On the Electro-Chemo-Mechanical Coupling in Solid State Batteries and its Impact on Morphological Interface Stability

On the Electro-Chemo-Mechanical Coupling in Solid State Batteries and its Impact on Morphological Interface Stability PDF Author: Ganser, Markus
Publisher: KIT Scientific Publishing
ISBN: 3731510472
Category : Technology & Engineering
Languages : en
Pages : 272

Get Book Here

Book Description
Solid state batteries with a lithium metal electrode are considered the next generation of high energy battery technology. Unfortunately, lithium metal is prone to harmful protrusion or dendrite growth which causes dangerous cell failure. Within this work the problem of protrusion growth is tackled by deriving a novel electro-chemo-mechanical theory tailored for binary solid state batteries which is then used to discuss the impact of mechanics on interface stability by numerical studies.

Modeling transport properties and electrochemical performance of hierarchically structured lithium-ion battery cathodes using resistor networks and mathematical half-cell models

Modeling transport properties and electrochemical performance of hierarchically structured lithium-ion battery cathodes using resistor networks and mathematical half-cell models PDF Author: Birkholz, Oleg
Publisher: KIT Scientific Publishing
ISBN: 373151172X
Category : Science
Languages : en
Pages : 246

Get Book Here

Book Description
Hierarchically structured active materials in electrodes of lithium-ion cells are promising candidates for increasing gravimetric energy density and improving rate capability of the system. To investigate the influence of cathode structures on the performance of the whole cell, efficient tools for calculating effective transport properties of granular systems are developed and their influence on the electrochemical performance is investigated in specially adapted cell models.

Application of Data Mining and Machine Learning Methods to Industrial Heat Treatment Processes for Hardness Prediction

Application of Data Mining and Machine Learning Methods to Industrial Heat Treatment Processes for Hardness Prediction PDF Author: Lingelbach, Yannick
Publisher: KIT Scientific Publishing
ISBN: 3731513528
Category :
Languages : en
Pages : 278

Get Book Here

Book Description
This work presents a data mining framework applied to industrial heattreatment (bainitization and case hardening) aiming to optimize processes and reduce costs. The framework analyses factors such as material, production line, and quality assessment for preprocessing, feature extraction, and drift corrections. Machine learning is employed to devise robust prediction strategies for hardness. Its implementation in an industry pilot demonstrates the economic benefits of the framework. - This work presents a data mining framework applied to industrial heattreatment (bainitization and case hardening) aiming to optimize processes and reduce costs. The framework analyses factors such as material, production line, and quality assessment for preprocessing, feature extraction, and drift corrections. Machine learning is employed to devise robust prediction strategies for hardness. Its implementation in an industry pilot demonstrates the economic benefits of the framework.

Multiscale Modeling of Curing and Crack Propagation in Fiber-Reinforced Thermosets

Multiscale Modeling of Curing and Crack Propagation in Fiber-Reinforced Thermosets PDF Author: Schöller, Lukas
Publisher: KIT Scientific Publishing
ISBN: 3731513404
Category :
Languages : en
Pages : 230

Get Book Here

Book Description
During the production of fiber-reinforced thermosets, the resin material undergoes a reaction that can lead to damage. A two-stage polymerization reaction is modeled using molecular dynamics and evaluations of the system including a fiber surface are performed. In addition, a phase-field model for crack propagation in heterogeneous systems is derived. This model is able to predict crack growth where established models fail. Finally, the model is used to predict crack formation during curing.

Consequences of hydroxyl generation by the silica/water reaction - Part I: Diffusion and Swelling

Consequences of hydroxyl generation by the silica/water reaction - Part I: Diffusion and Swelling PDF Author: Fett, Theo
Publisher: KIT Scientific Publishing
ISBN: 3731511487
Category : Science
Languages : en
Pages : 226

Get Book Here

Book Description
Water diffusing into silica surfaces gives rise for several effectson diffusion behaviour and mechanical properties. Water added to silica glass increases its specific volume so that the silica expands near the surface. Mechanical boundary conditions give rise for compressive “swelling stresses”. This fact provides a tool for the interpretation of many experimental observations from literature.

Consequences of hydroxyl generation by the silica/water reaction - Part II: Global and local Swelling - Part III: Damage and Young's Modulus

Consequences of hydroxyl generation by the silica/water reaction - Part II: Global and local Swelling - Part III: Damage and Young's Modulus PDF Author: Fett, Theo
Publisher: KIT Scientific Publishing
ISBN: 3731511592
Category : Science
Languages : en
Pages : 226

Get Book Here

Book Description
Water diffusing into silica surfaces gives rise for several effects on diffusion behaviour and mechanical properties. In a preceding booklet, we focused on diffusion and fiber strengths and deformations which were obtained by water soaking under external loading. In the present booklet we deal with results and interpretations of strength increase in the absence of applied stresses.

Dynamic Model-based Analysis of Oxygen Reduction Reaction in Gas Diffusion Electrodes

Dynamic Model-based Analysis of Oxygen Reduction Reaction in Gas Diffusion Electrodes PDF Author: Röhe, Maximilian
Publisher: KIT Scientific Publishing
ISBN: 3731512343
Category :
Languages : en
Pages : 178

Get Book Here

Book Description
In this work, the first simulation model of oxygen depolarized cathodes (ODC), which are silver catalyst-based gas diffusion electrodes, is presented that considers the phase equilibrium of the gas-liquid interface and structure-related inhomogeneities in electrolyte distribution. By means of the model it has been identified that mass transport of water and ions in the liquid phase is a crucial factor for electrode performance and how it is influenced by the electrode structure.

Development of NbN based Kinetic Inductance Detectors on sapphire and diamond substrates for fusion plasma polarimetric diagnostics

Development of NbN based Kinetic Inductance Detectors on sapphire and diamond substrates for fusion plasma polarimetric diagnostics PDF Author: Mazzocchi, Francesco
Publisher: KIT Scientific Publishing
ISBN: 3731511819
Category : Technology & Engineering
Languages : en
Pages : 212

Get Book Here

Book Description
This work aimed at designing, studying and producing the first prototypes of KIDs tailored for fusion plasma polarimetric diagnostics. Diamond was considered for the first time as substrate material for low-temperature superconducting detectors given its unmatched optical, radiation hardness and thermal qualities, properties necessary for working environments potentially saturated with radiation. This work represents a first step toward the optimization and final application of this technology.

Opportunities for Advanced Ceramics to Meet the Needs of the Industries of the Future

Opportunities for Advanced Ceramics to Meet the Needs of the Industries of the Future PDF Author: Douglas W. Freitag
Publisher:
ISBN:
Category : Ceramics
Languages : en
Pages : 162

Get Book Here

Book Description


Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batteries

Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batteries PDF Author: Snehashis Choudhury
Publisher: Springer Nature
ISBN: 3030289435
Category : Technology & Engineering
Languages : en
Pages : 239

Get Book Here

Book Description
This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. This discovery is significant because it overturns a longstanding perception in the field of nanoparticle-polymer hybrid electrolytes that only solid electrolytes with mechanical modulus higher than that of the metal electrode are able to stabilize electrodeposition of reactive metals.