Author: Evelyn Pauline Gause
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 200
Book Description
Optical and NMR Spectra of Symmetrical and Unsymmetrical Nickel (II) Complexes with Some Tetradentate Schiff Bases
Author: Evelyn Pauline Gause
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 200
Book Description
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 200
Book Description
Nickel(II) Complexes of Some Neutral Tetradentate Schiff Base Ligands
Author: Thomas Grant Campbell
Publisher:
ISBN:
Category :
Languages : en
Pages : 234
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 234
Book Description
Nickel (II) Complexes Containing Non-cyclic and Macrocyclic Ligands Derived from 2,3-butanedione Monohydrazone and 3,3-dimethyl-1,2-butanedione Monohydrazone
Author: Douglas Brian Bonfoey
Publisher:
ISBN:
Category : Organonickel compounds
Languages : en
Pages : 122
Book Description
Publisher:
ISBN:
Category : Organonickel compounds
Languages : en
Pages : 122
Book Description
Nickel (II) Complexes of Some Unusual Tetradentate Ligands Containing Nitrogen and Sulfur Donors
Author: Major Curt Thompson
Publisher:
ISBN:
Category : Nickel
Languages : en
Pages : 82
Book Description
Publisher:
ISBN:
Category : Nickel
Languages : en
Pages : 82
Book Description
Beauty in Chemistry
Author: Luigi Fabbrizzi
Publisher: Springer Science & Business Media
ISBN: 3642283411
Category : Science
Languages : en
Pages : 180
Book Description
The Beauty of Chemistry in the Words of Writers and in the Hands of Scientists, by Margherita Venturi, Enrico Marchi und Vincenzo Balzani Living in a Cage Is a Restricted Privilege, by Luigi Fabbrizzi Inner and Outer Beauty, by Kenneth N. Raymond und Casey J. Brown The Mechanical Bond: A Work of Art, by Carson J. Bruns und J. Fraser Stoddart The Beauty of Knots at the Molecular Level, by Jean-Pierre Sauvage und David B. Amabilino
Publisher: Springer Science & Business Media
ISBN: 3642283411
Category : Science
Languages : en
Pages : 180
Book Description
The Beauty of Chemistry in the Words of Writers and in the Hands of Scientists, by Margherita Venturi, Enrico Marchi und Vincenzo Balzani Living in a Cage Is a Restricted Privilege, by Luigi Fabbrizzi Inner and Outer Beauty, by Kenneth N. Raymond und Casey J. Brown The Mechanical Bond: A Work of Art, by Carson J. Bruns und J. Fraser Stoddart The Beauty of Knots at the Molecular Level, by Jean-Pierre Sauvage und David B. Amabilino
Synthesis and Characterisation of Nickel (II) and Copper (II) Complexes of Some Macrocyclic Schiff-base Ligands
Author: Hassan Keypour
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Ni(II) Complexes of the Linear Tetradentate Ligand, 4,6,6-trimethyl-1,9-diamine-3, 7-diazanon-3-ene-nickel(II)
Author: Ellen Hsia Hung
Publisher:
ISBN:
Category : Nickel
Languages : en
Pages : 134
Book Description
Publisher:
ISBN:
Category : Nickel
Languages : en
Pages : 134
Book Description
Nickel (II) Complexes of Schiff Bases Derived from Pyrrole-2-aldehyde and Dipropylenetriamine
Author: Russell P. Cheney
Publisher:
ISBN:
Category : Nickel
Languages : en
Pages : 188
Book Description
Publisher:
ISBN:
Category : Nickel
Languages : en
Pages : 188
Book Description
Oxygen Complexes and Oxygen Activation by Transition Metals
Author: Arthur Martell
Publisher: Springer Science & Business Media
ISBN: 1461309557
Category : Science
Languages : en
Pages : 341
Book Description
This monograph consists of manuscripts, summary statements, and poster abstracts submitted by invited speakers and poster contributors who participated in the symposium "Oxygen Complexes and Oxygen Activation by Transition Metals," held March 23-26, 1987, at Texas A&M University. This meeting was the fifth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The co chairmen of the conference were Professors Arthur E. Martell and Donald T. Sawyer of the Texas A&M University Chemistry Department. The program was developed by an academic-industrial steering committee consisting of the co-chairmen and members appointed by the sponsoring chemical companies Dr. James F. Bradzil, The Standard Oil Company, Ohio; Dr. Jerry R. Ebner, Monsanto Company; Dr. Craig Murchison, Dow Chemical Company; Dr. Donald C. Olsen, Shell Development Company; Dr. Tim R. Ryan, Celanese Chemical Company; and Dr. Ron Sanderson, Texaco Chemical Company. The subject of this conference reflects the intense interest that has developed in academic institutions and industry on several aspects of dioxygen chemistry. These include the formation of dioxygen complexes and their applications in facilitated transport and oxygen separation; homo geneous and heterogeneous catalysis of oxidation; and oxygenation of organic substrates by molecular oxygen. The conference differs in two respects from several other symposia on dioxygen chemistry held during the past few years. First, there is extensive industrial participation, especially with respect to oxygen activation.
