a historical overview of the HSAB concept, followed by a classification of hard and soft acids and bases and their theoretical descriptions. The reader is methodically introduced to the stability of organic compounds and complexes; displacement reactions of HSAB; and the chemistry of alkenes, aromatic, and heterocyclic compounds. The reactivity of organophosphorus and carbonyl compounds; organosulfur compounds and other chalcogenides; and organoboranes is also considered. The book concludes with an evaluation of other applications of the HSAB principle, paying particular attention to solubility and protonation; carbenes and nitrenes; the organic chemistry of group IV elements; and the reactions of organohalides, Grignard, and related agents. This book is intended for senior undergraduates or graduate chemistry majors, as well as organic chemists who are not familiar with the HSAB concept.
Author: R. J. Cremlyn
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 272
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Book Description
Sulfur chemistry is becoming increasingly important as the role of this element is explored in both biological and environmental fields. After the initial chapters have discussed the synthesis, reactivity, and properties of the compounds in general, each of the next nine chapters takes a specific sulfur containing functional group and expands the discussion on synthetic procedures. The final chapter looks at the major uses of organo-sulfur compounds and their impact on biological and environmental areas.
