Nitration and Aromatic Reactivity

Nitration and Aromatic Reactivity PDF Author: J. G. Hoggett
Publisher: Cambridge University Press
ISBN: 9780521080293
Category : Science
Languages : en
Pages : 266

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Book Description
First published in 1971 this volume claims that nitration is important because it is the most general process for the preparation of aromatic nitro-compounds.

Nitration and Aromatic Reactivity

Nitration and Aromatic Reactivity PDF Author: J. G. Hoggett
Publisher: Cambridge University Press
ISBN: 9780521080293
Category : Science
Languages : en
Pages : 266

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Book Description
First published in 1971 this volume claims that nitration is important because it is the most general process for the preparation of aromatic nitro-compounds.

The Sulfonation of Benzene

The Sulfonation of Benzene PDF Author: Adelbert William Harvey
Publisher:
ISBN:
Category : Benzene
Languages : en
Pages : 24

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Book Description


Basic Principles of Organic Chemistry

Basic Principles of Organic Chemistry PDF Author: John D. Roberts
Publisher:
ISBN: 9780805383218
Category : Chemistry, Organic
Languages : en
Pages : 1596

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Book Description
Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Nitration

Nitration PDF Author: George Andrew Olah
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 352

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Book Description
Comprehensive and up-to-date, the book brings together for the first time synthetic nitration methods and mechanistic aspects of both aromatic and aliphatic nitrations. Researchers and students will appreciate the complete perspective of the whole field that this unique work offers.

Fundamental Aliphatic Chemistry

Fundamental Aliphatic Chemistry PDF Author: P. W. G. Smith
Publisher: Elsevier
ISBN: 1483139069
Category : Science
Languages : en
Pages : 238

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Book Description
Organic Chemistry for General Degree Students is written to meet the requirements of the London General Internal examination and degree examinations of a similar standing. It will also provide for the needs of students taking the Part 1 examination for Graduate Membership of the Royal Institute of Chemistry, or the Higher National Certificate, whilst the treatment is such that Ordinary National Certificate courses can be based on the first two volumes Within the limits broadly defined by the syllabus, the aim of this first volume is to provide a concise summary of the important general methods of preparation and properties of the main classes of aliphatic compounds. Due attention is paid to practical considerations with particular reference to important industrial processes. At the same time, the fundamental theoretical principles of organic chemistry are illustrated by the discussion of a selection of the more important reaction mechanisms. Questions and problems are included, designed to test the student's appreciation of the subject and his ability to apply the principles embodied therein. A selection of questions set in the relevant examinations is also included.

The Nitro Group in Organic Synthesis

The Nitro Group in Organic Synthesis PDF Author: Noboru Ono
Publisher: John Wiley & Sons
ISBN: 0471458465
Category : Science
Languages : en
Pages : 392

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Book Description
The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include: * Henry reaction * Asymmetric Michael addition * Alkylation, acylation, halogenation, and related reactions of RNO2 * Substitution and elimination of NO2 and RNO2 The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.

Homolytic Aromatic Substitution

Homolytic Aromatic Substitution PDF Author: G. H. Williams
Publisher: Elsevier
ISBN: 1483151131
Category : Science
Languages : en
Pages : 142

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Book Description
Homolytic Aromatic Substitution deals with the theoretical aspects of homolytic aromatic substitution reactions. The effect of various kinds of free radicals on the substitution of atoms or groups (usually hydrogen) attached to aromatic nuclei is examined, and the preparative use of homolytic substitution reactions is also considered. This book is comprised of seven chapters and begins with an introduction to the general characteristics of homolysis, along with homolytic and heterolytic aromatic substitution. The discussion then turns to the various theoretical approaches used to rationalize aromatic substitution, particularly those that are germane to a consideration of the problems of orientation and reactivity in homolytic substitution. The following chapters explore homolytic arylation reactions, including those between aryl radicals and aromatic substrates; relative rates of arylation and partial rate factors for phenylation; the reaction mechanism underlying intramolecular arylation; and homolytic alkylation reactions. The final chapter deals with hydroxylation and some other substitution reactions such as benzoyloxylation, acetyloxylation, halogenation, amination and amidation, and mercuration. This monograph will be of interest to organic chemists.

Nitrosation Reactions and the Chemistry of Nitric Oxide

Nitrosation Reactions and the Chemistry of Nitric Oxide PDF Author: D.L.H. Williams
Publisher: Elsevier
ISBN: 0080473601
Category : Science
Languages : en
Pages : 281

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Book Description
Since 1988, there has been much literature published on the chemistry of nitric oxide, particularly in the field of S-nitrosation and the chemistry of S-nitroso compounds. Written by a chemist for the chemistry community, this book provides an update of the chemistry of nitrosation reactions, dealing with both the synthetic and mechanistic aspects of these reactions. It also looks at the chemistry of nitric oxide in relation to the amazing biological properties of this simple diatomic molecule, which were unknown until around 1990.* Provides an update on previously published literature on nitric oxide chemistry* Contains chapters on reagents for nitrosation, nitrosation at nitrogen, aliphatic and aromatic carbon, oxygen, sulfur and metal centres* Looks at hot research topics such as synthesis, properties and reactions of s-nitrosothiols

Reactions of Aromatic Compounds

Reactions of Aromatic Compounds PDF Author: R.G. Compton
Publisher: Elsevier
ISBN: 008086807X
Category : Science
Languages : en
Pages : 521

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Book Description
Reactions of Aromatic Compounds

Nitroalkanes

Nitroalkanes PDF Author: Roberto Ballini
Publisher: John Wiley & Sons
ISBN: 3527826777
Category : Science
Languages : en
Pages : 322

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Book Description
Discover a comprehensive exploration of recent progress in the preparation of nitroalkanes from two leading voices in the field Nitroalkanes: Synthesis, Reactivity, and Applications delivers a thorough summary of the importance of nitroalkanes in organic synthesis. The book covers their preparation, transformation into other functional groups, like carbonyls and amines, and their use in the formation of single carbon-carbon or double carbon-carbon bonds. The distinguished authors have included chapters on acyclic and cyclic alpha-nitro ketones as well as the synthesis of cyclopropanes and spiro ketals. The book provides treatments of the application of nitroalkanes for the synthesis of important heterocycles, poly-functionalized structures, natural products, and compounds of biological and pharmaceutical interest. A one-stop resource in a topic that hasn???t been fully addressed by any other book in decades, this book covers the most important synthetic routes toward nitroalkanes. Readers will also benefit from the inclusion of: A thorough introduction to the synthesis of nitroalkanes, as well as the transformation of the nitro group into other functionalities An exploration of the formation of C-C single bonds, C=C double bonds, and the breaking of C3C bonds from cyclic alpha-nitro ketones Discussions of acyclic alpha-nitro ketones, nitroalkanes as precursors of cyclopropanes, and the synthesis of spiro ketals An examination of the preparation and synthetic applications of 1,3-Dinitroalkanes Perfect for organic chemists, natural products chemists, and catalytic chemists, Nitroalkanes: Synthesis, Reactivity, and Applications will also earn a place in the libraries of medicinal chemists seeking a one-stop resource for the most recent developments in the preparation of nitroalkanes, their functionalization, and their applications.