Publisher: Springer Science & Business Media
ISBN: 1461309557
Category : Science
Languages : en
Pages : 341
Book Description
This monograph consists of manuscripts, summary statements, and poster abstracts submitted by invited speakers and poster contributors who participated in the symposium "Oxygen Complexes and Oxygen Activation by Transition Metals," held March 23-26, 1987, at Texas A&M University. This meeting was the fifth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The co chairmen of the conference were Professors Arthur E. Martell and Donald T. Sawyer of the Texas A&M University Chemistry Department. The program was developed by an academic-industrial steering committee consisting of the co-chairmen and members appointed by the sponsoring chemical companies Dr. James F. Bradzil, The Standard Oil Company, Ohio; Dr. Jerry R. Ebner, Monsanto Company; Dr. Craig Murchison, Dow Chemical Company; Dr. Donald C. Olsen, Shell Development Company; Dr. Tim R. Ryan, Celanese Chemical Company; and Dr. Ron Sanderson, Texaco Chemical Company. The subject of this conference reflects the intense interest that has developed in academic institutions and industry on several aspects of dioxygen chemistry. These include the formation of dioxygen complexes and their applications in facilitated transport and oxygen separation; homo geneous and heterogeneous catalysis of oxidation; and oxygenation of organic substrates by molecular oxygen. The conference differs in two respects from several other symposia on dioxygen chemistry held during the past few years. First, there is extensive industrial participation, especially with respect to oxygen activation.
Relaxation Spectra of Some Nickel (ii) and Cobalt (ii) Complexes
Author: Gordon G. Hammes
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
Book Description
The rate constants for the formation and dis sociation of Ni(II) and Co(II) complexes with one, two and three glycine, diglycine, or imida zole molecules were determined by the temperature jump technique. The approximate time scale of the reactions studied ranged from 0.1 to 500 msec. The rate-determining step of the complex building reaction, following initial formation of an ion pair, is the dissociation of a water molecule from the inner hydration sphere of the metal ion. The measured rate constants can be normalized with respect to electrostatic and steric factors by dividing out the calculated ion-pair equilibrium constant. The rate constant of dissociation thus obtained is characteristic of a given metal ion, and, in nearly all the re actions studied, was 20 to 25 times greater for Co(II) than for Ni(II). The difference in acti vation energies corresponding to this rate ratio is of the order of magnitude predicted on the basis of crystal-field theories. For glycine, these normalized rate constants tend to increase in reactions involving the higher complexes, in dicating a loosening of the hydration shell due to the fact that the glycine is bound to the metal via the negatively charged carboxyl group. These rate constants are independent of the number of ligands bound if the bonding takes place via uncharged groups. (Author).
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
Book Description
The rate constants for the formation and dis sociation of Ni(II) and Co(II) complexes with one, two and three glycine, diglycine, or imida zole molecules were determined by the temperature jump technique. The approximate time scale of the reactions studied ranged from 0.1 to 500 msec. The rate-determining step of the complex building reaction, following initial formation of an ion pair, is the dissociation of a water molecule from the inner hydration sphere of the metal ion. The measured rate constants can be normalized with respect to electrostatic and steric factors by dividing out the calculated ion-pair equilibrium constant. The rate constant of dissociation thus obtained is characteristic of a given metal ion, and, in nearly all the re actions studied, was 20 to 25 times greater for Co(II) than for Ni(II). The difference in acti vation energies corresponding to this rate ratio is of the order of magnitude predicted on the basis of crystal-field theories. For glycine, these normalized rate constants tend to increase in reactions involving the higher complexes, in dicating a loosening of the hydration shell due to the fact that the glycine is bound to the metal via the negatively charged carboxyl group. These rate constants are independent of the number of ligands bound if the bonding takes place via uncharged groups. (Author).