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Author: Stephan Pawlenko
Publisher: Walter de Gruyter
ISBN: 3110862387
Category : Science
Languages : en
Pages : 201
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Book Description
Author: Stephan Pawlenko
Publisher: Walter de Gruyter
ISBN: 3110862387
Category : Science
Languages : en
Pages : 201
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Book Description
Author: Vladimir Ya Lee
Publisher: Academic Press
ISBN: 0128019913
Category : Science
Languages : en
Pages : 758
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Book Description
Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Author: Sam Stuart
Publisher: Elsevier
ISBN: 1483284468
Category : Science
Languages : en
Pages : 350
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Book Description
Organosilicon Chemistry provides information pertinent to the fundamental aspects and application of organosilicon chemistry. This book discusses the exact manner and extent of d-orbital involvement in organosilicon compounds in ground, electronic, and transition excited states. Organized into two parts encompassing 21 chapters, this book begins with an overview of preparing stable organosiliconium ions. This text then discusses the use of fused salts as reaction media in the preparative chemistry. Other chapters consider a detailed investigation on the molecular association and volatility of alkoxides of group (IV) elements. This book discusses as well the reaction between dimethyldichlorosilane and ethylene glycon, which has been shown to produce a dimeric ten-membered ring compound. The final chapter deals with the results of the investigations concerning the properties of the contact mass and of the non-volatile silicon-free products, which are produced in the direct synthesis of phenylhalogenosilanes. This book is a valuable resource for chemists and research workers.
Author: Norbert Auner
Publisher: Wiley-VCH
ISBN: 9783527306701
Category : Science
Languages : en
Pages : 0
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Book Description
Never Change a winning team. The fifth volume in this renowned series retains the established and successful concept: Leading experts from academia and industry present a comprehensive and detailed overview of the latest results in organosilicon chemistry. Synthesis and characterization of new organosilicon compounds Applications in polymer and materials science Summary of the latest research results The result is a unique collection of first-hand information, vital for every expert working in this field. From the contents: Reactions of Silicon Atoms- An Access to Unusual Molecules New Reactions of Stable Silylenes Synthesis and Chemistry of Some Bridged Silicocations Synthesis of a Highly Enantiomerically Enriched Silyllithium Compound Experimental Determination of the Inversion Barriers of Oligosily Anions SiO and SiOSiN Chains, Rings, and Cages Novel Cyclic and Polycyclic Chalcogenides of Silicon Organosilicon Compounds in Medicine and Cosmetics Organosilicon Chemistry and Nanoscience Sustainable Silicon Production The Role of Silanes in Filled and Crosslinked Polymers Catalytic Hydrosilylation of Fatty Compounds Novel Routes fro the Preparation of Nanoporous Silica Particles Aluminosiloxanes as Molecular Models for Aluminosilicates
Author: Prof. Dr. Shigeyoshi Inoue
Publisher: MDPI
ISBN: 3038976385
Category : Science
Languages : en
Pages : 228
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Book Description
The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
Author: Ernest W. Colvin
Publisher: Butterworth-Heinemann
ISBN: 148314223X
Category : Science
Languages : en
Pages : 361
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Book Description
Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a "ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.
Author: Sam Stuart
Publisher: Elsevier
ISBN: 1483284824
Category : Science
Languages : en
Pages : 257
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Book Description
Organosilicon Chemistry: 2 provides information pertinent to the fundamental aspects of organosilicon chemistry. This book discusses the organosilicon substituents in anionic rearrangements as well as examines the production of tetrakis allene from a large number of aliphatic and aromatic polyhalogenated compounds. Organized into 14 chapters, this book begins with an overview of the use of organosilyl groups as migrating substituents. This text then examines the development in the chemistry of organosilicon cyclic compounds. Other chapters consider the evidence supporting the intermediacy of silylenes and the general picture of the chemistry of organosilylenes. This book discusses as well the two major approaches for the silylation of polyhalogenated compounds, including the direct reaction of polyhalogenated compounds and the metalation or halogen-metal exchange between the halogenated aromatic compounds and organolithium reagents. The final chapter deals with the importance of hydrosilation. This book is a valuable resource for chemists, scientists, and research workers.
Author: Vladimir Ya. Lee
Publisher: John Wiley & Sons
ISBN: 1119956269
Category : Science
Languages : en
Pages : 390
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Book Description
Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry
Author: Herbert W Roesky
Publisher: Academic Press
ISBN: 0128035684
Category : Science
Languages : en
Pages : 540
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Book Description
Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter
Author: Bogdan Marciniec
Publisher: Taylor & Francis
ISBN: 9782884491228
Category : Chemical reactions
Languages : en
Pages : 620
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Book Description
Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.
